Sulfur dioxide detector device embodied by using S02-oxidant bioagent

• US 5,206,170 A
• Filed: 10/01/1991
• Issued: 04/27/1993
• Est. Priority Date: 03/28/1991
• Status: Expired due to Fees

• Current Assignee: Nakano Vinegar Co., Ltd.
• Original Assignee: Nakano Vinegar Co., Ltd.
• Inventors: Kubo, Nobuko, Iijima, Shigesada, Sato, Takeshi, Akano, Hirofumi, Kawamura, Yoshiya
• Primary Examiner(s): KRATZ, PETER F
• Application Number:
  US07/769,534
• Time in Patent Office: 574 Days
• Field of Search: 435/817, 435/291, 435/288, 204/415, 204/403, 204/153.17, 204/153.19
• US Class Current: 204/403.05
• CPC Class Codes: C12Q 1/001 Enzyme electrodes
• CPC Class Codes: C12Q 1/005 involving specific analytes or enzymes including groups of enzymes, e.g. oxydases; C12Q1/004 takes precedence
• CPC Class Codes: G01N 33/0042 for SO2, SO3
• CPC Class Codes: Y02A 50/20 Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
• CPC Class Codes: Y10S 435/817 Enzyme or microbe electrode

Abstract

In a sulfur dioxide detector using SO₂ -oxidant microbes, a bio-membrane is located at one end of an oxygen concentration sensor, the bio-membrane containing the SO₂ -oxidant microbes between an immobilized membrane and a gas permeable membrane. The sensor has an electrode in contact with the immobilized membrane. A dish-shaped or frusto-conical cell has an open end which is in contact with the gas permeable membrane so that SO₂ -laden solution supplied to the cell causes sulfurous acid to oxidize to sulfuric acid as the SO₂ permeates through the bio-membrane so as to change an output from the sensor. An inlet and outlet hole are formed on a sidewall of the cell. The outlet hole is located to be always directly above the inlet hole so as to drain foam formed when the SO₂ -laden solution is supplied to the cell through the inlet hole and drained from the outlet hole.

Claims

1. A sulfur dioxide detector device using SO₂ -oxidant bioagent, the detector device comprising:

a horizontally arranged sensor housing;

an oxygen concentration sensor removably disposed within the sensor housing;

a bio-membrane concentrically located at one end of the oxygen concentration sensor, the bio-membrane including an SO₂ -oxidant bioagent provided between an immobilized membrane and a gas permeable membrane;

the oxygen concentration sensor having an oxygen electrode placed in contact with the immobilized membrane of the bio-membrane;

a dish-shaped cell formed with a horizontally extending axis, and having an open end which is in contact with the gas permeable membrane of the bio-membrane so that SO₂ -laden solution supplied to the cell oxidizes sulfurous acid into sulfuric acid as SO₂ permeates through the bio-membrane so as to change an output from the oxygen concentration sensor depending on an amount of SO₂ ; and

an inlet hole and an outlet hole each formed on a sidewall of the cell in diametrically opposed relationship, the outlet hole being always located directly above the inlet hole so as to quickly drain foam formed when the SO₂ -laden solution is supplied to the dish-shaped cell through the inlet hole and drained from the outlet hole, the inlet and outlet holes being directed toward the gas permeable membrane to make an angle with the axial direction of the cell of less than 90 degrees.

2. A sulfur dioxide detector device as recited in claim 1, wherein the bioactive agent is selected from the group consisting of Thiobacillus thiooxidans and enzyme derived from Thiobacillus ferroxidans.

3. A sulfur dioxide detector device as recited in claim 1, wherein an opening area of the outlet is 2˜

4 times as great as that of the inlet hole.

4. A sulfur dioxide detector device as recited in claim 1, wherein the dish-shaped cell has a volume capacity within the range from 0.3 ml to 0.6 ml.

5. A sulfur dioxide detector device as recited in claim 1, further comprising a retainer frame removably disposed within the sensor housing in a manner to surround one end of the oxygen concentration sensor, and a press ring removably fitted around the retainer frame so as to retain a periphery of the bio-membrane between the retainer frame and the press ring.

6. A sulfur dioxide detector device as recited in claim 5, wherein the oxygen concentration sensor is enclosed in a cylindrical handle which is removably disposed in the sensor housing.

7. A sulfur dioxide detector device as recited in claim 5, wherein a support plate is fixedly provided between the gas permeable membrane of the bio-membrane and the open end of the cell, the support plate having a central open window into which an O-ring is fitted to elastically urge the bio-membrane against the oxygen electrode of the oxygen concentration sensor.