Bilaminate polymer coated metal strip and method for manufacture thereof

• US 5,182,141 A
• Filed: 02/13/1990
• Issued: 01/26/1993
• Est. Priority Date: 02/13/1990
• Status: Expired due to Term

• Current Assignee: Decoma International Corporation
• Original Assignee: Co-Ex-Tec Industries
• Inventors: Borys, Tadeusz, Wakefield, Earlby E. J., Lee, Shueh-Mo
• Primary Examiner(s): Thibodeau, Paul J.
• Assistant Examiner(s): Le, Hoa T.
• Application Number:
  US07/479,469
• Time in Patent Office: 1,078 Days
• Field of Search: 428/31, 428/344, 428/347, 428/349, 428/635, 428/354, 428/424.6, 156/244.1, 156/182, 156/281, 156/304.1, 156/273.3, 156/273.5, 156/315, 427/208.2, 427/407.1, 427/200, 427/372.2, 427/409, 427/379, 427/388.2
• US Class Current: 427/379
• CPC Class Codes: B32B 15/06 of natural rubber or synthetic rubber
• CPC Class Codes: B32B 15/08 of synthetic resin
• CPC Class Codes: B32B 2309/02 Temperature
• CPC Class Codes: B32B 2327/06 PVC, i.e. polyvinylchloride
• CPC Class Codes: B32B 27/304 comprising vinyl halide (co)polymers, e.g. PVC, PVDC, PVF, PVDF
• CPC Class Codes: B32B 37/1207 Heat-activated adhesive B32B37/04 takes precedence
• CPC Class Codes: B32B 7/12 using interposed adhesives or interposed materials with bonding properties
• CPC Class Codes: B60J 10/265 the surface being primarily decorative
• CPC Class Codes: B60J 10/75 for sealing the lower part of the panes
• CPC Class Codes: C09J 5/06 involving heating of the applied adhesive

Abstract

A metal substrate having a first thermosetting elastomer layer and a second thermoplastic layer, both layers being chemically bonded to the substrate, and a method of manufacture therefor. Preferably, the first layer is extruded EPDM which is bonded to the substrate by with a heat-activable polyisocyanate adhesive and the second layer is extruded PVC which is bonded to the substrate by a heat-activable modified acrylic adhesive. Flock may be chemically bonded to a portion of the EPDM. An automotive trim product is disclosed. The preferred method of manufacture is a continuous process involving the steps of applying EPDM adhesive to the substrate; heat activating the adhesive; extruding the EPDM onto the substrate; applying PVC adhesive to the substrate; heating the partially coated substrate to concomitantly activate the PVC adhesive and cure the EPDM; and then extruding the PVC onto the substrate.

Claims

1. A process for the manufacture of a bilaminate coated metal substrate comprising:

(a) preparing the metal substrate for application of adhesives thereto;

(b) applying a first activable adhesive to a first area of the substrate which is to be coated by a first layer of a thermosetting polymer;

(c) activating the adhesive to ready the substrate for application of the thermosetting polymer;

(d) applying the thermosetting polymer to the first area to form the first layer;

(e) heating the thermosetting polymer to cure it;

(f) applying a second activable adhesive to a second area of the substrate which is to be coated by a second layer of a thermoplastic polymer;

(g) activating the second adhesive; and

(h) applying the thermoplastic polymer to the second area to form the second layer whereby a bilaminate metal substrate having the first layer chemically bonded thereto and the second layer chemically bonded to the second area of the substrate is produced.

2. The process of claim 1 wherein preparing the substrate comprises cleaning the metal substrate.

3. The process of claim 1 wherein starting substrate material comprises a ribbon of aluminum, stainless steel, zinc or galvanized steel and preparing the substrate further comprises the prior step of rollforming the starting material and cleaning the substrate comprises washing the rollformed metal in an alkaline solution and rinsing the alkaline solution therefrom.

4. The process of claim 1 wherein the first adhesive is a polyisocyanate heat activable adhesive and activating the first adhesive comprises heating the adhesive to a temperature and for a length of time sufficient to activate the adhesive.

5. The process of claim 1 wherein the second adhesive is a modified acrylic adhesive and activating the second adhesive comprises heating the adhesive for a length of time sufficient to activate the adhesive.

6. The process of claim 1 wherein the thermosetting polymer is a polymer of ethylene propylene diene monomer.

7. The process of claim 1 wherein applying the thermosetting polymer and the thermoplastic polymer comprises extruding the respective polymers.

8. A process for the manufacture of a bilaminate coated metal substrate comprising:

(a) preparing the substrate for application of adhesives thereto;

(b) applying a first activable adhesive to a first area of the substrate which is to be coated by a first layer of a thermosetting polymer;

(c) activating the adhesive to ready the substrate for application of the thermosetting polymer;

(d) applying the thermosetting polymer to the first area to form the firs layer;

(e) applying a second heat activable adhesive to a second area of the substrate which is to be coated by a second layer of a thermoplastic polymer;

(f) heating the substrate obtained in step (e) to cure the thermosetting polymer and to activate the second adhesive; and

(g) applying the thermoplastic polymer to the second area whereby a bilaminate metal substrate having the first layer chemically bonded thereto and the second layer chemically bonded to the second area of the substrate is produced.

9. The process of claim 8 wherein the first adhesive is a polyisocyanate based heat-activable adhesive and the second adhesive is a modified acrylic heat-activable adhesive.

10. The process of claim 9 wherein the first adhesive is activated when exposed to a temperature from about 110°

C. to about 140°

C. for a sufficient length of time.

11. The process of claim 10 wherein the second adhesive is activated when exposed to a temperature from about 200°

C. to about 260°

C. for a sufficient length of time.

12. The process of claim 11 wherein the thermosetting polymer is a polymer of ethylene propylene diene monomer, the thermoplastic polymer is polyvinyl chloride and step (f) involves heating the substrate in a temperature range from about 200°

C. to about 260°

C.

13. The process of claim 12 wherein applying the thermosetting polymer and the thermoplastic polymer comprises extruding the respective polymers, the substrate comprises a ribbon of aluminum, stainless steel, galvanized steel or zinc metal for use in step (a) and steps (c) to (g) are carried out as a continuous process for each ribbon.

14. The process of claim 13 further comprising the subsequent steps of:

(h) applying a flock adhesive to a first area of the first polymer;

(i) curing the flock adhesive;

(j) applying flock to the first area of the first polymer to produce a bilaminate metal product; and

(k) cutting the product into suitable unit lengths.

15. The process of claim 8 further comprising the sep of applying a third adhesive to a portion of the thermosetting polymer after the step of applying the thermosetting polymer and before step (f) and wherein the third adhesive is cured during step (f) and step (g) further comprises applying the thermoplastic polymer to the portion of the thermosetting polymer to which the third adhesive has been applied.

16. The process of claim 15 wherein the first adhesive and the third adhesive have the same composition.