Polycarbonate/aromatic polyester blends modified with a grafted olefin copolymer

• US 5,189,091 A
• Filed: 11/26/1990
• Issued: 02/23/1993
• Est. Priority Date: 05/04/1989
• Status: Expired due to Fees

• Current Assignee: The Dow Chemical Company (Dow, Inc.)
• Original Assignee: The Dow Chemical Company (Dow, Inc.)
• Inventors: Laughner, Michael K.
• Primary Examiner(s): Buttner, David J.
• Application Number:
  US07/617,829
• Time in Patent Office: 820 Days
• Field of Search: 525/66, 525/67, 525/92, 525/133, 525/146, 525/425, 525/439, 524/445, 524/449, 524/451, 524/456, 524/537
• US Class Current: 524/445
• CPC Class Codes: C08L 2666/02 Organic macromolecular compounds, natural resins, waxes or and bituminous materials
• CPC Class Codes: C08L 51/00 Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds for ABS polymers C08L55/02; Compositions of derivatives of such polymers
• CPC Class Codes: C08L 55/02 ABS [Acrylonitrile-Butadiene-Styrene] polymers
• CPC Class Codes: C08L 69/00 Compositions of polycarbonates; Compositions of derivatives of polycarbonates

Abstract

A polycarbonate blend of good impact strength, solvent resistance and weldline properties is prepared by admixing with polycarbonate an aromatic polyester, a grafted olefin/carbon monoxide copolymer and, optionally, an elastomeric toughening agent such as a rubber, and, optionally, a filler.

Claims

1. A composition of matter comprising, in admixture, an aromatic polycarbonate, an aromatic polyester and a grafted olefin/carbon monoxide copolymer.

2. The composition of claim 1 wherein one or more vinyl or vinylidene monomers, or mixtures thereof, are grafted onto the olefin/carbon monoxide copolymer.

3. The composition of claim 2 wherein the portion of the olefin/carbon monoxide copolymer derived from the monomer(s) or mixtures thereof, grafted to said olefin/carbon monoxide copolymer is from about 1% to about 50% by weight of said olefin/carbon monoxide copolymer.

4. The composition of claim 1 wherein one or more monomers selected from the group consisting of an acrylate, a methacrylate and an acetate are grafted onto the olefin/carbon monoxide copolymer.

5. The composition of claim 1 wherein one or more monomers selected from the group consisting of an acetate, a vinyl compound derived from acrylic acid, a vinyl aromatic compound, and a vinyl cyanide are grafted onto the olefin/carbon monoxide copolymer.

6. The composition of claim 5 wherein at least a mixture of styrene and acrylonitrile is grafted onto the olefin/carbon monoxide copolymer.

7. The composition of claim 1 or 2 wherein one or more polymers or copolymers, or mixtures thereof, polymerized from one or more vinyl or vinylidene monomers, or mixtures thereof, are grafted onto the olefin/carbon monoxide copolymer.

8. The composition of claim 7 wherein at least a styrene/acrylonitrile copolymer is grafted onto the olefin/carbon monoxide copolymer.

9. The composition of claim 1 wherein said olefin/carbon monoxide copolymer is a copolymer of ethylene and carbon monoxide.

10. The composition of claim 1 wherein the portion of the olefin/carbon monoxide copolymer derived from carbon monoxide is about 0.1% to about 40% by weight.

11. The composition of claim 1 further comprising an elastomeric toughening agent.

12. The composition of claim 11 wherein the elastomeric toughening agent is a thermoplastic elastomer or a core-shell graft copolymer, or a mixture thereof.

13. The composition of claim 11 further comprising a filler.

14. The composition of claim 13 wherein the content thereof by weight of the total composition is (a) about 9 parts to about 94 parts aromatic polycarbonate, (b) about 1 part to about 25 parts grafted olefin/carbon monoxide copolymer, (c) about 5 parts to about 90 parts aromatic polyester, (d) up to about 20 parts elastomeric toughening agent, and (e) up to about 40 parts filler.

15. The composition of claim 1, 11 or 13 in the form of a molded article.

16. The composition of claim 1, 11 or 13 in the form of an extruded sheet.

17. The composition of claim 13 wherein the filler is one or more of the filler selected from the group consisting of organic fibers, inorganic fibers and mineral fillers.

24. The composition of claim 7 wherein the portion of the olefin/carbon monoxide copolymer derived from the monomer(s), or mixtures thereof, grafted to said olefin/carbon monoxide copolymer is from about 1% to about 50% by weight of said olefin/carbon monoxide copolymer.

18. A composition of matter comprising, in admixture, an aromatic polycarbonate, a poly(alkylene phenylenedicarboxylate) and a grafted olefin/carbon monoxide copolymer.

19. A composition of matter comprising, in admixture,

(a) an aromatic polycarbonate;

(b) an aromatic polyester selected from poly(ethylene terephthalate), poly(butylene terephthalate), and a mixture thereof; and

(c) a copolymer

(i) polymerized from carbon monoxide and one or more of the monomers selected from the group consisting of ethylene, vinyl acetate and an alkyl acrylate,

onto which is grafted

(ii) one or more members of the group consisting of an alkyl acrylate, an alkyl methacrylate, vinyl acetate, a vinyl aromatic compound, a vinyl cyanide, and glycidyl methacrylate.

20. The composition of claim 19 further comprising (d) one or more of the elastomeric toughening agents selected from the group consisting of a thermoplastic elastomer and a core-shell graft copolymer.

21. The composition of claim 20 wherein the elastomeric toughening agent is one or more of the members selected from the group consisting of ethylene/propylene/diene rubber, nitrile rubber, polyisoprene, hydrogenated styrene/butadiene block copolymer, hydrogenated styrene/isoprene block copolymer, alkyl methacrylate/butadiene/styrene core-shell elastomer, and alkyl acrylate core-shell elastomer.

22. The composition of claim 19 or 20 further comprising (e) a talc filler.

23. The composition of claim 19 or 20 further comprising (e) one or more of the fillers selected from the group consisting of talc, glass, clay, mica, wollastonite, graphite, silica, aramid fibers, and metal fibers.