Flexible electrographic imaging member

• US 5,187,496 A
• Filed: 10/29/1990
• Issued: 02/16/1993
• Est. Priority Date: 10/29/1990
• Status: Expired due to Term

• Current Assignee: Xerox Corporation (Xerox Holdings Corp.)
• Original Assignee: Xerox Corporation (Xerox Holdings Corp.)
• Inventors: Yu, Robert C. U.
• Primary Examiner(s): Miller, Jr., George H.
• Assistant Examiner(s): Gibson, Randy W.
• Application Number:
  US07/604,282
• Time in Patent Office: 841 Days
• Field of Search: 346/134, 346/135.1, 428/220, 428/323, 428/332, 428/337, 428/195
• US Class Current: 346/135.1
• CPC Class Codes: G03G 5/0202 Dielectric layers for electrography
• CPC Class Codes: G03G 5/0211 obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
• CPC Class Codes: G03G 5/10 Bases for charge-receiving or other layers
• CPC Class Codes: Y10T 428/25 Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
• CPC Class Codes: Y10T 428/26 Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
• CPC Class Codes: Y10T 428/266 of base or substrate

Abstract

An electrographic imaging member including:

(a) a flexible dielectric imaging layer having a uniform thickness of between about 10 micrometers and about 50 micrometers and including a thermoplastic film forming polymer, and

(b) a flexible supporting substrate having an electrically conductive surface, the substrate including:

(1) a single substrate layer having a uniform thickness of between about 25 micrometers and about 200 micrometers and including a thermoplastic film forming polymer or

(2) dual layers comprising an inner substrate layer and an outer substrate layer, the inner substrate layer having a uniform thickness of between about 25 micrometers and about 200 micrometers and including a thermoplastic film forming polymer and the outer substrate layer having a uniform thickness of between about 10 micrometers and about 50 micrometers and including a thermoplastic film forming polymer,

wherein the linear tension force measured in any direction along the plane of the dielectric imaging layer is substantially the same as the linear tension force measured along the plane of the outer substrate layer in the same direction as the direction selected for measuring the linear tension force in the dielectric imaging layer to impart a flat shape to the electrographic imaging member. A method of using this member in an electrographic imaging process is also disclosed.

Claims

1. A flexible electrographic imaging member comprising:

(a) a flexible dielectric imaging layer having a uniform thickness of between about 10 micrometers and about 50 micrometers and comprising a thermoplastic film forming polymer wherein said dielectric imaging layer is free of photoconductive material, and

(b) a flexible supporting substrate having an electrically conductive surface, said substrate comprising a single substrate layer having a uniform thickness and between about 25 micrometers and about 200 micrometers and comprising a thermoplastic film forming polymer wherein said dielectric imaging layer and said single substrate layer have thermal coefficients of contraction that are substantially the same.

2. An electrographic imaging member according to claim 1 wherein said supporting substrate comprises a film forming binder and inorganic particles.

3. An electrographic imaging member according to claim 1 wherein a thin electrically conductive layer is interposed between said flexible supporting substrate and said dielectric imaging layer.

4. An electrographic imaging member according to claim 1 wherein said single substrate layer and has a thickness of between about 40 micrometers and about 130 micrometers.

5. An electrographic imaging member according to claim 1 wherein said single substrate layer and has a thickness of between about 50 micrometers and about 75 micrometers.

6. A flexible electrographic imaging member comprising:

(a) a flexible dielectric imaging layer having a uniform thickness of between about 10 micrometers and about 50 micrometers and comprising a thermoplastic film forming polymer, and

(b) a flexible supporting substrate having an electrically conductive surface, said substrate comprising dual layers comprising an inner substrate layer and an outer substrate layer, said inner substrate layer having a uniform thickness of between about 25 micrometers and about 200 micrometers and comprising a thermoplastic film forming polymer and said outer substrate layer having a uniform thickness of between about 10 micrometers and about 50 micrometers and comprising a thermoplastic film forming polymer, wherein said

dielectric imaging layer has a linear tension force (F_t.sbsb.1) measured along a plane of said dielectric imaging layer and said outer substrate layer

has a linear tension force (F_t.sbsb.2) measured along a plane of said outer substrate layer in a direction which is the same as for determining said linear tension force (F_t.sbsb.1), F_t.sbsb.1 minus F_t.sbsb.2 being less than about ±

20 percent with respect to F_t.sbsb.1

wherein said F_t.sbsb.1 is;

space="preserve" listing-type="equation">=(A.sub.1)(M.sub.1)[Δ

t.sub.1 (ε

.sub.1 -ε

.sub.S)]

and said F_t.sbsb.2 is;

space="preserve" listing-type="equation">=(A.sub.2)(M.sub.2)[Δ

t.sub.2 (ε

.sub.2 -ε

.sub.S)]

wherein;

A₁ is cross section of said dielectric imaging layer,

A₂ is cross section of said outer substrate layer,

M₁ is Young'"'"'s Modulus of said dielectric imaging layer,

M₂ is Young'"'"'s Modulus of said outer substrate layer,

Δ

t₁ is highest processing temperature of said dielectric imaging layer minus ambient temperature,

Δ

t₂ is highest processing temperature of said outer substrate layer minus ambient temperature,

ε

₁ is thermal coefficient of contraction of said dielectric imaging layer,

ε

_S is thermal coefficient of contraction of said inner substrate layer, and

ε

₂ is thermal coefficient of contraction of said outer substrate layer.

