Method and apparatus for measuring the fouling potential of membrane system feeds

• US 5,198,116 A
• Filed: 02/10/1992
• Issued: 03/30/1993
• Est. Priority Date: 02/10/1992
• Status: Expired due to Term

• Current Assignee: D.W. Walker & Associates, Inc.
• Original Assignee: D.W. Walker & Associates, Inc.
• Inventors: Comstock, Daniel L., Durham, Lee A.
• Primary Examiner(s): Dawson, Robert A.
• Assistant Examiner(s): DRODGE, JOSEPH W
• Application Number:
  US07/832,941
• Time in Patent Office: 414 Days
• Field of Search: 73/61.63, 73/61.64, 210/85, 210/87, 210/96.1, 210/96.2, 210/106, 210/108, 210/193, 210/194, 210/198.1, 210/321.6, 210/321.69, 210/321.65, 210/321.84, 210/500.41, 210/636 , 210/639, 210/739, 210/746, 210/791, 210/709, 210/257.2, 210/258, 340/607, 422/68.1, 422/82.01, 436/178, 436/806, 204/153.1
• US Class Current: 210/636
• CPC Class Codes: B01D 2311/04 Specific process operations in the feed stream; Feed pretreatment
• CPC Class Codes: B01D 2311/12 Addition of chemical agents
• CPC Class Codes: B01D 2311/25 Recirculation, recycling or bypass, e.g. recirculation of concentrate into the feed
• CPC Class Codes: B01D 2321/16 Use of chemical agents
• CPC Class Codes: B01D 2321/167 Use of scale inhibitors
• CPC Class Codes: B01D 61/025 Reverse osmosis; Hyperfiltration
• CPC Class Codes: B01D 61/04 Feed pretreatment
• CPC Class Codes: B01D 65/02 Membrane cleaning or sterilisation ; Membrane regeneration
• CPC Class Codes: B01D 65/08 Prevention of membrane fouling or of concentration polarisation

Abstract

The optimum antifoulant concentration and cleaning interval for reverse osmosis membranes is determined by providing samples of a liquid to be purified in a reverse osmosis system, the samples having a range of antifoulant concentrations added. The zeta potential for each sample is measured, and the amount of antifoulant that provides the lowest (most negative) zeta potential is selected as the preferred antifoulant concentration. A cleaning frequency sample of the liquid to be purified with the preferred antifoulant concentration is prepared and passed across a cleaning frequency membrane that passes dissolved matter in the permeate but does not pass colloidal material. The rate of change in flow of the permeate of the cleaning frequency sample is measured as a function of time, and the cleaning frequency of the cleaning frequency sample is determined. In one embodiment, the cleaning frequency membrane used in the testing is comparable to the filter support used in the reverse osmosis system, but has no separation membrane thereon. A test cell for measuring permeation through the cleaning frequency membrane is provided.

Claims

1. A method of determining the optimum cleaning approach for a reverse osmosis membrane, comprising the steps of:

providing a set of samples of a liquid to be purified in a reverse osmosis system, the samples having a range of antifoulant concentrations added;

measuring the zeta potential for each sample; and

selecting the concentration of antifoulant that provides the lowest (most negative) zeta potential as the preferred antifoulant concentration and determining the optimum cleaning approach for a reverse osmosis membrane in response to a parameter measured by passing a sample having said preferred antifoulant concentration through a membrane.

2. The method of claim 1, wherein the liquid is water.

3. The method of claim 1, wherein the method contains the additional steps, after the step of selecting, of

preparing a cleaning frequency sample of the liquid to be purified with the preferred antifoulant concentration;

passing the cleaning frequency sample in a cross flow manner across a cleaning frequency membrane that passes dissolved matter in the permeate but does not pass colloidal material; and

measuring the rate of change in flow of the permeate of the cleaning frequency sample as a function of time.

4. The method of claim 3, including the additional step, after the step of measuring, of

determining the cleaning frequency of the cleaning frequency sample from the rate of change in flow as a function of time.

5. The method of claim 3, wherein the step of passing is accomplished using apparatus comprising

means for supplying a flow of a liquid to be purified by reverse osmosis;

and

a test cell having

a cleaning frequency membrane,

an inlet for introducing a flow of the liquid to be purified to a first side of the cleaning frequency membrane,

a concentrate outlet on the first side of the cleaning frequency membrane arranged so that the flow of liquid passes over the first side of the cleaning frequency membrane in flowing from the inlet to the concentrate outlet, and

a permeate outlet on a second side of the cleaning frequency membrane.

6. A method of determining the optimum antifoulant concentration and cleaning interval for a reverse osmosis membrane, comprising the steps of:

providing samples of a liquid to be purified in a reverse osmosis system, the samples having a range of antifoulant concentrations added;

measuring the zeta potential for each sample;

selecting the preferred concentration of antifoulant as that which provides the lowest zeta potential;

preparing a cleaning frequency sample of the liquid to be purified with the preferred antifoulant concentration;

passing the cleaning frequency sample across one side of a membrane, so that a fraction of the cleaning frequency sample passes through the membrane as a permeate, the membrane being selected such that it passes dissolved matter in the permeate but does not pass colloidal material;

measuring the rate of change in flow of the permeate of the cleaning frequency sample through the membrane as a function of time; and

determining the cleaning frequency of the cleaning frequency sample from a preexisting correlation, using the rate of change in flow of the permeate as a function of time.

7. A method of determining the cleaning interval for a reverse osmosis membrane having molecular sieve layer, comprising the steps of:

providing a cleaning frequency sample of a reverse osmosis feed liquid;

passing the sample across one side of a cleaning frequency membrane, so that a fraction of the cleaning frequency sample passes through the cleaning frequency membrane as a permeate, the cleaning frequency membrane being selected such that it passes dissolved matter in the permeate but does not pass colloidal material at a rate relatively rapid compared to said sample being passed through said reverse osmosis membrane;

measuring the rate of change in flow of the permeate of the sample through the membrane as a function of time; and

determining the cleaning frequency of the reverse osmosis membrane, the reverse osmosis membrane comprising the same membrane material as used in the cleaning frequency membrane of the step of passing, from the rate of change in flow of the permeate as a function of time.

8. Apparatus for use in determining the required cleaning frequency for a reverse osmosis filter element, comprising:

means for supplying a flow of a liquid capable of being purified by a reverse osmosis membrane having a molecular sieve layer; and

a test cell having

a cleaning frequency membrane constructed and arranged to pass dissolved matter in a permeate but to not pass colloidal material at a rate relatively rapid compared to said liquid being purified by the reverse osmosis membrane,

an inlet on a first side of the cleaning frequency membrane for introducing a flow of the liquid to be purified to a first side of the cleaning frequency membrane,

a concentrate outlet on the first side of the cleaning frequency membrane disposed so that the flow of liquid introduced from the inlet contacts the first side of the cleaning frequency membrane in flowing to the concentrate outlet, and

a permeate outlet on a second side of the cleaning frequency membrane.

9. The apparatus of claim 8, wherein the cleaning frequency membrane includes a layer of a polysulfone.

10. The apparatus of claim 8, wherein the cleaning frequency membrane of the test cell is in the form of a flat plate.

11. The apparatus of claim 8, wherein the means for supplying includes

a constant temperature feed supply, and

a pump that pumps liquid from the feed supply to the inlet of the test cell.

12. The apparatus of claim 11, wherein the apparatus further includes

return lines that return the concentrate and the permeate to the feed supply.

13. The apparatus of claim 8, further including

means for measuring the time rate of flow of permeate.