Peroxyacid antimicrobial composition

• US 5,200,189 A
• Filed: 07/23/1991
• Issued: 04/06/1993
• Est. Priority Date: 07/23/1991
• Status: Expired due to Term

• Current Assignee: Ecolab USA Incorporated (Ecolab, Inc.)
• Original Assignee: Ecolab, Inc.
• Inventors: Stanley, Patricia M., Oakes, Thomas R., Keller, Jerome D.
• Primary Examiner(s): Page, Thurman K.
• Assistant Examiner(s): LEVY, NEIL S
• Application Number:
  US07/734,580
• Time in Patent Office: 623 Days
• Field of Search: 424/616, 424/405, 514/557, 514/558, 514/559, 514/714, 422/28
• US Class Current: 424/405
• CPC Class Codes: A01N 2300/00 Combinations or mixtures of active ingredients covered by classes A01N27/00 - A01N65/48 with other active or formulation relevant ingredients, e.g. specific carrier materials or surfactants, covered by classes A01N25/00 - A01N65/48
• CPC Class Codes: A01N 37/16 containing the group; Thio analogues thereof
• CPC Class Codes: C11D 3/3945 Organic per-compounds C11D3/3902 takes precedence
• CPC Class Codes: C11D 3/48 Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions

Abstract

A peroxyacid antimicrobial concentrate and use composition is provided comprising a C₁ to C₄ peroxycarboxylic acid, and a C₆ to C₁₈ peroxyacid. The combination of these acids produces a synergistic effect, providing a much more potent biocide than can be obtained by using these components separately. Other components can be added to the composition such as hydrotrope coupling agents, stabilizers, etc. An effective antimicrobial use solution is formed at low concentrations when the concentrate composition is diluted with water to a pH in the range of about 2 to 8. Sanitizing of substantially fixed, "in-place" processing lines in dairies, breweries, and other food processing operations is one utility of the composition.

Claims

1. A peroxyacid antimicrobial concentrate composition comprising:

(a) about 0.01 to 25 wt. % of a C₁ -C₄ peroxycarboxylic acid;

(b) about 0.01 to 10 wt. % of a peroxyacid of the structure R₁ --CO₃ H, wherein R₁ comprises a linear, saturated hydrocarbon chain having about 5 to 17 carbon atoms;

(c) about 0.1 to 30 wt. % of a hydrotrope coupling agent capable of solubilizing said peroxyacid of (b) in the concentrate and when the concentrate is diluted with water; and

(d) about 1 to 50 wt. % of hydrogen peroxide;

wherein the concentrate composition is capable of being diluted with a major proportion of water to form an antimicrobial sanitizing use solution having a pH in the range of about 3 to 7.

2. The concentrate composition of claim 1 wherein said C₁ -C₄ peroxycarboxylic acid comprises peroxyacetic acid, peroxypropionic acid, peroxysuccinic acid, peroxyglycolic acid, or mixtures thereof.

3. The concentrate composition of claim 1 wherein said peroxyacid of (b) is a peroxyfatty acid having about 8 to 12 carbon atoms per molecule.

4. The concentrate composition of claim 3 wherein said peroxyfatty acid comprises peroxyoctanoic acid, peroxydecanoic acid, or mixtures thereof.

5. The concentrate composition of claim 3 wherein the weight ratio of C₁ -C₄ peroxycarboxylic acid to peroxyfatty acid is about 15:

1 to 3;

1.

6. The concentrate composition of claim 1 wherein said hydrotrope comprises n-octanesulfonate.

7. The concentrate composition of claim 3 further comprising about 5 to 50 wt. % of a fatty acid, a C₁ -C₄ carboxylic acid, or mixtures thereof.

8. The concentrate composition of claim 7 wherein said C₁ -C₄ carboxylic acid component comprises acetic acid, propionic acid, or mixtures thereof.

9. The concentrate composition of claim 7 wherein said fatty acid comprises octanoic acid, decanoic acid, or molecule.

10. The composition of claim 1 further comprising an effective amount of a chelating agent for binding polyvalent metal cations.

11. The composition of claim 10 wherein said chelating agent is 1-hydroxyethylidene-1,1-diphosphonic acid.

12. The composition of claim 11 wherein said chelating agent is present in an amount of about 1 wt. % based on the concentrate composition.