Process and installation for biological treatment, e.g. by nitrification and/or denitrification, of an effluent including nitrated pollution

• US 5,192,441 A
• Filed: 09/11/1991
• Issued: 03/09/1993
• Est. Priority Date: 02/14/1989
• Status: Expired due to Fees

• Current Assignee: Omnium Detraitements et Devalorisation
• Original Assignee: Omnium Detraitements et Devalorisation
• Inventors: Sibony, Jacques, Desbos, Gilbert
• Primary Examiner(s): Silverman, Stanley S.
• Assistant Examiner(s): Upton, Christopher
• Application Number:
  US07/759,146
• Time in Patent Office: 545 Days
• Field of Search: 210/603, 210/605, 210/616, 210/625, 210/626, 210/630, 210/903, 210/151, 210/195.3, 210/204, 210/205, 210/208, 210/219, 210/220, 210/259, 210/631
• US Class Current: 210/603
• CPC Class Codes: B01D 21/00 Separation of suspended solid particles from liquids by sedimentation separation of ores or the like by sedimentation B03B5/48 - B03B5/60 ; differential sedimentation B03D3/00; purification of water, waste water, sewage or sludge C02F, e.g. devices for separating or removing fatty or oily substances or similar floating material from water, waste water or sewage C02F1/40
• CPC Class Codes: B01D 21/0039 Settling tanks provided with contact surfaces, e.g. baffles, particles
• CPC Class Codes: B01D 21/0045 Plurality of essentially parallel plates
• CPC Class Codes: B01D 21/2488 bringing about a partial recirculation of the liquid, e.g. for introducing chemical aids
• CPC Class Codes: B01D 21/26 Separation of sediment aided by centrifugal force or centripetal forcecentrifuges B04B; cyclones B04C
• CPC Class Codes: C02F 1/36 ultrasonic vibrations
• CPC Class Codes: C02F 1/385 by centrifuging suspensions centrifuges B04B
• CPC Class Codes: C02F 2303/24 Separation of coarse particles, e.g. by using sieves or screens
• CPC Class Codes: C02F 3/085 Fluidized beds
• CPC Class Codes: C02F 3/10 Packings; Fillings; Grids packing elements in general B01J19/30, B01J19/32
• CPC Class Codes: C02F 3/2806 Anaerobic processes using solid supports for microorganisms
• CPC Class Codes: Y02W 10/10 Biological treatment of water, waste water, or sewage
• CPC Class Codes: Y10S 210/903 Nitrogenous

Abstract

A process for the biological treatment by nitrification and/or denitrification of an effluent containing nitrogen pollution includes the following steps:

an incident flow of this water is brought into a mixing zone with at least one compartment in which, by turbulent mechanical agitation, an inconsumable and insoluble granular material, loaded with biomass, is put in homogeneous suspension in this water, and is maintained at a more or less constant mass concentration;

this water and this granular material in suspension are circulated in a separation zone from which is extracted on the one hand clarified water, and on the other hand biomass loaded granular material; and

almost all of the active biomass fixed on said granular material is brought back by forced recycling to the mixing zone.

Claims

1. A method for biological treatment of sewage effluent water containing nitrogen pollution, comprising:

bringing an incident flow of said sewage into a mixing zone with at least one compartment and effecting, by high turbulent mechanical agitation within said compartment, homogeneous suspension of a substantially unconsumable and insoluble granular material in a concentration of at least about 5 g/l, loaded with biomass in a concentration of less than 1 g/liter, in said sewage, and maintaining a generally constant mass concentration in said homogeneous suspension;

circulating said sewage and said granular material in suspension to a separation zone and decanting clarified water from the granular material loaded with active biomass using laminar flow decantation; and

effecting forced and direct recycling of at least 75% of the active biomass fixed to said granular material to the mixing zone.

2. The method according to claim 1, wherein the nitrogen pollution is in the form of ammonium hydroxide, oxygen is further injected into the mixing zone in an amount sufficient to encourage the development of a biomass which consumes the pollution contained in the sewage to be treated.

