Bilayer oxide film and process for producing same

• US 5,178,967 A
• Filed: 02/08/1990
• Issued: 01/12/1993
• Est. Priority Date: 02/03/1989
• Status: Expired due to Term

• Current Assignee: Novelis Incorporated (Hindalco Industries Limited)
• Original Assignee: Alcan Incorporated (Rio Tinto Limited)
• Inventors: Rosenfeld, Aron M., Smits, Paul
• Primary Examiner(s): Niebling, John
• Assistant Examiner(s): Leader, William T.
• Application Number:
  US07/476,969
• Time in Patent Office: 1,069 Days
• Field of Search: 204/37.6, 204/38.3, 204/42, 156/230, 156/233, 156/289, 156/234, 156/150, 156/151, 156/238, 156/239, 428/43, 428/699, 428/697, 428/701, 205/106, 205/138, 205/139, 205/152, 205/171, 205/173, 205/175, 205/189, 205/190, 205/201, 205/202, 205/229
• US Class Current: 428/697
• CPC Class Codes: C25D 11/04 of aluminium or alloys based thereon
• CPC Class Codes: C25D 11/045 for forming AAO templates
• CPC Class Codes: C25D 11/26 of refractory metals or alloys based thereon
• CPC Class Codes: Y10S 206/819 Material

Abstract

A bilayer oxide film which comprises a preferably porous layer containing aluminum oxide and a non-porous layer comprising an oxide of a valve metal, e.g. tantalum. The layers are integral. The film is produced by forming a coating of aluminium or an anodizable aluminum alloy on a valve metal (or alloy), anodizing the resulting structure in an electrolyte (preferably one capable of converting the aluminum (or alloy) to a porous oxide film) in the presence of an adhesion-reducing agent (e.g. fluoride ions) that makes the resulting anodized bilayer film easily detachable from the remaining valve metal. The bilayer film is then detached from the valve metal, e.g. by adhering a flexible plastic film to the bilayer and using the film to peel off the bilayer from the valve metal. The resulting bilayer can be used for a variety of purposes, e.g. as a vapor or oxygen barrier useful for packaging, or as a coating containing magnetic particles used to make a magnetic recording medium.

Claims

1. A process for producing a packaging film having low oxygen and moisture permeability including a bilayer oxide film comprising a layer containing aluminum oxide and a layer containing an oxide of tantalum or niobium, said process comprising:

providing a substrate comprising a metal, at least at an exposed surface of the substrate, selected from the group consisting of tantalum, niobium and anodizable alloys thereof;

forming a coating on said surface of a material selected from the group consisting of aluminum and anodizable aluminum alloys;

anodizing said coated substrate for a sufficient time and at a sufficient voltage to consume said coating and some of said metal of said substrate to form a bilayer oxide film, said anodization being carried out in the presence of a fluoride as an adhesion-reducing agent capable of reducing the strength of attachment of the bilayer film to the remaining metal;

attaching a flexible packaging sheet to said bilayer film; and

detaching said flexible sheet and said bilayer oxide film from said remaining metal.

2. A process according to claim 1, wherein said valve metal is Ta.

3. A process according to claim 1, wherein said adhesion-reducing agent is a member of the group consisting of fluorine containing salts and fluorine containing acids.

4. A process according to claim 1, wherein said adhesion-reducing agent is present in an electrolyte used for said anodization step.

5. A process according to claim 4 wherein said adhesion-reducing agent is present in said electrolyte in an amount of at least 0.003% by volume.

6. A process according to claim 1, wherein said adhesion-reducing agent is applied to said coating prior to said anodizing step.

7. A process according to claim 1, wherein said coating is formed on said substrate by a vapour deposition technique.

8. A process according to claim 7 wherein said vapour deposition technique is sputtering.

9. A process according to claim 1, wherein said anodization is carried out in an electrolyte which results in the formation of a porous aluminum oxide layer as one layer of said bilayer oxide film.

10. A process according to claim 9 wherein a substance is deposited in pores in said porous layer.

11. A process according to claim 10 wherein said substance is deposited by electro-deposition prior to detaching said bilayer film from the remaining valve metal.

