Multilayered tubular packaging casing

• US 5,185,189 A
• Filed: 05/28/1991
• Issued: 02/09/1993
• Est. Priority Date: 05/26/1990
• Status: Expired due to Term

• Current Assignee: Kalle Nalo GmbH & Co., KG
• Original Assignee: Hoechst Aktiengesellschaft (Sanofi )
• Inventors: Stenger, Karl, Saal, Marliese
• Primary Examiner(s): Thomas, Alexander S.
• Assistant Examiner(s): Nold, Charles R.
• Application Number:
  US07/706,362
• Time in Patent Office: 623 Days
• Field of Search: 428/34.8, 428/475.8, 428/476.1, 428/35.7, 428/36.6, 138/118.1
• US Class Current: 428/34.8
• CPC Class Codes: A22C 13/0013 Chemical composition of synthetic sausage casings
• CPC Class Codes: A22C 2013/002 made by extrusion
• CPC Class Codes: A22C 2013/0053 multilayer casings
• CPC Class Codes: A22C 2013/0083 biaxially oriented
• CPC Class Codes: B32B 1/08 Tubular products
• CPC Class Codes: B32B 2307/518 bi-axially
• CPC Class Codes: B32B 2323/04 Polyethylene
• CPC Class Codes: B32B 2323/10 Polypropylene
• CPC Class Codes: B32B 2439/70 Food packaging
• CPC Class Codes: B32B 27/08 of synthetic resin
• CPC Class Codes: B32B 27/32 comprising polyolefins comprising vinyl (co)polymers or acrylic (co)polymers B32B27/30
• CPC Class Codes: B32B 27/34 comprising polyamides
• CPC Class Codes: Y10T 428/1324 Flexible food casing [e.g., sausage type, etc.]
• CPC Class Codes: Y10T 428/1352 Polymer or resin containing [i.e., natural or synthetic]
• CPC Class Codes: Y10T 428/1379 Contains vapor or gas barrier, polymer derived from vinyl chloride or vinylidene chloride, or polymer containing a vinyl alcohol unit
• CPC Class Codes: Y10T 428/31743 Next to addition polymer from unsaturated monomer[s]
• CPC Class Codes: Y10T 428/31746 Polymer of monoethylenically unsaturated hydrocarbon

Abstract

A polyamide-based multilayered tubular packaging casing for pasty matter, in particular a synthetic sausage casing, is disclosed having an outer layer comprised of aliphatic polyamide, aliphatic copolyamide or a polymer blend comprising at least one of these compounds, an intermediate layer that is impermeable to water vapor and comprised of a polyolefin and an adhesion-promoting agent, and an inner layer that is preferably impermeable to oxygen and comprised of aliphatic and/or partially aromatic polyamides and/or aliphatic and/or partially aromatic copolyamides.

Claims

1. A multilayered, tubular packaging casing for pasty materials having an outer layer, an intermediate layer and an inner layer wherein:

said outer layer comprises a polymer selected from the group consisting of an aliphatic polyamide, an aliphatic copolyamide and a polymer blend containing at least one aliphatic polyamide or aliphatic copolyamides;

said intermediate layer comprises a polyolefin and an adhesion promoting agent, said intermediate layer having a thickness of at least about 2 microns; and

said inner layer comprises a polymer selected from the group consisting of an aliphatic polyamide, a partially aromatic polyamide, an aliphatic copolyamide, a partially aromatic copolyamide and a polymer blend containing at least one aliphatic polyamide, partially aromatic polyamide, aliphatic copolyamide, or partially aromatic copolyamide.

2. The casing as claimed in claim 1, wherein said aliphatic polyamide or copolyamide of said outer layer comprises units selected from the group consisting of an aliphatic primary diamine, an aliphatic dicarboxylic acid, an omega-aminocarboxylic acid, and a lactam of said omega-aminocarboxylic acid.

3. The casing as claimed in claim 2, wherein said aliphatic primary diamine has 4 to 8 carbon atoms.

4. The casing as claimed in claim 2, wherein said aliphatic dicarboxylic acid has 4 to 10 carbon atoms.

5. The casing as claimed in claim 2, wherein said omega-aminocarboxylic acid has 6 to 12 carbon atoms.

6. The casing as claimed in claim 3, wherein said aliphatic primary diamine comprises tetra-, penta-, hexa- or octamethylene diamine.

7. The casing as claimed in claim 4, wherein said aliphatic dicarboxylic acid comprises adipic acid, azelaic acid, sebacic acid or dodecane dicarboxylic acid.

