Method and materials for producing a printing master

• US 5,212,030 A
• Filed: 11/21/1989
• Issued: 05/18/1993
• Est. Priority Date: 11/21/1989
• Status: Expired due to Fees

• Current Assignee: Placer Limited (Placer Niugini Limited)
• Original Assignee: Placer Limited (Placer Niugini Limited)
• Inventors: Figov, Murray
• Primary Examiner(s): McCamish, Marion E.
• Assistant Examiner(s): CROSSAN, STEPHEN
• Application Number:
  US07/439,704
• Time in Patent Office: 1,274 Days
• Field of Search: 430/49, 430/281
• US Class Current: 430/49.43
• CPC Class Codes: G03G 13/283 obtained by a process including the transfer of a tonered image, i.e. indirect process

Abstract

A specially coated paper which has been prepared for imaging in an electrophotographic reproduction process, and a method for developing an image produced on this paper so that it may be used as a lithographic printing plate. The base material is polyester and is coated with either a thermoplastic or cross-linking resin or mixture of resins. The layer which is used for coating the polyester is loaded with zinc oxide. Once the printing plate has been prepared, it is then imaged in a photocopier or laser printer using the indirect electrophotographic process. Background dots can then be eliminated by application of a specific mixture to the printing plate before printing. The mixture preferably consists of an emulsion with an external hydrophilic phase, and an internal lipophylic/solvent phase held together by a surfactant or mixture of surfactants. Optionally, the external phase may also contain an aqueous solution of ferrocyanide or tannic acid or any other known conversion agent so that it may be applied to the plate without the need for previously etching it with the conventional electrostatic conversion etch. The plates may be imaged in laser printers, so that printing plates may be obtained directly from both digital and analog information on equipment that need not be dedicated to such use, which is already owned by potential users.

Claims

1. A method of producing a printing plate using the indirect electrophotographic process, said method comprising the steps of:

coating a polyester printing plate base material with a pigment-loaded resin;

imaging said coated printing plate in an indirect electrophotographic process, forming image areas;

applying a conversion etch solution for etching said image areas; and

applying a background cleaning mixture to said etched image areas to improve the sharpness thereof while simultaneously removing unwanted background image formed by toner particles,

wherein said background cleaning mixture is an emulsion comprising an external hydrophilic phase of water, a humectant and an acid, at least one surfactant with an HLB greater than 10, and an internal lipophilic phase consisting of an oil and an organic solvent, where the total surfactant and lipophilic phase are a total weight of less than 30%;

and wherein the strength of said organic solvent in said background cleaning mixture is 2.7% by weight, to remove said unwanted background image while sharpening said etched image areas.

3. The method of either of claims 1 or 2 wherein said imaging step is performed in a laser printer utilizing the indirect electrophotographic method.

4. The method of either of claims 1 or 2 wherein said imaging step is performed in a laser printer with a laterally inverted image and that same image is used, emulsion-to-emulsion, to image a metal offset printing plate with u.v. light.

5. The method of either of claims 1 or 2 wherein said imaging step is performed using a plain paper copier.

6. The method of either of claims 1 or 2 wherein in the emulsion comprising an external hydrophilic phase, at least one surfactant, and an internal lipophilic phase, the external hydrophilic phase of said emulsion contains ferrocyanide ions.

7. The method of either of claims 1 or 2 wherein said emulsion contains a desensitizing resin in the external hydrophilic phase.

8. The method of either of claims 1 or 2 wherein said emulsion contains a lipophilic resin in the internal lipophilic phase.

2. A method of producing a printing plate using the indirect electrophotographic process, said method comprising the steps of;

coating a polyester printing plate base material with a pigment-loaded resin;

imaging said coated printing plate in an indirect electrophotographic process, forming image areas;

applying a conversion etch solution for etching said image areas; and

applying a background cleaning mixture to said etched image areas to improve the sharpness thereof while simultaneously removing unwanted background image formed by toner particles,

wherein said background cleaning mixture is an emulsion comprising an external hydrophilic phase of water, a humectant and an acid, at least one surfactant with an HLB greater than 10, and an internal lipophilic phase consisting of an oil and an organic solvent, where the total surfactant and lipophilic phase are a total weight of less than 30%;

and wherein the strength of said organic solvent in said background cleaning mixture is 8.4% by weight, to remove said unwanted background image while sharpening said etched image areas.

9. An emulsion for improving the sharpness of etched image areas while simultaneously removing unwanted background image areas formed by toner particles on an electrophotographically produced polyester printing plate, said emulsion comprising an external hydrophilic phase, an internal lipophilic phase, and a surfactant,

wherein said external hydrophilic phase contains at least one of the group consisting of ferrocyanide ions, a desensitizing resin, or an acid,

and said internal lipophilic phase contains a lipophilic resin and an organic solvent,

and wherein the strength of said organic solvent in said emulsion is 2.7% by weight, to remove said unwanted background image while sharpening said etched image areas.

10. An emulsion for improving the sharpness of etched image areas while simultaneously removing unwanted background image areas formed by toner particles on an electrophotographically produced polyester printing plate, said emulsion comprising an external hydrophilic phase, an internal lipophilic phase, and a surfactant,

wherein said external hydrophilic phase contains at least one of the group consisting of ferrocyanide ions, a desensitizing resin, or an acid,

and said internal lipophilic phase contains a lipophilic resin and an organic solvent,

and wherein the strength of said organic solvent in said emulsion is 8.4% by weight, to remove said unwanted background image while sharpening said etched image areas.