3. The method according to claim 2, wherein said oxygen is injected in the form of air.

4. The method according to claim 1, wherein the nitrogen pollution is in the form of nitrate, a source of organic carbon is also injected into this mixing zone and said mixing zone is maintained as an anaerobic environment.

5. The method according to claim 1, the nitrogen pollution being in organic form or in the form of ammonium hydroxide, the mixing zone comprising in series an aerobic nitrification zone in which said homogeneous suspension is effected by said turbulent mechanical agitation and into which oxygen is injected and downstream thereof an anaerobic denitrification zone into which said homogeneous suspension is entered and maintained by a second turbulent mechanical agitation and into which a source of organic carbon is injected, said forced and direct recycling being effected to said aerobic nitrification zone.

6. The method according to claim 1, wherein the nitrogen pollution is in organic form or in the form of ammonium hydroxide, the mixing zone comprises in series an anaerobic denitrification zone in which said homogeneous suspension is effected by said turbulent mechanical agitation then an aerobic nitrification zone into which said homogeneous suspension is entered and maintained by a second turbulent mechanical agitation and into which oxygen is injected, and water loaded with granular material leaving the aerobic nitrification zone is recycled towards the anaerobic denitrification zone with a flow at least equal to the incident flow of sewage, said forced and direct recycling from said separation zone being effected to said anaerobic denitrification zone.

7. The method according to claim 1, wherein the granular material that is put in a homogeneous suspension is fine sand.

8. The method according to claim 1 wherein the granular material contained in a non-recycled residual part of the granular material extracted with sludges from the separation zone is recovered by separation and re-injected together with fixed biomass into the mixing zone, and sludges separated from this granular material are drained off.

9. The method according to claim 1, wherein the concentration of granular material in the mixing zone is maintained approximately at a value of between 5 and 100 g/l.

10. The method according to claim 9, characterized in that the concentration of granular material when it is fine sand is maintained at a value of between 5 and 50 g/l.

11. The method according to claim 1, wherein the turbulent agitation causes an internal recycling of between 5 and 100 times the incident sewage.

12. The method according to claim 11 wherein the suspension is returned to the mixing zone by forced recycling in a flow amounting to between 100 and 500% of the incident flow of sewage.

13. The method according to claim 1 wherein said forced and direct recycling is effected upstream of the mixing zone.

14. The method according to claim 1, wherein the homogeneous suspension is left to degas before being passed into the separation zone.

15. Installation for biological treatment of a pre-treated sewage effluent water containing a nitrogen pollution comprising:

a mixing zone with at least one compartment provided with a pipe means for admitting water to be treated and a mechanical means for high turbulent agitation within said compartment, said mixing zone containing a substantially unconsumable and insoluble granular material in a concentration of at least about 5 g/l loaded with fixed biomass in a concentration of less than about 1 g/l forming a homogeneous suspension;

a separation zone downstream of the mixing zone provided with an inlet for said homogeneous suspension and with a first channel means for draining off clarified water and a second channel means for draining off the granular material loaded with fixed biomass, said separation zone including a lamellar decantation device; and

a recycling pipe fitted with a pumping means for pumping said granular material loaded with fixed biomass, said recycling pipe connecting the second channel means and the mixing zone.

16. Installation according to claim 15, wherein the mixing zone includes a mixing reactor containing oxygenation means.

17. Installation according to claim 16, wherein the oxygenation means are formed by an oxygenation manifold.

18. Installation according to claim 15, wherein the mixing zone comprises in series an aerobic nitrification reactor provided with said mechanical means for turbulent agitation and including an oxygen input and an anaerobic denitrification reactor provided with a second mechanical means for turbulent agitation and including an organic carbon inlet pipe, said recycling pipe connecting said second channel to said aerobic nitrification reactor.

19. Installation according to claim 15, wherein the mixing zone comprises in series an anaerobic denitrification reactor provided with said mechanical means for turbulent agitation, then an aerobic nitrification reactor provided with a second mechanical means for turbulent agitation and with an oxygen input, a second recycling pipe being connected between the exit of the aerobic nitrification reactor and the anaerobic denitrification reactor, said recycling pipe connecting said second channel to said anaerobic denitrification reactor.

