Method and system for forming carbon dioxide from carbon-containing materials in a molten bath of immiscible metals

• US 5,177,304 A
• Filed: 07/24/1990
• Issued: 01/05/1993
• Est. Priority Date: 07/24/1990
• Status: Expired due to Fees

• Current Assignee: Molten Metal Technology Incorporated, Quantum Catalytics LLC
• Original Assignee: Molten Metal Technology Incorporated
• Inventors: Nagel, Christopher J.
• Primary Examiner(s): Straub, Gary P.
• Assistant Examiner(s): HENDRICKSON, STUART L
• Application Number:
  US07/557,561
• Time in Patent Office: 896 Days
• Field of Search: 423/437, 423/415 R, 423/DIG. 12, 423/DIG. 20, 588/201, 588/204, 588/221, 110/346
• US Class Current: 588/314
• CPC Class Codes: A62D 2101/04 Pesticides, e.g. insecticides, herbicides, fungicides or nematocides
• CPC Class Codes: A62D 2101/06 Explosives, propellants or pyrotechnics, e.g. rocket fuel or napalm
• CPC Class Codes: A62D 2101/20 Organic substances
• CPC Class Codes: A62D 2101/22 containing halogen
• CPC Class Codes: A62D 2101/40 Inorganic substances
• CPC Class Codes: A62D 3/32 by treatment in molten chemical reagent, e.g. salts or metals
• CPC Class Codes: C10J 2300/0946 Waste, e.g. MSW, tires, glass, tar sand, peat, paper, lignite, oil shale
• CPC Class Codes: C10J 2300/1269 by radiating device, e.g. radiant tubes
• CPC Class Codes: C10J 3/57 Gasification using molten salts or metals C10J3/02, C10J3/46 take precedence
• CPC Class Codes: F23G 5/085 High-temperature heating means, e.g. plasma, for partly melting the waste
• CPC Class Codes: Y02P 20/52 using catalysts, e.g. selective catalysts
• CPC Class Codes: Y10S 423/12 Molten media

Abstract

A method and a system for converting carbon-containing feed to atomic carbon and for oxidizing atomic carbon to carbon dioxide is disclosed. Carbon-containing feed, such as municipal garbage, low grade fuel oil and organic or inorganic sludge is introduced to a molten metal bath. The molten metal bath includes a first molten metal phase having a significant solubility of atomic carbon and a second molten metal phase, substantially immiscible in the first molten metal phase and having a solubility of atomic carbon less than that of the first molten metal phase. Carbon in the carbon-containing feed is catalytically converted to atomic carbon. The atomic carbon are oxidized in the first molten metal phase to carbon monoxide which is then directed to the second molten metal phase. Carbon monoxide in the second molten metal phase is oxidized to form carbon dioxide. The carbon dioxide is released to the atmosphere. Other atomic free radicals formed in the molten metal both are substantially converted to oxides and other stable compounds.

Claims

1. A method for increasing conversion of atomic carbon, formed from a carbon-containing feed, to carbon dioxide in a molten metal bath, comprising the steps of:

a) introducing the carbon-containing feed to a reactor containing a molten metal bath having;

1) a first molten metal phase, consisting essentially of metal having a free energy of oxidation, at the molten metal bath conditions, greater than that of oxidation of atomic carbon to form carbon monoxide; and

2) a second molten metal phase for increasing conversion of the atomic carbon to carbon dioxide in the molten metal bath compared to conversion to carbon dioxide in the first molten metal phase, the second molten metal phase being substantially immiscible in the first molten metal phase and in contact with the first molten metal phase, said second molten metal phase consisting essentially of metal having a free energy of oxidation, at the molten metal bath conditions, greater than that of oxidation of carbon monoxide to form carbon dioxide, in which the solubility of atomic carbon is significantly lower than in the first molten metal phase,

whereby the molten metal bath in said reactor catalytically converts carbon in the carbon-containing feed to atomic carbon, and whereby atomic carbon formed in the second molten metal phase migrates to the first molten metal phase; and

b) introducing oxygen to the molten metal bath, whereby atomic carbon in the first molten metal phase is oxidized to form carbon monoxide and whereby carbon monoxide migrates to the second molten metal phase wherein carbon monoxide is oxidized to form carbon dioxide thereby increasing conversion of the atomic carbon to carbon dioxide in the molten metal bath compared to conversion of atomic carbon to carbon dioxide in the first molten metal phase at the same molten metal bath conditions.

