Oil microsensor having interdigitated electrodes with rough surfaces and methods of making and using the same

• US 5,200,027 A
• Filed: 11/12/1991
• Issued: 04/06/1993
• Est. Priority Date: 11/12/1991
• Status: Expired due to Term

• Current Assignee: GM Global Technology Operations Incorporated (General Motors Company)
• Original Assignee: General Motors Corporation (General Motors Company)
• Inventors: Wang, Su-Chee S., Klingenmaier, Otto J., Lee, Han-Sheng
• Primary Examiner(s): Powell, William A.
• Application Number:
  US07/790,401
• Time in Patent Office: 511 Days
• Field of Search: 73/116, 156/649, 156/651, 156/656, 156/659.1, 156/664, 156/665, 156/666, 252/79.1, 252/79.2, 252/79.5, 204/15, 437/187, 437/193, 437/194, 437/225, 437/228, 437/245
• US Class Current: 216/51
• CPC Class Codes: G01N 27/226 Construction of measuring vessels; Electrodes therefor
• CPC Class Codes: G01N 33/2888 Lubricating oil characteristics, e.g. deterioration lubricating properties G01N33/30

Abstract

Disclosed is an oil sensor having roughened electrode surfaces to produce oil condition related output current or voltage from the automotive engine oil as it is used.

Claims

1. A method of making an oil sensor comprising the steps of:

growing silicon dioxide on a silicon wafer;

depositing silicon nitride on the silicon dioxide;

depositing polysilicon on the silicon nitride;

evaporating a material comprising at least one selected from the group consisting of aluminum, copper, silver, nickel and gold, on the polysilicon to form a thin layer;

forming an interdigitated pattern in said layer by photolithography to form electrodes;

exposing the electrodes to a zincate solution comprising ZnO and NaOH; and

thereafter exposing the electrode to an a HNO₃ solution.

2. A method as set forth in claim 1 wherein said step of exposing the electrodes to a solution of HNO₃ is for a period sufficient to remove the zinc coat produced after exposing the electrodes to a zincate solution.

3. A method as set forth in claim 1 wherein said step of exposing the electrodes to a solution of HNO₃ is conducted for a period of about 20 seconds and wherein said HNO₃ is 5 percent by weight of said HNO₃ solution.

4. A method as set forth in claim 1 wherein said steps of exposing the electrode to a zincate solution and a HNO₃ solution is preformed three times.

5. A method as set forth in claim 4 wherein the electrode is further exposed to a zincate solution for about three seconds so that a very thin layer of zinc forms on the electrode so as to minimize the growth of oxide on said electrode.

6. A product comprising the product-by-process of claim 1.

7. A method as set forth in claim 1 further comprising the step of electroplating the sensor with a chemically inert metal so as to increase the durability of the sensor.

8. A method as set forth in claim 1 wherein said step of exposing the electrode to a zincate solution is conducted for a period of about 10 to 15 seconds.

9. A method as set forth in claim 8 wherein said step of exposing the electrode to a zincate solution is repeated once.

10. A method as set forth in claim 8 wherein said step of exposing the electrode to a zincate solution is repeated twice.

11. A method of making an oil sensor comprising the steps of:

growing silicon dioxide on a silicon wafer;

depositing silicon nitride on the silicon dioxide;

depositing polysilicon on the silicon dioxide;

evaporating a material comprising at least one selected from the group consisting of aluminum, copper, silver, nickel and gold on the polysilicon to form a thin layer;

forming an interdigitated pattern in said layer by photolithography to form electrodes;

roughing the surfaces of the electrodes so that upon deploying said oil sensor in an oil comprising electrochemically active species, being used in an automotive engine, the end of the useful life of the oil is quantitatively determinable from the output voltage of said sensor.

12. A product comprising the product-by-process of claim 11.

13. A method as set forth in claim 11 wherein said step of roughing comprises etching.

14. A method of making an oil sensor comprising the steps of:

growing silicon dioxide on a silicon wafer;

depositing silicon nitride on the silicon dioxide;

depositing polysilicon on the silicon nitride;

evaporating a material comprising at least one selected from the group consisting of aluminum, copper, silver, nickel and gold on the polysilicon to form a thin layer;

forming an interdigitated pattern in said layer by photolithography to form electrodes;

roughing the electrodes an amount sufficient so that said sensor produces a monotonic output voltage or a check mark curve upon deployment in an oil comprising antioxidants and detergents as the oil is being used to lubricate an engine.

15. A product comprising the product-by-process of claim 14.

16. A method as set forth in claim 14 wherein said step of roughing comprises etching.