8. The casing as claimed in claim 5, wherein said omega-aminocarboxylic acid comprises 11-amino-undecanoic acid, and the lactam of said omega-aminocarboxylic acid comprises omega-lauric lactam or caprolactam.

9. The casing as claimed in claim 1, wherein the outer layer comprises a polymer blend of polyamide and copolyamide and an additional component selected from the group consisting of polyolefins and modified polyolefins in an amount of up to 25% by weight of the outer layer.

10. The casing as claimed in claim 9, wherein said polyolefin is polyethylene.

11. The casing as claimed in claim 10, wherein said polyester is polybutylene terephthalate.

12. The casing as claimed in claim 9, wherein the additional component is a polyolefin present in an amount of up to 25% by weight of the outer layer.

13. The casing as claimed in claim 9, wherein the additional component is a modified polyolefin present in an amount of up to 25% by weight of the outer layer.

14. The casing as claimed in claim 9, wherein the additional component is selected from the group consisting of ionomers and polyesters in an amount of up to 15% by weight of the outer layer.

15. The casing as claimed in claim 9, further comprising an additional component selected from the group consisting of an ionomer and polyester in an amount of up to 15% by weight of the outer layer.

16. The casing as claimed in claim 1, wherein said polyolefin of said intermediate layer is selected from the group consisting of a homopolymer of ethylene, a homopolymer of propylene, a copolymer of linear alpha-olefins having 2 to 8 carbon atoms, and a mixture thereof.

17. The casing as claimed in claim 1, wherein said polyolefin of said intermediate layer comprises a copolymer selected from the group consisting of an ethylene/propylene copolymer, an ethylene/propylene/butylene copolymer, a propylene/butylene copolymer and a mixture thereof.

18. The casing as claimed in claim 1, wherein said adhesion promoting agent is present in the intermediate layer in an amount between about 5% to 50% by weight based on the total weight of said polyolefin and said adhesion promoting agent.

19. The casing as claimed in claim 18, wherein said adhesion promoting agent is present in the intermediate layer in an amount between about 10% to 35% by weight based on the total weight of said polyolefin and said adhesion promoting agent.

20. The casing as claimed in claim 1, wherein said adhesion promoting agent of said intermediate layer is a polyolefin resin modified by at least one functional group.

21. The casing as claimed in claim 20, wherein said functional group is selected from the group consisting of vinyl acetate, vinyl alcohol, and an ethylenically unsaturated carboxylic acid anhydride.

22. The casing as claimed in claim 1, wherein said aliphatic polyamide of said inner layer is selected from the group consisting of an aliphatic primary diamine, an aliphatic dicarboxylic acid, an omega-aminocarboxylic acid, and a lactam of said omega-aminocarboxylic acid.

23. The casing as claimed in claim 22, wherein said aliphatic primary diamine has 4 to 8 carbon atoms.

24. The casing as claimed in claim 23, wherein said aliphatic primary diamine comprises tetra-, penta-, hexa- or octamethylene diamine.

25. The casing as claimed in claim 22, wherein said aliphatic dicarboxylic acid has 4 to 10 carbon atoms.

26. The casing as claimed in claim 25, wherein said aliphatic dicarboxylic acid comprises adipic acid, azelaic acid, sebacic acid or dodecane dicarboxylic acid.

27. The casing as claimed in claim 22, wherein said omega-aminocarboxylic acid has 6 to 12 carbon atoms.

28. The casing as claimed in claim 27, wherein said omega-aminocarboxylic acid comprises 11-amino-undecanoic acid, and the lactam of said omega-aminocarboxylic acid comprises omega-lauric lactam or caprolactam.

29. The casing as claimed in claim 1, wherein said partially aromatic polyamide and/or partially aromatic copolyamide is present in said inner layer in an amount between 5% to 85% by weight based upon the combined total weight of the polymer blend in said inner layer.

30. The casing as claimed in claim 29, wherein said partially aromatic polyamide and/or partially aromatic copolyamide is present in said inner layer in an amount between 10% to 40% by weight based upon the combined total weight of the polymer blend in said inner layer.

31. The casing as claimed in claim 1, wherein said casing comprises a three-layered coextruded and biaxially stretch-oriented tubular film which optionally is also heat-set.

32. The casing as claimed in claim 1, wherein said casing has a total wall thickness between 30 and 60 μ

m, said outer layer having a thickness between 45% to 80% of said total wall thickness, said intermediate layer having a thickness between 5% to 40% of said total wall thickness, and said inner layer having a thickness between 2% and 35% of said total wall thickness.