7. An electrographic imaging member according to claim 6 wherein said supporting substrate comprises a film forming binder and organic particles.

8. An electrographic imaging member according to claim 6 wherein said dual layers comprise an inner substrate layer having a thickness between about 40 micrometers and about 130 micrometers and an outer substrate layer having a thickness between about 13 micrometers and about 40 micrometers.

9. An electrographic imaging member according to claim 8 wherein said inner substrate layer has a uniform thickness of between about 50 micrometers and about 75 micrometers.

10. An electrographic imaging member according to claim 8 wherein said outer substrate layer has a uniform thickness of between about 16 micrometers and about 30 micrometers.

11. An electrographic imaging process comprising providing a flexible electrographic imaging member comprising a flexible dielectric imaging layer having a uniform thickness of between about 10 micrometers and about 50 micrometers and comprising a thermoplastic film forming polymer, and a flexible supporting substrate having an electrically conductive surface, said substrate comprising a single substrate layer having a uniform thickness of between about 25 micrometers and about 200 micrometers and comprising a thermoplastic film forming polymer wherein said dielectric imaging layer and said single substrate layer have thermal coefficients of contraction that are substantially the same.

12. An electrographic imaging process according to claim 11 wherein said dielectric imaging layer comprises a film forming binder and inorganic particles.

13. An electrographic imaging process according to claim 11 wherein said flexible supporting substrate comprises a film forming binder and inorganic particles.

14. An electrographic imaging process according to claim 11 wherein said flexible supporting substrate comprises a film forming binder and organic particles.

15. An electrographic imaging process according to claim 11 wherein said single substrate layer has a thickness of between about 40 micrometers and about 130 micrometers.

16. An electrographic imaging process according to claim 11 wherein said single substrate layer has a thickness of between about 50 micrometers and about 75 micrometers.

17. An electrographic imaging process comprising providing a flexible electrographic imaging member comprising dual layers comprising an inner substrate layer and an outer substrate layer, wherein said inner substrate layer has a uniform thickness of between about 25 micrometers and about 200 micrometers and said outer substrate layer has a uniform thickness of between about 10 micrometers and about 50 micrometers and comprising a thermoplastic film forming polymer, wherein said dielectric imaging layer has a linear tension force (F_t.sbsb.1) measured along a plane of said dielectric imaging layer and said outer substrate layer has a linear tension force (F_t.sbsb.2) measured along a plane of said outer substrate layer in a direction which is the same as said direction for determining said linear tension force (F_t.sbsb.1), F_t.sbsb.1 minus F_t.sbsb.2 is less than about ±

20 percent with respect to F_t.sbsb.1,

wherein said F_t.sbsb.1 is;

space="preserve" listing-type="equation">=(A.sub.1)(M.sub.1)[Δ

t.sub.1 (ε

.sub.1 -ε

.sub.2)]

and said F_t.sbsb.2 is;

space="preserve" listing-type="equation">=(A.sub.2)(M.sub.2)[Δ

t.sub.2 (ε

.sub.2 -ε

.sub.S)]

wherein;

A₁ is cross section of said dielectric imaging layer,

A₂ is cross section of said outer substrate layer,

M₁ is Young'"'"'s Modulus of said dielectric imaging layer,

M₂ is Young'"'"'s Modulus of said outer substrate layer,

Δ

t₁ is highest processing temperature of said dielectric imaging layer minus ambient temperature,

Δ

t₂ is highest processing temperature of said outer substrate layer minus ambient temperature,

ε

₁ is thermal coefficient of contraction of said dielectric imaging layer,

ε

_S is thermal coefficient of contraction of said inner substrate layer, and

ε

₂ is thermal coefficient of contraction of said outer substrate layer,

forming an electrostatic latent image on said imaging member, forming a toner image on said imaging member in conformance with said electrostatic latent image and transferring said toner image to a receiving member.

18. An electrographic imaging process according to claim 17 wherein said dielectric imaging layer comprises a film forming binder and inorganic particles.

19. An electrographic imaging process according to claim 17 wherein said dielectric imaging layer comprises a film forming binder and organic particles.

20. An electrographic imaging process according to claim 17 including forming said electrostatic latent image on said imaging member by fluid jet assisted ion projection.

21. An electrographic imaging process according to claim 17 wherein said inner substrate layer has a uniform thickness of between about 40 micrometers and about 130 micrometers and said outer substrate layer has a uniform thickness of between about 13 micrometers and about 40 micrometers and comprise a thermoplastic film forming polymer.

22. An electrographic imaging process according to claim 17 wherein said dielectric imaging layer is free of photoconductive material, said

dielectric imaging layer has a linear tension force (F_t.sbsb.1) measured along a plane of said dielectric imaging layer and said outer substrate layer has a

linear tension force (F_t.sbsb.2) measured along a plane of said outer substrate layer in a direction which is the same as said direction for determining said linear

tension force (F_t.sbsb.1), minus F_t.sbsb.2 is less than about ±

15 percent with

respect to F_t.sbsb.1.