Method for creating a corrosion-resistant aluminum surface

• US 5,194,138 A
• Filed: 07/20/1990
• Issued: 03/16/1993
• Est. Priority Date: 07/20/1990
• Status: Expired due to Fees

• Current Assignee: University of Southern California
• Original Assignee: University of Southern California
• Inventors: Mansfeld, Florian B., Shih, Hong, Wang, You
• Primary Examiner(s): Woo, Jay H.
• Assistant Examiner(s): Mackey, James P.
• Application Number:
  US07/556,109
• Time in Patent Office: 970 Days
• Field of Search: 148/241, 148/272, 148/273, 148/275, 204/38.1, 205/183
• US Class Current: 205/183
• CPC Class Codes: C23C 22/56 Treatment of aluminium or alloys based thereon

Abstract

A method for treating the surface of an aluminum-based material so as to make the surface resistant to corrosion includes the steps of contacting the surface with an aqueous cerium non-halide solution and then contacting the surface with an aqueous cerium halide solution. These steps may optionally be followed by a step of positively charging the metal surface while in contact with an aqueous molybdenum solution.

Claims

1. A method for treating the surface of an aluminum-based material so as to make the surface resistant to corrosion, comprising the steps of:

(a) contacting the surface with an aqueous cerium non-halide solution for at least about 1 hour, the cerium non-halide solution having a pH of between about 4 and about 7 and being at a temperature of at least about 80°

C.; and

(b) contacting the metal surface from step (a) with an aqueous solution consisting essentially of a cerium halide for at least about 1 hour, the cerium halide solution having a pH of between about 4 and about 7 and being at a temperature of at least about 80°

C.

2. The method of claim 1 wherein the aqueous cerium non-halide solution comprises nitrate ions.

3. The method of claim 1 wherein the aqueous cerium non-halide solution consists essentially of cerium nitrate.

4. The method of claim 1 wherein the surface is contacted with the aqueous cerium non-halide solution for at least about 1.5 hours.

5. The method of claim 1 wherein the surface is contacted with the aqueous cerium non-halide solution for at least about 2 hours.

6. The method of claim 1 wherein the pH of the cerium non-halide solution is between about 4.5 and about 5.5.

7. The method of claim 1 wherein the temperature of the cerium-non-halide solution is at least about 90°

C.

8. The method of claim 1 wherein the temperature of the cerium non-halide solution is at least about 98°

C.

9. The method of claim 1 wherein the cerium non-halide solution is at its boiling point.

10. The method of claim 1 wherein the aqueous cerium halide solution comprises chloride ions.

11. The method of claim 1 wherein the surface is contacted with the aqueous cerium halide solution for at least about 1.5 hours.

12. The method of claim 1 wherein the surface is contacted with the aqueous cerium halide solution for at least about 2 hours.

13. The method of claim 1 wherein the pH of the cerium halide solution is between about 4.5 and about 6.

14. The method of claim 1 wherein the temperature of the cerium -halide solution is at least about 90°

C.

15. The method of claim 1 wherein the temperature of the cerium halide solution is at least about 98°

C.

16. The method of claim 1 wherein the cerium halide solution is at its boiling point.

17. The method of claim 1 comprising the additional step of, after contacting the surface with the cerium non-halide and cerium halide solutions, positively charging the surface while contacting the surface with an aqueous molybdenum solution.

18. The method of claim 17 wherein the aqueous molybdenum solution contains molybdate ions.

19. The method of claim 17 wherein the surface is charged to a potential within the passive region of the aluminum-based material.

20. The method of claim 19 wherein the charge on the surface is between about 300 and about 800 mV above the corrosion potential of the material.

21. The method of claim 19 wherein the surface is charged between about 400 mV and about 600 mV above the corrosion potential of the material.

40. The method of claims 1 or 22 wherein the surface consists essentially of aluminum.

41. The method of claims 13 or 22 wherein the surface comprises an aluminum metal matrix composite.

42. The method of claims 1 or 35 comprising the further steps of, prior to performing step (a), removing metal oxides from the surface and then reoxidizing the metal surface to create a uniform aluminum oxide layer on the surface.

22. A method for treating a surface of an aluminum-based material so as to make the surface resistant to corrosion, comprising the steps of:

(a) contacting the surface with an aqueous cerium non-halide solution for at least about 1 hours, the cerium non-halide solution having a pH of between about 4 and about 7 and being at a temperature of at least about 80°

C.;

(b) contacting the surface from step (a) with an aqueous solution consisting essentially of a cerium halide for at least about 1 hour, the cerium halide solution having a pH of between about 4 and about 7 and being at a temperature of at least about 80°

C.; and

(c) positively charging the metal surface from step (b) while contacting the surface with an aqueous molybdenum solution.

23. The method of claim 27 wherein the aqueous cerium non-halide solution comprises cerium nitrate.

24. The method of claim 27 wherein the surface is contacted with the aqueous cerium non-halide solution for at least about 1.5 hours.

25. The method of claim 22 wherein the surface is contacted with the aqueous cerium non-halide solution for at least about 2 hours.

26. The method of claim 22 wherein the pH of the cerium non-halide solution is between about 4.5 and about 5.5.

27. The method of claim 22 wherein the temperature of the cerium non-halide solution is at least about 90°

C.

28. The method of claim 22 wherein the temperature of the cerium on-halide solution is at least about 98°

C.

29. The method of claim 22 wherein the cerium non-halide solution is at its boiling point.

30. The method of claim 22 wherein the aqueous cerium halide solution comprises cerium chloride.

31. The method of claim 22 wherein the surface is contacted with the aqueous cerium halide solution for at least about 1.5 hours.

32. The method of claim 22 wherein the surface is contacted with the aqueous cerium halide solution for at least about 2 hours.

33. The method of claim 22 wherein the pH of the cerium halide solution is between about 4.5 and about 6.

34. The method of claim 22 wherein the temperature of the cerium halide solution is at least about 90°

C.

35. The method of claim 22 wherein the temperature of the cerium halide solution is at least about 98°

C.

36. The method of claim 22 wherein the cerium halide solution is at its boiling point.

37. The method of claim 22 wherein the surface is charged to a potential within the passive region of the aluminum-based material.

38. The method of claim 22 wherein the charge on the surface is between about 300 and about 800 mV.

39. The method of claim 22 wherein the surface is charged between about 400 mV and about 600 mV.