Ion-beam based deposition of coatings for electrochromic devices

• US 5,189,550 A
• Filed: 12/13/1991
• Issued: 02/23/1993
• Est. Priority Date: 09/11/1989
• Status: Expired due to Fees

• Current Assignee: Tufts University
• Original Assignee: Tufts University
• Inventors: Morel, Bertrand, Haas, Terry E., Arntz, Floyd O., Wong, Kwok-Keung, Goldner, Ronald B.
• Primary Examiner(s): Hille, Rolf
• Assistant Examiner(s): SAADAT, MAHSHID D
• Application Number:
  US07/787,302
• Time in Patent Office: 438 Days
• Field of Search: 359/270, 359/273, 359/275
• US Class Current: 359/273
• CPC Class Codes: C03C 17/3417 all coatings being oxide coatings
• CPC Class Codes: C23C 14/083 of refractory metals or yttrium
• CPC Class Codes: E06B 3/6722 with adjustable passage of light
• CPC Class Codes: G02F 1/1524 Transition metal compounds

Abstract

Thin film coatings for solid state storage batteries and electrochromic energy conservation devices are now formed on low temperature glass and plastic substrates by an ion-assisted RF deposition process. The attachment of such coated glass or plastic substrates to existing windows in situ allows ordinary plate glass windows in homes, office buildings and factories to be converted to "smart-windows" resulting in a substantial savings in heating and air conditioning costs.

Claims

1. An electrochromic device comprising:

a light transmissive substrate having a first layer of electrically-conductive material deposited thereon by thermal evaporation;

a layer of tungsten oxide deposited on said first layer by thermal evaporation of tungsten oxide within a stream of oxygen or argon ions;

a layer of ion conductive-electron resistive material deposited on said tungsten oxide by thermal evaporation;

a counter-electrode layer deposited on said electron resistive-ion conductive layer by thermal evaporation; and

a second layer of electrically-conductive material on said counter-electrode layer by thermal evaporation.

2. The electrochromic device of claim 1 wherein said light-transmissive substrate comprises plastic or glass.

3. The electrochromic device of claim 1 wherein said first and second electrically-conductive materials comprise indium and tin oxides.

4. The electrochromic device of claim 1 wherein said ion conductive-electron resistive layer comprises a lithiated oxide.

5. The electrochromic device of claim 1 wherein said counter-electrode layer comprises indium oxide.