Methods for production of surface coated niobium reinforcements for intermetallic matrix composites

• US 5,198,187 A
• Filed: 11/20/1991
• Issued: 03/30/1993
• Est. Priority Date: 11/20/1991
• Status: Expired due to Fees

• Current Assignee: University of Florida (State University System of Florida)
• Original Assignee: University of Florida (State University System of Florida)
• Inventors: Abbaschian, Reza, Gokhale, Atul B., Lu, Lixion
• Primary Examiner(s): Walsh, Donald P.
• Assistant Examiner(s): JENKINS, DANIEL J
• Application Number:
  US07/794,944
• Time in Patent Office: 496 Days
• Field of Search: 419/35, 419/24, 75/232, 75/235
• US Class Current: 419/35
• CPC Class Codes: B22F 1/16 Metallic particles coated with a non-metal coated with lubricating or binding agents or with organic material B22F1/10
• CPC Class Codes: B22F 2999/00 Aspects linked to processes or compositions used in powder metallurgy
• CPC Class Codes: B22F 3/23 involving a self-propagating high-temperature synthesis or reaction sintering step making cermets by reaction sintering C22C1/051
• CPC Class Codes: C22C 32/0015 with only single oxides as main non-metallic constituents

Abstract

An improved method of forming a composite body of a metal, intermetallic or ceramic matrix reinforced with niobium filaments, particles, platelets or mixtures thereof, the method comprising admixing the niobium reinforcing material with powders of the matrix component elements, forming the admixture into a desired shape and converting the powders to a matrix reinforced with the niobium material, the improvement wherein the reinforcing material has a surface coating thereon of a compound Nb₂ O₅, wherein the compound NbO reacts during formation of the matrix with a portion of at least one of the powdered elements to form a barrier layer at the reinforcer-matrix interface to prevent further reaction between the reinforcer and the matrix component elements. Also disclosed is a method of treating niobium particles, filaments, platelets or mixtures thereof by exposing the surface thereof to molecular O₂ at temperatures and pressure conditions such that the niobium and molecular O₂ react to form a surface coating on the niobium material of the compound Nb₂ O₅. Also disclosed are the novel products of the above-described methods.

Claims

1. In a self-propagating, high-temperature synthesis, molten metal or powder metallurgical method of forming a composite body comprising a metal, intermetallic or ceramic matrix reinforced with a member selected from the group consisting of filaments, particles, platelets and mixtures thereof composed of a material containing elemental niobium, said method comprising admixing said reinforcing member with powders of said matrix component elements, forming said admixture into a desired shape and subjecting said shaped admixture to temperature and pressure conditions sufficient to convert said powders to a metal, intermetallic or ceramic matrix reinforced with said reinforcing member, the improvement wherein:

said reinforcing member admixed with said powders has a surface coating thereon of a compound Nb₂ O₅, wherein said compound Nb₂ O₅ reacts in situ during formation of said matrix with a portion of at least one of said powdered elements according to the equation Nb₂ O₅ +Z→

ZO+Nb, wherein Z is said at least one powdered element and the reaction product ZO forms as a barrier layer at the reinforcing member/matrix interface to prevent further reaction between said reinforcing member and said matrix component elements.

2. The method of claim 1 wherein said reinforcing member consists essentially of niobium.

3. The method of claim 1 wherein said matrix component elements are selected from the group consisting of Al, Ti, Ni, Ta and Nb.

4. The method of claim 1 wherein said reinforcing member consists essentially of Nb, said surface coating is essentially Nb₂ O₅, said matrix component elements are Nb and Al, or Ta, Ti and Al, or Ni and Al, and said barrier layer reaction product is alumina.

5. The method of claim 4 wherein said matrix is NbAl₃.

6. The method of claim 4 wherein said matrix is TaTiAl₂.

7. The method of claim 4 wherein said matrix is NiAl.

8. The product produced by the method of claim 1.

9. A method of treating a member selected from the group consisting of particles, filaments, platelets and mixtures thereof composed of a material containing elemental niobium comprising exposing a surface of said member to molecular O₂ at temperature and pressure conditions such that said niobium and molecular O₂ react to form a surface coating on said member of the compound Nb₂ O₅.

10. The method of claim 9 wherein said member consists essentially of niobium.

11. The method of claim 9 wherein said surface coating is essentially Nb₂ O₅.

12. The method of claim 9 including the preliminary steps of cleaning and degreasing said surfaces of said member.

13. The method of claim 12 wherein said preliminary cleaning step comprises etching said surfaces of said member.

14. The method of claim 13 wherein said surfaces are etched with a mixture of HF and HNO₃.

15. The method of claim 12 wherein said surfaces are degreased by contact with a solution containing methanol.

16. The product produced by the method of claim 9.