Laser markable white pigment composition

• US 5,206,280 A
• Filed: 03/08/1991
• Issued: 04/27/1993
• Est. Priority Date: 03/15/1990
• Status: Expired due to Fees

• Current Assignee: BAE Systems Plc
• Original Assignee: British Aerospace, Inc. (BAE Systems Plc)
• Inventors: Williams, Stewart W.
• Primary Examiner(s): Michl, Paul R.
• Assistant Examiner(s): Cain, Edward J.
• Application Number:
  US07/666,898
• Time in Patent Office: 781 Days
• Field of Search: 524/409, 524/411, 524/412, 524/413, 524/433, 524/436, 524/437
• US Class Current: 524/409
• CPC Class Codes: B41M 5/267 Marking of plastic artifacts, e.g. with laser
• CPC Class Codes: B44B 7/002 in layered material
• CPC Class Codes: H01B 7/365 being indicia imposed on the insulation or conductor

Abstract

A laser markable white pigment composition includes a first pigment which is markable by ultraviolet laser, a second pigment, which is nonabsorbing in the ultraviolet region of the optical spectrum and which has a white appearance in the visible region of the optical spectrum, with the ratio of the amount of first pigment to amount of second pigment being in the range of from 4:1 to 1:10, so that the second pigment is present in an amount sufficient to increase the optical density, that is the whitening effect, of the composition, without adversely affecting the laser markability of the composition, and a carrier which is at least one fluoropolymer transparent in the ultraviolet region of the optical spectrum.

Claims

1. A laser markable white pigment composition, which composition consists essentially of

a first pigment which is markable by ultraviolet laser,

a second pigment, which is nonabsorbing in the ultraviolet region of the optical spectrum and which has a white appearance in the visible region of the optical spectrum, with the ratio of the amount of first pigment to amount of second pigment being in the range of from 4:

1 to 1;

10, so that the second pigment is present in an amount sufficient to increase the optical density, that is the whitening effect, of the composition, without adversely affecting the laser markability of the composition, and

a balance of the composition being a carrier which is at least one fluoropolymer transparent in the ultraviolet region of the optical spectrum.

2. A composition according to claim 1, in which the first pigment is at least one selected from the group comprising titanium dioxide, antimony trioxide, polyethylethylketone (PEEK) and polyethlysulphone (PES).

3. A composition according to claim 1, in which the second pigment is at least one selected from the group comprising silicon dioxide, magnesium oxide, aluminium oxide and diamond.

4. A composition according to claim 1, in which the fluoropolymer is at least one selected from the group comprising polytetrafluoroethylene, fluoroethylenepropylene and ethylenetetrafluoroethylene.

5. A composition according to claim 1, comprising from 1 to 35% by dry weight titanium dioxide, from 2 to 30% by dry weight second pigment and the balance, apart from impurities and incidental constituents, being fluoropolymer.

6. A composition according to claim 5, including 4% by dry weight titanium dioxide and from 4 to 20% by dry weight second pigment.

7. A composition according to claim 1, in the form of a dry mix.

8. A composition according to claim 1, in the form of a dispersion in water.