Composition comprising encapsulated substrate with thermoplastic polymer overcoating

• US 5,187,011 A
• Filed: 01/09/1992
• Issued: 02/16/1993
• Est. Priority Date: 12/04/1989
• Status: Expired due to Fees

• Current Assignee: Exxon Research and Engineering Company (Exxon Mobil Corporation)
• Original Assignee: Exxon Research and Engineering Company (Exxon Mobil Corporation)
• Inventors: Swarup, Vijay, Geiger, Albert J., Kresge, Edward N., Drake, Evelyn N., Manalastas, Pacifico V., Thaler, Warren A., Newlove, John C., McDougall, Lee A.
• Primary Examiner(s): Stoll, Robert L.
• Assistant Examiner(s): SAYALA, CHHAYA D
• Application Number:
  US07/819,304
• Time in Patent Office: 404 Days
• Field of Search: 428/402.2, 428/402.21, 428/402.22, 428/402.24, 428/403, 428/407, 428/500, 428/517, 428/334, 427/212, 427/214, 71/6, 71/28, 71/119, 71/64.02, 71/64.07, 71/64.11, 524/547, 524/364, 525/344
• US Class Current: 428/402.24
• CPC Class Codes: C09K 8/60 Compositions for stimulating production by acting on the underground formation
• CPC Class Codes: Y10T 428/263 Coating layer not in excess of 5 mils thick or equivalent
• CPC Class Codes: Y10T 428/2989 Microcapsule with solid core [includes liposome]
• CPC Class Codes: Y10T 428/2991 Coated
• CPC Class Codes: Y10T 428/2998 including synthetic resin or polymer
• CPC Class Codes: Y10T 428/31855 Of addition polymer from unsaturated monomers
• CPC Class Codes: Y10T 428/31917 Next to polyene polymer

Abstract

An encapsulated breaker chemical composition used in an oil or gas stimulation operation which comprises: a breaker chemical; and a pinhole free coating of an ionically and covalently crosslinked neutralized sulfonated elastomeric polymer of about 2 to about 80 microns thick deposited onto the surface of the breaker chemical, wherein said polymer encapsulates the breaker chemical, wherein the polymer is permeable to the breaker chemical and the polymer is non-reactive to the breaker chemical.

Claims

1. An encapsulated particulate composition comprising:

(a) a solid particulate substrate;

(b) a coating substantially free of pinholes comprising an ionically and convalently crosslinked neutralized sulfonated elastomeric polymer having a thickness of at least about 1 micron deposited on the surface of particles of said substrate, wherein said crosslinked neutralized sulfonated polymer encapsulates said substrate, wherein said crosslinked neutralized sulfonated polymer is permeable to said substrate at conditions of use and said crosslinked neutralized sulfonated polymer is non-reactive to said substrate, and

(c) a layer of thermoplastic polymer overcoating said coating.

2. The composition of claim 1 wherein said thermoplastic polymer is a neutralized sulfonated styrene polymer.

3. The composition of claim 2 wherein the thickness of said layer of thermoplastic polymer is within the range of from about 1 to about 20 microns.

4. The composition of claim 1 wherein said crosslinked elastomeric polymer is a neutralized sulfonated EPDM terpolymer.

5. The composition of claim 1 wherein said substrate is selected from the class consisting of herbicides, fertilizers and pesticides.

6. The composition of claim 5 wherein said substrate is urea.