Thin film electroluminescent device

• US 5,182,491 A
• Filed: 03/17/1992
• Issued: 01/26/1993
• Est. Priority Date: 11/09/1987
• Status: Expired due to Fees

• Current Assignee: Hitachi, Ltd.
• Original Assignee: Hitachi, Ltd.
• Inventors: Sato, Akira, Hashimoto, Kenichi, Tamura, Katsumi, Abe, Yoshio, Fuyama, Moriaki, Nakayama, Takahiro, Taguchi, Kazuo, Onisawa, Kenichi
• Primary Examiner(s): Yusko, Donald J.
• Assistant Examiner(s): Horabik, Michael
• Application Number:
  US07/852,942
• Time in Patent Office: 315 Days
• Field of Search: 313/502, 313/503, 313/506, 313/509
• US Class Current: 313/503
• CPC Class Codes: H05B 33/145 Arrangements of the electroluminescent material
• CPC Class Codes: H05B 33/18 characterised by the nature or concentration of the activator
• CPC Class Codes: H05B 33/22 characterised by the chemical or physical composition or the arrangement of auxiliary dielectric or reflective layers
• CPC Class Codes: H05B 33/26 characterised by the composition or arrangement of the conductive material used as an electrode
• CPC Class Codes: H05B 33/28 of translucent electrodes

Abstract

A thin film electroluminescent (EL) device includes a pair of opposing electrodes formed on a substrate of a transparent electrical insulator, and an EL layer formed between the electrodes and covered at both surfaces with insulating layers respectively. Strontium sulfide is used as a host material of the EL layer, and its crystals tend strongly to have a (200) orientation, so that the resistance to free transit of electrons participating in emission of luminescence is substantially eliminated to ensure a higher brightness.

Claims

1. A thin film EL device comprising a substrate of a transparent electrical insulator, a first electrode formed on said substrate, an EL layer formed on said first electrode through a transparent first insulating layer interposed therebetween, a transparent second insulating layer enclosing the exposed part of said EL layer, and a second electrode formed on said second insulating layer, wherein at least one of said first and second electrodes is transparent, said EL layer contains, as its host material, strontium sulfide whose crystals strongly tend to have a (200) orientation, and the ratio of the X-ray diffraction intensity I(200)/I(111) is more than three.

2. An EL device according to claim 1, wherein said EL layer has a film thickness of 0.5 to 1.5 μ

m.

3. An EL device according to claim 1, wherein one of said first and second electrodes is transparent and is formed of ITO (indium tin oxide).

4. An EL device according to claim 3, wherein another of said first and second electrodes is formed of aluminum.

5. An EL device according to claim 1, wherein each of said first and second insulating layers is formed of SiO₂ and Ta₂ O₅.

6. An EL device according to claim 1, wherein each of said first and second insulating layers is formed of a material selected from the group consisting of SiO₂, Ta₂ O₅, Y₂ O₃, Al₂ O₃, TiO₂, SrTiO₃, Si₃ N₄ and composite material of any two of those materials.

7. An EL device according to claim 1, wherein the host material of said EL layer contains luminescent centers in an amount of 0.05 to 0.5 mol %.

8. An EL device according to claim 7, wherein said electroluminescent centers are at least one of materials selected from the group consisting of Ce, Eu, Tb, Sm, Pr, Tm, and their sulfides, chlorides and fluorides.

9. An EL device according to claim 1, wherein each of said first and second electrodes is transparent and is formed of ITO (indium tin oxide).

10. An EL device according to claim 1, wherein said first electrode is formed of ITO (indium tin oxide) and said second electrode is formed of aluminum.

11. A thin film electroluminescent device having high brightness of luminescence comprising;

a substrate made of a transparent electrical insulator;

a first electrode formed on said substrate;

a transparent first insulating layer formed on said first electrode;

an electroluminescent layer formed over said transparent first insulating layer, said electroluminescent layer comprising, as its host material, a layer of strontium sulfide having a (200) orientation stronger than the (200) orientation of strontium sulfide in a powder form, wherein a ratio of an x-ray diffraction intensity I(200)I(111) of said layer of strontium sulfide is more than three;

a transparent second insulating layer formed over and enclosing said electroluminescent layer; and

a second electrode formed on said transparent second insulating layer, wherein at least one of said first and second electrodes is transparent.