Silicone rubber composition and its manufacture

• US 5,194,479 A
• Filed: 03/28/1991
• Issued: 03/16/1993
• Est. Priority Date: 03/29/1990
• Status: Expired due to Term

• Current Assignee: Shin-Etsu Chemical Company Limited
• Original Assignee: Shin-Etsu Chemical Company Limited
• Inventors: Nakamura, Tsutomu, Takahashi, Masaharu, Omura, Naoki
• Primary Examiner(s): Marquis, Melvyn I.
• Assistant Examiner(s): Dean, Karen A.
• Application Number:
  US07/676,437
• Time in Patent Office: 719 Days
• Field of Search: 524/861, 524/863, 524/588, 524/422, 524/401
• US Class Current: 524/401
• CPC Class Codes: C08G 77/12 containing silicon bound to hydrogen C08G77/045 takes precedence
• CPC Class Codes: C08G 77/20 containing silicon bound to unsaturated aliphatic groups C08G77/045 takes precedence
• CPC Class Codes: C08G 77/24 halogen-containing groups
• CPC Class Codes: C08G 77/26 nitrogen-containing groups
• CPC Class Codes: C08G 77/70 Siloxanes defined by use of the MDTQ nomenclature
• CPC Class Codes: C08K 13/02 Organic and inorganic ingredients
• CPC Class Codes: C08K 3/16 Halogen-containing compounds
• CPC Class Codes: C08K 3/30 Sulfur-, selenium- or tellurium-containing compounds
• CPC Class Codes: C08L 2666/54 Inorganic substances
• CPC Class Codes: C08L 83/00 Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
• CPC Class Codes: C08L 83/04 Polysiloxanes

Abstract

A silicone rubber composition comprising: (A) a diorganopolysiloxane, (B) a reinforcing filler, (C) an acid strength adjustor, and (D) a curing agent, wherein the extract water pH is in the range of 3.0 to 5.5, said extract water pH being defined in such a way that when 50 g of a toluene solution containing 5.0% by weight of said rubber composition is subjected to extraction with 10 g of deionized water, the pH of the resulting water is defined as the extract water pH. The cured product of said composition is good in extension fatigue resistance and flex fatigue resistance.

Claims

1. A silicone rubber composition comprising:

(A) a diorganopolysiloxane having the following average composition formula [I];

##EQU5## wherein R'"'"'s which may be the same or different, each represent an unsubstituted or substituted monovalent hydrocarbon group having 1 to 10 carbon atoms and a is a number of from 1.95 to 2.05,

and possessing an average degree of polymerization in the range of 3,000 to 30,000,

(B) a reinforcing filler,

(C) hydrochloric acid or sulfuric acid as an acid strength adjustor, and

(D) a curing agent,

said silicone rubber composition is further characterized such that when 50 g of a tolune solution containing 5.0% by weight of said rubber composition is extracted with 10 g of deionized water forming an organic phase and a water phase, the pH of the water phase thus extracted is in the range of 3.0 to 5.5.

2. A composition as claimed in claim 1, wherein out of all R'"'"'s in formula [I], 98 mol % or more comprise alkyl groups having 1 to 4 carbon atoms.

3. A composition as claimed in claim 1, wherein the reinforcing filler (B) comprises a reinforcing silica.

4. A composition as claimed in claim 1, wherein the curing agent (D) is an organic peroxide.

5. A composition as claimed in claim 1, wherein the diorganopolysiloxane (A) has an alkenyl group, and the curing agent (D) is a combination of an organohydrogenpolysiloxane and a platinum family metal catalyst.

6. A composition as claimed in claim 1, wherein the reinforcing filler (B) is blended in an amount of 10 to 100 parts by weight per 100 parts by weight of the diorganopolysiloxane (A).

7. A composition as claimed in claim 1, wherein said extract water pH is 3.5 to 4.8.

8. A process for producing a silicone rubber composition as claimed in claim 1 comprising the steps of mixing said diorganopolysiloxane (A), said filler (B), and said acid strength adjustor (C), heat-treating the mixture at 100°

to 200 °

C., and mixing said heat-treated mixture with said curing agent (D).

9. A cured product obtained by curing a composition as claimed in claim 1.