2. A method of claim 1 further including a vitreous layer.

3. A method of claim 2 wherein the solubility of carbon monoxide in the vitreous layer is less than that of the first molten metal.

4. A method of claim 3 wherein the vitreous layer has a lower thermal conductivity than the first molten metal and the second molten metal.

5. A method of claim 4 wherein the carbon-containing feed is exposed in the molten metal bath to conditions sufficient to cause catalytic extraction of substantially all atomic constituents from the carbon-containing feed, whereby the atomic constituents are converted to free radicals.

6. A method of claim 5 wherein the carbon-containing feed is exposed to at least a portion of the free radicals, whereby the atomic constituents of the carbon-containing feed are at least partially extracted from the carbon-containing feed and are thereby converted to free radicals.

7. A method of claim 6 wherein the free radicals formed by extraction of atomic constituents from the carbon-containing feed include hydrogen free radicals.

8. A method of claim 7 wherein the free radicals formed by extraction of atomic constituents from the carbon-containing feed include free hydrogen radicals.

9. A method of claim 8 wherein the carbon monoxide and carbon dioxide formed from carbon generates sufficient heat to allow exposure of the carbon-containing feed to the first molten metal phase and the second molten metal phase to catalytically convert carbon-containing feed to atomic free radicals, including atomic carbon.

10. A method of claim 9, further including introducing oxygen above the vitreous layer in an amount sufficient to substantially oxidize free radicals leaving the molten metal bath and to form a gas phase above the vitreous layer.

11. A method of claim 10 wherein the system is disposed in a vessel and wherein the carbon-containing feed is introduced to the system at the vitreous layer.

12. A method of claim 11 wherein oxygen is introduced through a bottom portion of the vessel.

13. A method of claim 12 wherein the first molten metal forms a first layer and where the second molten metal forms a second layer disposed adjacent to the first layer and above the first layer.

14. A method of claim 13 wherein the oxygen introduced to the system through the bottom portion of the vessel is directed into the first layer.

15. A method of claim 14 wherein the first molten metal phase consists essentially of molten iron.

16. A method of claim 15 wherein the second molten metal phase consists essentially of molten copper.

17. In a method for catalytically converting carbon in a carbon-containing feed to atomic carbon in a molten metal bath, wherein carbon-containing feed and oxygen are introduced to the molten metal bath, and whereby the carbon-containing feed is exposed to conditions sufficient to allow the molten metal bath to catalytically convert carbon in carbon-containing feed to atomic carbon;

the improvement comprising introducing the carbon-containing feed into a reactor containing a molten metal bath having a first molten metal phase consisting essentially of metal having a free energy of oxidation, at the molten metal bath conditions, greater than that of oxidation of atomic carbon to form carbon monoxide, and a second molten metal phase, substantially immiscible in the first molten metal phase and in contact with the first molten metal phase, said second molten metal phase consisting essentially of metal having a free energy of oxidation, at the molten metal bath conditions, greater than that of oxidation of carbon monoxide to form carbon dioxide, in which the solubility of atomic carbon is significantly lower than in the first molten metal phase, whereby atomic carbon formed in the second molten metal phase migrate to the first molten metal phase, and whereby carbon monoxide formed in the first molten metal phase migrates to the second molten metal phase for reacting with oxygen, introduced to the molten metal bath, to form carbon dioxide, thereby increasing conversion of atomic carbon to carbon dioxide in the molten metal bath compared to the conversion of atomic carbon to carbon dioxide in the first molten metal phase at the same molten metal bath conditions.