Odor sensing system

• US 5,177,994 A
• Filed: 05/22/1991
• Issued: 01/12/1993
• Est. Priority Date: 05/22/1991
• Status: Expired due to Term

• Current Assignee: Tokyo Institute of Technology (National University Corporation Tokyo Institute of Technology)
• Original Assignee: Suntory Limited and Tokyo Institute of Technology
• Inventors: Fukuda, Atsushi, Asakura, Yasuo, Moriizumi, Toyosaka, Nakamoto, Takamichi
• Primary Examiner(s): Williams, Hezron E.
• Assistant Examiner(s): ROSKOS, JOSEPH
• Application Number:
  US07/704,112
• Time in Patent Office: 601 Days
• Field of Search: 73/23.34, 422/83, 422/88
• US Class Current: 73/23.34
• CPC Class Codes: G01N 2291/0256 Adsorption, desorption, surface mass change, e.g. on biosensors
• CPC Class Codes: G01N 29/036 by measuring frequency or resonance of acoustic waves
• CPC Class Codes: G01N 33/0031 comprising two or more sensors, e.g. a sensor array electrochemical electrode arrays G01N27/27

Abstract

An odor sensing system is comprised of a sensor cell including a plurality of quartz resonator sensors aligned therein to detect odor by variation of resonance frequencies derived from weight loading on surfaces thereof, a recognition line including a neural network which recognizes data obtained by subtraction between an output signal of the sensor as frequency variation and, a reference signal selected by one of the output signals of the sensor. The sensor cell is thermostatically regulated by circulating thermostatic water therein to maintain the temperature higher than an advance line of the system. A sample to be recognized is supplied to the sensor cell in a form of vapor generated by blowing a standard gas onto the surface of the sample.

Claims

1. An odor sensing system for discrimination of closely parallel odors, said system comprising:

a sample vapor supply line having a gas supply means to supply gas flow through said system, a mass flow controller connected to said gas supply means to maintain said flow constantly, a cleaning circuit including a switch-over means connected to said mass flow controller allowing said gas flow to pass through said circuit, and a sampling circuit connected to said mass flow controller, said switch-over means switching between said cleaning circuit and said sampling circuit, said sampling circuit including a plurality of sample vapor generators selectively allowing said gas flow to pass therethrough to generate a sample vapor therein,

a signal output line connected to said sample vapor supply line having a plurality of gas sensors to convert said plurality of sample vapors received from said line to a plurality of pattern signals; and

a recognition line connected to said signal output line to receive said plurality of signals therefrom, said recognition line having distinction means to calculate a respective subtraction between said signals to distinguish differences therebetween, and a discrimination means connected to said distinction means to discriminate odor included in said sample from said subtracted signals.

2. An odor sensing system as set forth in claim 1, wherein said system further includes thermostatic regulation means to maintain a temperature essentially surrounding said signal output line higher than that of said sample vapor supply line for establishing homogeneity of said sample vapor to be passed therethrough by preventing coagulation of said sample vapor in said system.

3. An odor sensing system as set forth in claim 2, wherein said thermostatic regulation is accomplished by circulating water through said sample vapor supply line and said signal output line, said water being regulated to a desired temperature.

4. An odor sensing system as set forth in claim 1, wherein said system further includes an exhaust line connected to said output line to exhaust said sample vapor from said system toward an outside ambient.

5. An odor sensing system as set forth in claim 1, wherein said sample vapor is generated by blowing said gas flow to the surface of said sample in said sample vapor generator, if said sample is in liquid form.

6. An odor sensing system as set forth in claim 5, wherein said gas flow is blown from a blow end installed in said sample vapor generator, keeping a desired distance between said blow end and said surface of the sample constant.

7. An odor sensing system as set forth in claim 6, wherein said distance is determined to 8 mm.

8. An odor sensing system as set forth in claim 1, wherein said gas flow supplied from said gas supply means is standard air.

9. An odor sensing system as set forth in claim 1, wherein said mass flow controller controls said gas flow in a flow rate of less than 60 ml/min.

10. An odor sensing system as set forth in claim 9, wherein said flow rate is determined to 50 ml/min.

11. An odor sensing system as set forth in claim 1, wherein said gas sensor included in said signal output line is a quartz resonator sensor having a pair of membranes, said quartz resonator sensor held therebetween to adsorb an odorant included in said sample vapor.

12. An odor sensing system as set forth in claim 11, wherein said quartz resonator sensor is movable from its desired position in said signal output line by positioning in a metallic casing.

13. An odor sensing system as set forth in claim 11, wherein said membrane is selected from the group consisting of gas chromatographic stationary phases, celluloses, and lipid materials.

14. An odor sensing system as set forth in claim 11, wherein said membrane is selected from the group consisting of dioleyl phosphatidylserin, sphingomyelin, lecithin, cholesterol, perfluorinated bilayer, polyethyleneglycol, ethyl cellulose, and acetyl cellulose.

15. An odor sensing system as set forth in claim 1, wherein said cleaning circuit is switched over before said sample is put into said sample vapor generator to clean said signal output line.

16. An odor sensing system as set forth in claim 1, wherein said switch-over means is a solenoid valve.

17. An odor sensing system as set forth in claim 1, wherein said plurality of sample vapor generators are passed through by said gas flow before said sample is put thereinto for cleaning thereof.

18. An odor sensing system as set forth in claim 17, wherein said gas flow is heated.

19. A method for discriminating odors having closely parallel characteristics comprising the steps of:

supplying a gas flow to a plurality of samples to selectively generate a sample vapor therefrom;

gathering said selectively generated sample vapors;

converting said plurality of sample vapors to a plurality of signals having a frequency variation, individually;

selecting one of said signals,

detecting said selected signal to memorize as a reference signal,

detecting the remainder of said signals sequentially,

calculating a subtraction between said reference signal and said remainder signals, respectively to distinguish a difference therebetween, and

discriminating said subtracted signals to recognize odor included in said sample using a pattern algorithm.

20. A method as set forth in claim 19 further comprising the step of removing odorants present from previous discriminations before supplying said gas flow to said sample.

21. A method as set forth in claim 19 further comprising the step of thermostatically regulating a conversion temperature of said sample vapor higher than a generating temperature for establishing homogeneity of said sample vapor to be passed therethrough by preventing coagulation thereof.

22. A method as set forth in claim 21, wherein said thermostatic regulation is accomplished by circulating water regulated to a desired temperature for said generation and said conversion, respectively.

23. A method as set forth in claim 19, wherein said step of supplying said gas flow including a step of blowing said gas flow to the surface of said sample, if said sample is in liquid form.

24. A method as set forth in claim 23, wherein said blowing is done keeping a desired distance from the surface of the sample constant.

25. A method as set forth in claim 24, wherein said distance is determined to 8 mm.

26. A method as set forth in claim 19, wherein said step of supplying said gas flow is controlled by a mass flow controller at a flow rate of less than 60 ml/min.

27. A method as set forth in claim 26, wherein said flow rate is determined to 50 ml/min.

28. A method as set forth in claim 19, wherein said step of converting is accomplished by a plurality of quartz resonator sensors, each sensor having a pair of membranes, said quartz resonator sensor held therebetween to adsorb said odorant included in said sample vapor.

29. A method as set forth in claim 28, wherein said membrane is selected from the group consisting of gas chromatographic stationary phases, celluloses, and lipid materials.

30. A method as set forth in claim 28, wherein said membrane is selected from the group consisting of dioleyl phosphatidyleerin, sphingomyelin, lecithin, cholesterol, perfluorinated bilayer, polyethyleneglycol, ethyl cellulose, and acetyl cellulose.