Large surface area electrodes

• US 5,212,622 A
• Filed: 10/29/1991
• Issued: 05/18/1993
• Est. Priority Date: 11/03/1989
• Status: Expired due to Term

• Current Assignee: Telectronics Pacing Systems, Inc (Abbott Laboratories)
• Original Assignee: Specialised Conductives Pty Limited
• Inventors: Forsyth, Maria, Tetaz, John R., MacFarlane, Douglas R.
• Primary Examiner(s): GRIFFIN, DONALD
• Application Number:
  US07/784,262
• Time in Patent Office: 567 Days
• Field of Search: 361/303-305, 361/502
• US Class Current: 361/305
• CPC Class Codes: H01B 1/122 Ionic conductors
• CPC Class Codes: H01B 1/22 the conductive material comprising metals or alloys
• CPC Class Codes: H01B 1/24 the conductive material comprising carbon-silicon compounds, carbon or silicon
• CPC Class Codes: H01M 4/02 Electrodes composed of, or comprising, active material
• CPC Class Codes: H01M 4/621 Binders
• CPC Class Codes: H01M 4/86 Inert electrodes with catalytic activity, e.g. for fuel cells
• CPC Class Codes: H01M 6/181 with polymeric electrolytes
• CPC Class Codes: Y02E 60/50 Fuel cells

Abstract

A high surface area electrode formed from filler particles having a high surface to volume ratio in a binder able to support the conduction of ions. The binder may be a hydrophilic polymer and hydrogel able to swell to incorporate a solvent and its dissolved ionic material while retaining its mechanical strength. The swelling may be regulated by control of the degree of cross-linking of the binder material.

Claims

1. A high surface are electrode comprising a composite material that comprises

an electronically conductive particulate filler having a high surface to volume ratio dispersed in

a binder material, wherein the particles of said particulate filler are substantially in intimate contact, and said binder material conducts ions to and from a substantial proportion of the surface of the filler particles.

2. The high surface area electrode of claim 1 wherein said binder material additionally comprises a polymeric material having ionized groups and counterions.

3. The high surface area electrode of claim 1 adapted to convert an electronic current in an external circuit to an ionic current at the electrode surface, wherein said conductive particulate filler is at some point in electrical contact with an external connection, and wherein the overall electric impedance contributed by the conduction processes is not so high that the electrode assembly as a whole dissipates a substantial amount of energy.

4. The high surface area electrode of claim 1, wherein the conductive filler medium comprises a conductive carbon black having a surface area exceeding 1000 m² /g.

5. The high surface area electrode of claim 1 wherein said conductive particulate filler is a metallic or metal alloy based material.

6. The high surface area electrode of claim 5 wherein said metallic material is selected from the group consisting of copper, nickel, silver, and platinum.

7. A high surface area electrode comprising a composite material that comprises

an electronically conductive particulate filler having a high surface to volume ratio dispersed in

a binder material, wherein the particles of said particulate filler are substantially in intimate contact, and said binder material conducts ions to and from a substantially proportion of the surface of the filler particles, wherein said binder is swellable in the solvent to incorporate both solvent and ionic material, said binder retaining sufficient mechanical strength remains to hold the mass of conductive filler particles together.

8. The high surface area electrode of claim 7 wherein said swellable binder material comprises a hydrophilic polymer.

9. The high surface area electrode of claim 7 wherein said swellable binder material comprises a hydrogel.

10. The high surface area electrode of claim 7 wherein said binder material is obtained from cross-linking.

11. The high surface area electrode of claim 10 wherein the material crosslinked are cellulose and its derivatives.

12. The high surface area electrode of claim 11 wherein the material crosslinked are selected from the group consisting of polyethers, polyurethanes, polyacrylates, polyesters, polyimines, and polyphosphasenes.

13. The high surface area electrode of claim 10 wherein the material crosslinked are polymeric materials having a degree of hydrophilic character such that they can absorb water and polar solvents.

14. The high surface area electrode of claim 10 wherein the material crosslinked are siloxanes suitably modified such that they have a degree of hydrophilic nature and can absorb water and polar solvents.

15. The high surface area electrode of claim 10 wherein the material crosslinked is a hydrogel forming polymer systems.

16. The high surface area electrode of claim 7 wherein said solution swellable materials when brought into contact with an ion containing solution will absorb an amount of the solution and its ions and become a conductor of ions.

