Anti-reflection optical element

• US 5,181,141 A
• Filed: 02/24/1992
• Issued: 01/19/1993
• Est. Priority Date: 03/31/1989
• Status: Expired due to Term

• Current Assignee: Hoya Corporation
• Original Assignee: Hoya Corporation
• Inventors: Sato, Koji, Nakamura, Kimio, Suzuki, Tokio, Kosaka, Masahisa, Kamiya, Hajime, Ohsora, Tetsuo
• Primary Examiner(s): NOT, DEFINED
• Application Number:
  US07/839,684
• Time in Patent Office: 330 Days
• Field of Search: 350/164, 350/165, 350/166, 359/580, 359/581, 359/582, 359/586, 427/164
• US Class Current: 359/580
• CPC Class Codes: G02B 1/115 Multilayers

Abstract

The anti-reflection optical element of the present invention achieves reduction of surface reflection by providing a multi-layered anti-reflection film directly or indirectly on an optical component made of a plastic. The anti-reflection optical element of the present invention uses a multi-layered anti-reflection film comprising at least one high refractive index film layer which is a film of mixed metal oxides comprising tantalum oxide, zirconium oxide and yttrium oxide deposited by evaporation process, and thereby has solved the problems of conventional anti-reflection optical elements that their optical, mechanical and chemical properties are deteriorated with the lapse of time.

Claims

1. An anti-reflection optical element comprising (i) an optical component made of a plastic and (ii) a multi-layered anti-reflection film provided directly or indirectly on said optical component, said film comprising at least one low refractive index film layer and at least one high refractive index film layer, said low refractive index film layer and said high refractive index film layer being laminated alternately on said optical component, said high refractive index film layer being a film of mixed metal oxides comprising tantalum oxide, zirconium oxide and yttrium oxide, deposited by evaporation process.

2. An anti-reflection optical element according to claim 1, wherein an abrasion resistance film is provided between the optical component and the multi-layered anti-reflection film.

3. An anti-reflection optical element according to claim 2, wherein a foundation layer is provided between the abrasion resistance film and the multi-layered anti-reflection film.

4. An anti-reflection optical element according to claim 2, wherein the abrasion resistance film contains an organosilicon polymer.

5. An anti-reflection optical element according to claim 1, wherein a foundation layer is provided between the optical component and the multi-layered anti-reflection film.

6. An anti-reflection optical element according to claim 5, wherein the foundation layer is a vapor-deposited film consisting of a silicon dioxide.

7. An anti-reflection optical element according to claim 1, wherein the high refractive index film layer is obtained from a mixed material comprising ZrO₂, Ta₂ O₅ and Y₂ O₃ at a molar ratio of 1:

0.8-1.5;

0.05-0.3 according to a vapor deposition method.

8. An anti-reflection optical element according to claim 1, wherein the plastic is a polyurethane obtained by polymerizing a polyisocyanate and at least one compound selected from compounds having two or more mercapto groups, compounds having two or more hydroxyl groups and compounds having one or more mercapto groups and one or more hydroxyl groups.

9. An anti-reflection optical element according to claim 8, wherein the compounds having one or more mercapto groups and one or more hydroxyl groups are each a compound having p hydroxyl groups (p is 0 or an integer of 1 or more) and q mercapto groups (q is an integer of 1 or more) wherein the sum of the number of hydroxyl groups and the number of the mercapto groups, (p+q) is 3 or more, and 6 or less carbon atoms exist between the furthest two of said groups (furthest two hydroxyl groups, furthest two mercapto groups or furthest hydroxyl and mercapto groups).

10. An anti-reflection optical element according to claim 1, wherein the plastic is a polymer of diethylene glycol bis(allyl carbonate).

11. An anti-reflection optical element according to claim 1, wherein the plastic is a copolymer of diethylene glycol bis(allyl carbonate) and at least one monomer selected from benzyl (meth)acrylate, diallyl tere- and/or isophthalate and methyl (meth)acrylate.