20. Installation according to claim 15, wherein the mechanical means for turbulent agitation comprise an agitator.

21. Installation according to claim 20, wherein this agitator comprises blades offset along a drive shaft and shaped in such a way as to cause flows in opposite directions along this shaft.

22. Installation according to claim 20, wherein this agitator is positioned vertically.

23. Installation according to claim 15, wherein the granular material is fine sand.

24. Installation according to claim 15, wherein said homogeneous suspension has a concentration of between 5 and 100 g/l. of said granular material in the form of fine sand loaded with fixed biomass.

25. Installation according to claim 15, wherein said homogeneous suspension has a concentration of between 5 and 50 g/l. of said granular material in the form of fine sand loaded with fixed biomass.

26. Installation according to claim 15, wherein the granular material has a granulometry of between 20 and 500 μ

m.

27. Installation according to claim 26, wherein the granular material is sand of a granulometry of between 80 and 200 μ

m.

28. Installation according to claim 15, further comprising a recovery/separation line starting from the loaded granular material drainage channel downstream of the recycling pipe and ending at a biomass loaded granular material re-injection pipe ending into or upstream of the mixing zone.

29. Installation according to claim 28, wherein the recovery line includes at least one hydrocyclone (D).

30. Installation according to claim 15, further comprising a degassing zone between the mixing zone and the separation zone.

31. A method for biological treatment of sewage effluent water containing nitrogen pollution, comprising:

bringing an incident flow of said sewage into a mixing zone with at least one compartment and effecting, by high turbulent mechanical agitation within said compartment, homogeneous suspension of a substantially unconsumable and insoluble granular material in a concentration of at least about 5 g/l, loaded with biomass in a concentration of less than about 1 g/l, in said sewage, and maintaining a generally constant mass concentration in said homogeneous suspension;

circulating said sewage and said granular material in suspension to a separation zone and extracting, using laminar flow decantation, clarified water from the granular material loaded with active biomass; and

effecting forced and direct recycling of at least 90% of the active biomass fixed to said granular material to the mixing zone.

32. A method according to claim 31 wherein substantially all of said active biomass fixed to said granular material is recycled to the mixing zone.

33. A method for biological treatment of sewage effluent water containing nitrogen pollution, comprising:

bringing an incident flow of said sewage into a mixing zone with at least one compartment and effecting, by turbulent mechanical agitation within said mixing zone compartment, homogeneous suspension of a substantially unconsumable and insoluble granular material, loaded with biomass, in a concentration of less than about 1 g/l, in said sewage, and maintaining a generally constant mass concentration in said homogeneous suspension while providing sufficient turbulence to effect an internal recycling of at least 10 times the feed rate of said incident flow of sewage;

circulating said sewage and said granular material in suspension in a separation zone including lamellar decantation elements and extracting by laminar flow decantation clarified water and the granular material loaded with active biomass; and

effecting forced and direct recycling of at least 75% of the active biomass fixed to said granular material to the mixing zone;

said granular material being sand having a granulometry of between 80 and 200 μ

m at a mass concentration in said homogeneous suspension of between 5 and 50 g/l.

34. A method according to claim 33, wherein said high turbulent agitation is sufficient to effect an internal recycling of between 10 and 100 times the feed rate of said incident flow of sewage, and wherein said recycling of the active biomass fixed to said granular material to the mixing zone is in an amount between 100% and 500% of the incident flow of said sewage into the mixing zone.

35. A method for biological treatment of sewage effluent water containing nitrogen pollution in organic form or in the form of ammonium hydroxide, comprising:

bringing an incident flow of said sewage into a first zone and effecting, by high turbulent mechanical agitation in said first zone, an homogeneous suspension of a substantially unconsumable and insoluble granular material in a concentration of at least about 5 g/l loaded with biomass in a concentration of less than about 1 g/l in said sewage and maintaining a generally constant mass concentration in said homogeneous suspension while effecting a first biological treatment;

circulating said homogeneous suspension into a second zone maintaining said suspension homogeneous by a second high turbulent mechanical agitation in said second zone while effecting a second biological treatment;

circulating said suspension from said second zone to a separation zone containing lamellar decantation elements and extracting by laminar flow clarified water and the granular material loaded with active biomass; and

effecting forced and direct recycling of at least 75% of active biomass fixed to said granular material to said first zone.

