Electric element capable of controlling the electric conductivity of .pi.-conjugated macromolecular materials

• US 5,206,525 A
• Filed: 08/20/1991
• Issued: 04/27/1993
• Est. Priority Date: 12/27/1989
• Status: Expired due to Fees

• Current Assignee: Nippon Petrochemicals Co., Ltd. (ENEOS Holdings, Inc.)
• Original Assignee: Nippon Petrochemicals Co., Ltd. (ENEOS Holdings, Inc.)
• Inventors: Yamamoto, Hiromichi, Nishibe, Takashi, Kumehara, Hideo
• Primary Examiner(s): Hille, Rolf
• Assistant Examiner(s): TRAN, MINH LOAN
• Application Number:
  US07/743,324
• Time in Patent Office: 616 Days
• Field of Search: 357/4, 357/8, 357/23.2, 357/23.7, 357/23.14, 357/25, 257/40
• US Class Current: 257/40
• CPC Class Codes: B82Y 10/00 Nanotechnology for information processing, storage or transmission, e.g. quantum computing or single electron logic
• CPC Class Codes: G11C 11/22 using ferroelectric elements
• CPC Class Codes: H10K 10/464 Lateral top-gate IGFETs comprising only a single gate
• CPC Class Codes: H10K 10/466 Lateral bottom-gate IGFETs comprising only a single gate
• CPC Class Codes: H10K 10/482 the IGFET comprising multiple separately-addressable gate electrodes
• CPC Class Codes: H10K 10/488 the channel region comprising a layer of composite material having interpenetrating or embedded materials, e.g. a mixture of donor and acceptor moieties, that form a bulk heterojunction
• CPC Class Codes: H10K 71/125 using electrolytic deposition e.g. in-situ electropolymerisation
• CPC Class Codes: H10K 85/113 Heteroaromatic compounds comprising sulfur or selene, e.g. polythiophene
• CPC Class Codes: H10K 85/114 Poly-phenylenevinylene; Derivatives thereof
• CPC Class Codes: H10K 85/141 comprising aliphatic or olefinic chains, e.g. poly N-vinylcarbazol, PVC or PTFE

Abstract

An electric element of the present invention comprises a π-conjugated macromolecular material which is liable to increase its conductivity by its excitation due to dielectric polarization, and a ferroelectric material disposed in the close proximity of said π-conjugated macromolecular material so that polarization of said ferroelectric material in the presence of an electric field causes excitation of said π-conjugated macromolecular material, thereby changing the conductivity of said π-conjugated macromolecular material correspondingly with the strength of said electric field and resultantly controlling said conductivity. The electric element can be used as a d.c. or a.c. relay element, memory element, switching element, or any other active element.

Claims

1. An electric element which comprises:

a π

-conjugated macromolecular material which is liable to increase its conductivity when it is put in an excited state by polarization of a dielectric substance;

a ferroelectric material disposed so close to said π

-conjugated macromolecular material that excitation of said π

-conjugated macromolecular material occurs in response to polarization of said ferroelectric material;

a pair of input and output electrodes disposed at the opposite ends of said π

-conjugated macromolecular material to make their respective ohmic-contacts therewith; and

a pair of control electrodes disposed so as to sandwich said π

-conjugated macromolecular material in the direction perpendicular to the direction in which said input and output electrodes are laid, the conductivity of said electric element between input and output electrodes varying corresponding to the voltage of the electric field when an electric field is applied between said control electrodes.

2. An electric element according to claim 1, wherein the π

-conjugated macromolecular material is formed into a layer and is then laminated onto the ferroelectric material layer.

3. The electric element according to claim 2 which further comprises a dielectric film to separate each of said control electrodes from said π

-conjugated macromolecular material.

4. The electric element according to claim 1, wherein said π

-conjugated macromolecular material has been oriented by stretching.

5. The electric element according to claim 4 which further comprises a dielectric film to separate each of said control electrodes from said π

-conjugated macromolecular material.

6. The electric element according to claim 1, wherein said ferroelectric material is mixed with said π

-conjugated macromolecular material and the mixture is formed into a layer whereby said π

-conjugated macromolecular material is disposed close to said ferroelectric material.

7. The electric element according to claim 6 which further comprises a dielectric film to separate each of said control electrodes from said π

-conjugated macromolecular material.

8. The electric element according to claim 1 which comprises a dielectric film to separate each of said control electrodes from said π

-conjugated macromolecular material.

9. A method of controlling the conductivity of a π

-conjugated macromolecular material, which material is capable of increasing its conductivity when put in its excited state by polarization of a dielectric substance, which comprises;

disposing a ferroelectric material so close to said π

-conjugated macromolecular material that polarization of said ferroelectric material causes excitation of said π

-conjugated macromolecular material; and

applying an electric field of controlled strength to said ferroelectric material to cause polarization of said ferroelectric material, whereby said π

-conjugated macromolecular material is put in its excited state and the conductivity of said π

-conjugated macromolecular material changes corresponding to the strength of said electric field.

10. The method of controlling the conductivity of a π

-conjugated macromolecular material according to claim 9 wherein said π

-conjugated macromolecular material has been oriented by stretching.