Polyurethane foam material free of halogenated hydrocarbons and process for producing the same

• US 5,182,309 A
• Filed: 12/21/1990
• Issued: 01/26/1993
• Est. Priority Date: 04/24/1989
• Status: Expired due to Fees

• Current Assignee: Hans W. Hutzen
• Original Assignee: Hans W. Hutzen
• Inventors: Hutzen, Hans W.
• Primary Examiner(s): WELSH JR, MAURICE
• Application Number:
  US07/635,152
• Time in Patent Office: 767 Days
• Field of Search: 521/99, 521/131, 521/107, 521/108
• US Class Current: 521/99
• CPC Class Codes: C08J 2203/14 Saturated hydrocarbons, e.g. butane; Unspecified hydrocarbons
• CPC Class Codes: C08J 2375/04 Polyurethanes
• CPC Class Codes: C08J 9/127 Mixtures of organic and inorganic blowing agents

Abstract

The present invention is related to polyurethane foam materials, pores thereof being free of halogenated hydrocarbon compounds, in particular free of CFCs, and a process for producing the same wherein no halogenated hydrocarbon, in particular no CFC is used as foaming agent. The pores of the polyurethane foam material contain minor amounts of the vaporized foaming agent used in the process of the invention, i.e. of the organic liquid product selected from the group consisting of a lower alkane having 3 to 6 carbon atoms or a mixture of such lower alkanes, said liquid foaming agent having a boiling point between -10° and =70° C. at normal pressure. In the process of the present invention said foaming agent is either finely dispersed in the mixture of the alcoholic starting component and the isocyanate starting component or said foaming agent is first emulsified in the alcoholic starting component, if necessary with the aid of an emulsifying agent, and the isocyanate component thereafter is added to this emulsion, and then the exothermic polymerization reation of the starting components is effected. Possibly, the so produced polyurethane foam material is stored for several hours or days.

Claims

1. Polyurethane insulating foam material comprising a catalyst, a pore stabilizing agent and/or a flame retardant, wherein the pores are free from halogenated hydrocarbons and contain minor amounts of a foaming agent used in the production of the foam material and selected from the group consisting of a lower alkane containing 3 to 6 carbon atoms and the mixtures of several of such lower alkanes, said foaming agent having a boiling point at normal pressure between -10°

and +70°

C., and wherein said flame retardant is selected from the group consisting of the liquid and the solid flame retardants, said flame retardant or flame retardants being present in the foam material in an amount of 5 to 35 percent by weight based upon the total weight of the final foam material.

2. The polyurethane insulating foam material according to claim 1, wherein the lower alkane is n-pentane.

3. The polyurethane insulating foam material according to claim 1, wherein the lower alkane is isopentane.

4. The polyurethane insulating foam material according to claim 1, wherein the pores additionally comprise a gas selected from the group consisting of nitrogen in an amount larger than the usual nitrogen content of air, a noble gas and the mixtures of several such gases.

5. The polyurethane insulating foam material according to claim 4, wherein the pores of the foam material comprise the noble gas argon.

6. The polyurethane insulating foam material according to claim 1, wherein the polyurethane material contains a flame retardant selected from the group of the phosphorous containing flame retardants, the boron containing flame retardants and the mixtures of several such flame retardants.

7. The polyurethane insulating foam material according to claim 1, wherein the polyurethane material contains the flame retardant or flame retardants in an amount of from 10 to 20 parts by weight based upon the total weight of the final foam material.

8. The polyurethane insulating foam material according to claim 1, wherein the polyurethane material contains an ammonium salt as solid flame retardant.

9. The polyurethane insulating foam material according to claim 1, wherein the polyurethane material contains a liquid flame retardant which is selected from the group consisting of the lower alkanol esters of lower alkane phosphonates, wherein the lower alkanol and the lower alkane group each contain 1 to 4 carbon atoms, and the mixtures of several such liquid flame retardants.

10. The polyurethane insulating foam material according to claim 9, wherein the lower alkane phosphonate contains 10 to 20 parts by weight of urea based upon the weight of the lower alkane phosponate.

11. The polyurethane insulating foam material according to claim 10, wherein the lower alkane phosphonate contains urea up to saturation.

12. Process for producing the polyurethane insulating foam material, comprising the steps of

adding to an alcoholic starting component for PUR foam material other additives selected from the group consisting of flame retardants, catalysts and pore stabilizers,

admixing and emulsifying in the alcoholic starting component a non-halogenated organic liquid product selected from the group consisting of the lower alkanes having 3 to 6 carbon atoms and the mixture of several such lower alkanes, said lower alkane or mixture of several lower alkanes having a boiling point between -10°

and +70°

C. at normal pressure,

adding to said emulsified mixture the isocyanate starting component in proportions as usual for the alcoholic starting component and the isocyanate starting component in PUR foaming materials, and

thereafter effecting the polymerization of the starting components for the PUR foam material to be produced under usual conditions.

13. Process according to claim 12, wherein the polymerization is effected with maintaining a pressure slightly above or slightly below normal pressure if it is necessary in view of the boiling point of the used liquid foaming agent.

14. Process according to claim 12, wherein the PUR foam material thus produced is stored for a period ranging from 2 days to several months, at a temperature being room temperature up to a slightly elevated temperature, and at a pressure being normal pressure down to a slightly decreased pressure.

15. Process according to claim 12, wherein the emulsion of the liquid foaming agent in the alcoholic starting component with addition of the other usual additives is effected continuously in a suitable premixer and the isocyanate component is admixed to the so produced emulsion thereafter.

16. Process according to claim 12, wherein the foaming agent is emulgated in the alcoholic starting component with admixture of the other usual additives and with further admixture of one or several emulsifying agents.

17. Process according to claim 16, wherein the emulgating agent or emulsifying agents are added in an amount of up to 10% by weight based upon the weight of the alcoholic starting component for the PUR foam material to be produced.

18. Process according to claim 16, wherein the emulsifying agent or emulsifying agents is a derivative of a fatty acid.

19. Process according to claim 12, wherein the used polymerization catalyst is selected from the group consisting of the basic catalysts known for PUR polymerization and the strongly basic catalyst known for such a reaction.

20. Process as claimed in claim 12, wherein the nonhalogenated organic liquid is n-pentane.

21. Process as claimed in claim 12, wherein the nonhalogenated organic liquid is isopentane.

22. Process as claimed in claim 12, wherein either the used liquid foaming agent or the mixture of the alcoholic starting component and the liquid foaming agent is saturated with a gas selected from the group consisting of nitrogen in an amount larger than the usual nitrogen content of air, a noble gas and the mixture of several such gases.

23. Process as claimed in claim 22, wherein the noble gas is argon.

24. Process as claimed in claim 12, wherein there is used a flame retardant selected from the group consisting of the phosphorus containing liquid flame retardants, the phosphorus containing solid flame retardants, the boron containing flame retardants and the mixtures of several such flame retardants.

25. Process as claimed in claim 24, wherein the flame retardants are added in an amount of 5 to 35 parts by weight based upon the total weight of the final foam material.

26. Process as claimed in claim 12, wherein there is added as flame retardant one or several lower alkanol esters of the lower alkane phosphonates, wherein the lower alkanol and the lower alkane group each contain 1 to 4 carbon atoms, and the mixtures of several such liquid flame retardants.

27. Process as claimed in claim 26, wherein the lower alkane phosphonate contains 10 to 20 parts by weight of urea based upon the weight of the lower alkane phosphonate.

28. Process as claimed in claim 26, wherein the lower alkane phosphonate contains urea up to saturation.