36. A method according to claim 35, wherein said first zone is an aerobic nitrification zone and said second zone is an anaerobic denitrification zone, said method comprising injecting oxygen into said aerobic nitrification zone and injecting a source of organic carbon into said anaerobic denitrification zone, and further comprising recycling a part of said homogeneous suspension from said anaerobic denitrification zone into said anaerobic nitrification zone with a flow at least equal to the incident flow of sewage.

37. A method according to claim 35, wherein said first zone is an anaerobic denitrification zone and said second zone is an aerobic nitrification zone, and comprising injecting a source of organic carbon into said anaerobic denitrification zone, injecting oxygen into said aerobic nitrification zone, and recycling a part of said homogeneous suspension from said aerobic nitrification zone to said anaerobic denitrification zone with a flow at least equal to the incident flow of sewage.

38. An apparatus for biological treatment of a pre-treated sewage effluent water containing a nitrogen pollution, comprising:

a mixing zone with at least one compartment provided with a pipe means for admitting water to be treated and a mechanical means for high turbulent agitation within said compartment, said mixing zone containing a substantially unconsumable and insoluble granular material loaded with fixed biomass in a concentration of less than about 1 g/l forming a homogeneous suspension;

a separation zone downstream of the mixing zone provided with an inlet for said homogeneous suspension and fitted with a first channel means for draining off clarified water and a second channel means for draining off the granular material loaded with fixed biomass, said separation zone including lamellar decanting elements; and

a recycling pipe fitted with a pumping means for pumping said granular material loaded with fixed biomass, said recycling pipe connecting the second channel means and the mixing zone;

said granular material being sand having a granulometry of between 80 and 200 μ

m at a mass concentration in said homogeneous suspension of between 5 and 50 g/l.

39. An apparatus for biological treatment of a pre-treated sewage effluent water containing a nitrogen pollution, comprising:

an aerobic nitrification reactor provided with a pipe means for inlet of water to be treated, with means for feeding oxygen therewithin and with a first mechanical means for high turbulent agitation therewithin, said aerobic nitrification reactor containing a substantially unconsumable and insoluble granular material in a concentration of at least about 5 g/l loaded with fixed biomass in a concentration of less than about 1 g/l forming a homogeneous suspension;

an anaerobic denitrification reactor connected to exit of said aerobic nitrification for circulation of said suspension, provided with a second mechanical means for turbulent agitation therewithin and with an organic carbon inlet pipe;

a separation zone downstream of said anaerobic denitrification reactor, provided with an inlet for said suspension and with a first channel means for draining off clarified water and a second channel means for draining off said granular material loaded with fixed biomass; and

a recycling pipe provided with a pumping means for pumping said granular material loaded with fixed biomass, said recycling pipe connecting said second channel means to said aerobic nitrification reactor.

40. An apparatus for biological treatment of a pre-treated sewage effluent water containing a nitrogen pollution, comprising:

an anaerobic denitrification reactor provided with a pipe means for inlet water to be treated and with a first mechanical means for turbulent agitation therewithin, said anaerobic denitrification reactor containing a substantially unconsumable and insoluble granular material in a concentration of at least about 5 g/l loaded with fixed biomass in a concentration of less than about 1 g/l forming a homogeneous suspension;

an aerobic nitrification reactor connected to said anaerobic denitrification for circulation of said suspension, provided with an oxygen feeding input and with a second mechanical means for turbulent agitation therewithin;

a first recycling pipe between exit of said aerobic nitrification reactor and said anaerobic denitrification reactor;

a separation zone downstream of said aerobic nitrification reactor, provided with an inlet for said suspension, with a first channel means for draining off clarified water and with a second channel means for draining off said granular material loaded with fixed biomass; and

a second recycling pipe provided with pumping means for pumping said granular material loaded with fixed biomass, said second recycling pipe connecting said second channel means to said anaerobic denitrification reactor.