Gel-free paint containing copper pyrithione or pyrithione disulfide plus cuprous oxide

• US 5,185,033 A
• Filed: 09/01/1992
• Issued: 02/09/1993
• Est. Priority Date: 09/01/1992
• Status: Expired due to Term

• Current Assignee: OLIN Corporation
• Original Assignee: OLIN Corporation
• Inventors: Waldron, Craig, Hani, Rahim, Farmer, Jr., Douglas A.
• Primary Examiner(s): Group, Karl
• Assistant Examiner(s): Green, Anthony J.
• Application Number:
  US07/938,962
• Time in Patent Office: 161 Days
• Field of Search: 106/15.05, 106/16, 106/18.33, 106/18.34, 71/67, 514/188, 514/345, 514/499, 514/500
• US Class Current: 106/18.33
• CPC Class Codes: C09D 5/14 Paints containing biocides, e.g. fungicides, insecticides or pesticides C09D5/16 takes precedence
• CPC Class Codes: C09D 5/1612 Non-macromolecular compounds

Abstract

The present invention relates generally to paints and paint bases, and, more specifically to a process for providing a stable gel-free dispersion of copper pyrithione or pyrithione disulfide plus cuprous oxide biocide in paint. The resulting paint is storage stable and remains gel-free after several months of storage at room temperature.

Claims

1. A paint or paint base composition characterized by enhanced biocidal efficacy and gellation resistance wherein the paint or paint base contains a biocide consisting essentially of cuprous oxide and copper pyrithione or pyrithione disulfide, or a combination thereof.

2. The paint or paint base of claim 1 wherein said copper pyrithione or pyrithione disulfide is present in an amount of between about 1% and about 25%, and said cuprous oxide being present in an amount of between about 20% and about 70%, the total amount of said copper pyrithione or pyrithione disulfide plus said cuprous oxide being between about 20% and about 80%, based upon the total weight of the paint or paint base.

3. The paint or paint base of claim 1 which additionally contains a resin selected from the group consisting of vinyl, alkyl, epoxy, acrylic, polyurethane and polyester resins, and combinations thereof.

4. The paint or paint base of claim 1 which additionally contains a swelling agent selected from the group consisting of natural and synthetic clay and natural and synthetic polymer swelling agents.

5. The paint or paint base of claim 4 wherein said swelling agent is selected from the group consisting of kaolin, montomorillonite (bentonite), clay mica (muscovite), and chlorite (hectonite), and combinations thereof.

6. A process for providing a gellation-inhibited paint or paint base containing copper pyrithione or pyrithione disulfide and cuprous oxide which comprises the step of adding said copper pyrithione or pyrithione disulfide and also adding cuprous oxide to a paint or paint base to provide a paint or paint base characterized by enhanced biocidal efficacy and resistance to gellation, said copper pyrithione or pyrithione disulfide being present in an amount of between about 1% and about 25%, and said cuprous oxide being present in an amount of between about 20% and about 70%, the total amount of said copper pyrithione or pyrithione disulfide plus said cuprous oxide being between about 20% and about 80% based upon the total weight of the paint or paint base.

7. The process of claim 6 wherein the total amount of copper pyrithione or pyrithione disulfide plus said cuprous oxide is between about 20% and about 75% based upon the total weight of the paint or paint base composition.

8. The process of claim 6 wherein said composition additionally contains a resin selected from the group consisting of vinyl, alkyl, epoxy, acrylic, polyurethane and polyester resins, and combinations thereof.

9. The process of claim 6 wherein said composition additionally contains a swelling agent selected from the group consisting of natural and synthetic clay and natural and synthetic polymer swelling agents.

10. The process of claim 9 wherein said swelling agent is selected from the group consisting of kaolin, montomorillonite (bentonite), clay mica (muscovite), and chlorite (hectonite), and combinations thereof.