Process for purifying resins utilizing bipolar interface

• US 5,211,823 A
• Filed: 06/19/1991
• Issued: 05/18/1993
• Est. Priority Date: 06/19/1991
• Status: Expired due to Fees

• Current Assignee: Millipore Corporation
• Original Assignee: Millipore Corporation
• Inventors: Ganzi, Gary C., Giuffrida, Anthony J.
• Primary Examiner(s): Niebling, John
• Assistant Examiner(s): Phasge, Arun S.
• Application Number:
  US07/717,460
• Time in Patent Office: 699 Days
• Field of Search: 204/182.4, 204/182.5, 204/131
• US Class Current: 204/534
• CPC Class Codes: B01J 47/08 subjected to a direct electric current
• CPC Class Codes: B01J 49/30 Electrical regeneration
• CPC Class Codes: C02F 1/4695 electrodeionisation

Abstract

Purified ion exchange resin particles are provided in a bifunctional electrodeionization step having anion depletion compartments containing anion exchange resin particles which are purified and cation depletion compartments containing cation exchange resin particle which are purified as well as ion concentration compartments. The bifunctional electrodeionization step for purifying resin particles is conducted under conditions to disassociate water into hydrogen ions and hydroxyl ions. Purified water having a purity of at least 1 megohm-cm is introduced into the anion depletion compartment and cation depletion compartments and water for accepting ionic impurities is introduced into the ion concentration compartments. The purified water is produced in an initial purification step which also can be an electrodeionization step. The water effluent from the anion depletion compartments and cation depletion compartments is recycled either to an initial water purification step or to the inlets of the anion depletion compartments or cation depletion compartments. The anion depletion compartments include an anion permeable membrane and a bifunctional interface. The cation depletion compartments include a cation permeable membrane and the bifunctional interface.

Claims

1. A process for purifying anion exchange resin particles and cation exchange resin particles containing less than about 1% and 0.1% ionic impurities respectively other than hydroxyl ion or hydrogen ion which comprises:

providing a water stream having a purity of at least about 1 megohm-cm,

passing said water stream through ion depletion compartments containing said resin particles in an electrodeionization apparatus, said electrodeionization apparatus comprising;

a cathode compartment at a first end of said apparatus,

an anode compartment at an end of said apparatus opposite said first end,

a plurality of sets of an anion depletion compartments and cation depletion compartments alternating with ion concentration compartments positioned between said cathode compartment and said anode compartment,

each anion depletion compartment and each cation depletion compartment being separated by a bifunctional interface,

passing a second liquid for accepting ions from said water stream through said concentration compartments while said water stream is passed through said anion depletion compartments and said cation depletion compartments,

applying an electrical voltage between an anode in said anode compartment and a cathode in said cathode compartment,

and recovering said purified resin particles.

3. The process of any one of claims 1 or 2 wherein said water stream is produced by an electrodeionization purification step.

4. The process of claim 3 wherein said water stream having a purity of at least 1 megohm - cm is produced in said ion depletion compartments and said purified water is recycled to ion depletion compartments in said electrodeionization purification step.

5. The process of claim 4 wherein operating conditions in said electrodeionization step minimize the formation of hydroxyl ion and hydrogen ion.

6. The process of claims 3 wherein said bifunctional interface is a bipolar membrane.

7. The process of any one of claims 1 or 2 wherein said water stream is exposed to ultra-violet radiation and is then introduced into an electrode-ionization purification step.

8. The process of claim 7 wherein purified water is produced in said ion depletion compartments and said purified water is recycled to ion depletion compartments in said electrodeionization purification step.

9. The process of claim 8 wherein operating conditions in said electrodeionization step minimize the formation of hydroxyl ion and hydrogen ion.

10. The process of claims 7 wherein said bifunctional interface is a bipolar membrane.

11. The process of any one of claims 1, 2, 4, 8 or 5 wherein said bifunctional interface is a bipolar membrane.

2. A process for purifying anion exchange resin particles and cation exchange resin particles containing less than about 1% and 0.1% ionic impurities respectively other than hydroxyl ion or hydrogen ion which comprises:

providing a water stream having a purity of at least about 1 megohm-cm,

passing said water stream through ion depletion compartments containing said resin particles in an electrodeionization apparatus, said electrodeionization apparatus comprising;

a cathode compartment at a first end of said apparatus,

an anode compartment at an end of said apparatus opposite said first end,

a plurality of sets of an anion depletion compartments and cation depletion compartments alternating with ion concentration compartments positioned between said cathode compartment and said anode compartment,

each anion depletion compartment and each cation depletion compartment being separated by a bifunctional interface,

passing a second liquid for accepting ions from said water stream through said concentration compartments while said water stream is passed through said anion depletion compartments and said cation depletion compartments,

applying an electrical voltage between an anode in said anode compartment and a cathode in said cathode compartment,

recovering purified water from said depletion compartments, and recycling purified water to said anion depletion compartments and said cation depletion compartments for a sufficient time period to form purified ion exchange resin particles in said anion depletion compartments and said cation depletion compartments,

and recovering said purified resin particles.