12. A process according to claim 10 wherein said substance is deposited by electroless deposition.

13. A process according to claim 1, wherein said anodization is carried out at a voltage in the range of 5 to 25 volts at least until said coating is consumed.

14. A process according to claim 13 wherein said voltage is increased to 25-200 V following the consumption of said coating.

15. A process according to claim 1, wherein said substrate comprising a layer of said Ta or Nb supported on a layer of a different material.

16. A process according to claim 15 wherein said Ta or Nb is deposited on said different material by a vapour deposition technique.

17. A process according to claim 1 which comprises the further steps, after detaching said bilayer film and attached packaging sheet from said remaining metal, of coating a metal substrate comprising a metal selected from the group consisting of Ta, Nb and anodizable alloys thereof, at least at an exposed surface thereof, with aluminum or an anodizable aluminum alloy, anodizing the coated metal substrate to cause an additional bilayer film to grow on said metal substrate, said anodization being carried out in the presence of a fluoride as an adhesion-reducing agent capable of making said additional bilayer film detachable from said metal substrate on which it is grown, attaching said oxide-coated packaging sheet to said additional bilayer film, and detaching said additional bilayer film and attached oxide coated packaging sheet from said metal substrate on which said additional bilayer film was grown, to form a doubly oxide coated packaging sheet.

18. A process according to claim 17 wherein said oxide coated packaging sheet is attached to said additional bilayer film such that the bilayer film of the oxide coated packaging sheet and the additional bilayer film are adjacent in the doubly oxide coated packaging sheet.

19. A process according to claim 1 wherein said process is repeated to form first and second oxide coated packaging sheets and wherein said first and second oxide coated packaging sheets are adhered together.

20. A process according to claim 19 wherein said first and second oxide coated packaging sheets are adhered together with the bilayer film of each of said oxide coated sheets positioned adjacent to each other.

21. A process according to claim 19 wherein the bilayer film of said oxide coated packaging sheet is covered by attaching an additional sheet of material to said bilayer film.

22. A process according to claim 21 wherein the material of said oxide coated packaging sheet and the material of said additional packaging sheet are made of the same material.

23. A process according to claim 1 wherein said anodization is carried out in an electrolyte which results in the formation of a non-porous barrier layer of aluminum oxide as one layer of said bilayer oxide film.

24. A packaging film of low oxygen and moisture permeability including a bilayer oxide film comprising a layer of aluminum oxide and a layer of an oxide of a metal selected from the group consisting of Ta, Nb and anodizable alloys thereof, said layers being integral;

said packaging film having been produced by a process which comprises;

providing a substrate comprising a metal, at least at an exposed surface of the substrate, selected from the group consisting of tantalum, niobium and anodizable alloys thereof;

forming a coating on said surface of a material selected from the group consisting of aluminum and anodizable aluminum alloys;

anodizing said coated substrate for a sufficient time and at a sufficient voltage to consume said coating and some of said metal of said substrate to form a bilayer oxide film, said anodization being carried out in the presence of a fluoride as an adhesion-reducing agent capable of reducing the strength of attachment of the bilayer film to the remaining metal;

attaching a flexible packaging sheet to said bilayer film; and

detaching said flexible sheet and said bilayer oxide film from said remaining metal.

25. A film according to claim 24 wherein said layer of aluminum oxide is porous whereas said layer of metal oxide is non-porous.

26. A film according to claim 24 wherein said metal oxide is an oxide of tantalum.

27. A film according to claim 24 wherein said aluminum oxide layer is porous and wherein pores in said porous layer contain a material deposited therein.

28. A film according to claim 24 wherein said flexible packaging sheet is a polymer.

29. A film according to claim 24 comprising a further bilayer oxide film adhered to said sheet or to said bilayer film.

30. A film according to claim 24 comprising a further packaging sheet adhered to said bilayer film.

31. A film according to claim 24 wherein said layer of aluminum oxide is a non-porous barrier layer and said layer of valve metal oxide is also non-porous.