17. A high surface area electrode comprising a composite material that comprises

an electronically conductive particulate filler having a high surface to volume ratio dispersed in

a binder material, wherein the particles of said particulate filler are substantially in intimate contact, and said binder material conducts ions to and from a substantial proportion of the surface of the filler particles, wherein said binder material additionally comprises a polymeric material having ionized groups and counterions, wherein said polymeric material forms polyelectrolytes when neutralized.

18. The high surface area electrode of claim 17 wherein said polymeric material comprises polyacrylic acid.

19. A high surface are electrode comprising a composite material that comprises

an electronically conductive particulate filler having a high surface to volume ratio dispersed in

a binder material, wherein the particles of said particulate filler are substantially in intimate contact, and said binder material conducts ions to and from a substantial proportion of the surface of the filler particles, wherein said binder material additionally comprises a polymeric material having ionized groups and counterions, wherein said polymeric comprises ionizable groups.

20. The high surface area electrode of claim 19 comprising cellulose or its derivatives.

21. The high surface area electrode of claim 19 comprising a polymeric material having a hydrophilic character such that it can absorb water and polar solvents.

22. The high surface area electrode of claim 19 comprising polymeric material selected from the group consisting of polyethers, polyurethanes, polyacrylates, and polyesters.

23. The high surface area electrode of claim 19 comprising polymeric material selected from the group consisting of siloxanes modified such that they have a degree of hydrophilic nature and can absorb water and polar solvents.

24. The high surface area electrode of claim 19 comprising hydrogel forming polymer systems.

25. The high surface area electrode of claim 19 wherein said ionizable group is selected form the group consisting of carboxylic acid groups, sulphonic acid groups, ammonium and alkyl ammonium groups, organo phosphate, organoborate and organocarbonate groups.

26. The high surface area electrode of claim 25 wherein said groups are in their acidic form.

27. The high surface area electrode of claim of claim 26 wherein the acidity is increased by incorporation of a complexing agent.

28. The high surface area electrode of claim 27 wherein said complexing agent is selected from the group consisting of AsF₃, SbF₃, BF₃.

29. The high surface area electrode of claim 25 wherein said groups are in their neutralized form and said material incorporates a counterion.

30. A high surface area electrode comprising a composite material that comprises

an electronically conductive particulate filler having a high surface to volume ratio dispersed in

a binder material, wherein the particles of said particulate filler are substantially in intimate contact, and said binder material conducts ions to and from a substantial proportion of the surface of the filler particles, wherein said material comprises an unreactive, low molecular weight liquid which can diffuse out of the electrode when it is first placed in the medium in which it is to be operated.

31. The high surface area electrode of claim 30 wherein said low molecular weight liquid may be selected from the group consisting of water, an alcohol, an ester, aldehyde, ketone, ether or carbonate.

32. A high surface area electrode comprising a composite material that comprises

an electronically conductive particulate filler having a high surface to volume ratio dispersed in

a binder material, wherein the particles of said particulate filler are substantially in intimate contact, and said binder material conducts ions to and from a substantial proportion of the surface of the filler particles, wherein said binder material comprises a solid polymer electrolyte.

33. A process for the preparation of a high surface area electrode comprising the steps of

preparing a composite comprised of

an electronically conductive particulate filler dispersed in a binder material such that the filler particles are substantially in intimate contact, comprising the further steps of

blending together carbon black with a liquid mixture which contains methoxyoctaoxyethylene methacrylate and octaoxyethylene dimethacrylate;

adding to this blend benzoyl peroxide;

casting the material into a film on a metallic sheet;

curing the material into a rubber material.

34. A process for the preparation of a high surface area electrode comprising the steps of

preparing a composite comprised of

an electronically conductive particulate filler dispersed in a binder material such that the filler particles are substantially in intimate contact comprising the further steps of

compressing carbon black on to a metal foil;

impregnating this layer of carbon with a liquid mixture comprising

polyethylene glycol, glycerol, propylene carbonate and hexamethylene dissocyarate;

comprising and curing.

35. A process for the preparation of a high surface area electrode comprising the steps of

preparing a composite comprised of

an electronically conductive particulate filler dispersed in a binder material such that the filler particles are substantially in intimate contact, comprising the further steps of

compressing carbon black onto a metal foil,

impregnating this layer of carbon with a liquid mixture comprising

sulphoethyl methacrylate lithium salt and octaoxyethylene dimethacrylate dissolved in propylene carbonate.