Encapsulated halogen bleaches and methods of preparation and use

• US 5,213,705 A
• Filed: 02/25/1991
• Issued: 05/25/1993
• Est. Priority Date: 04/30/1985
• Status: Expired due to Term

• Current Assignee: Ecolab, Inc.
• Original Assignee: Ecolab, Inc.
• Inventors: Olson, Keith E.
• Primary Examiner(s): Chaudhuri, Olik
• Assistant Examiner(s): EVERHART, CARIDAD
• Application Number:
  US07/660,176
• Time in Patent Office: 820 Days
• Field of Search: 252/91, 252/174.13, 252/186.35, 252/186.36, 252/535, 252/554, 252/95, 427/213, 427/212, 427/214, 427/215, 427/220
• US Class Current: 252/186.35
• CPC Class Codes: C11D 17/0039 Coated compositions or coated components in the compositions, (micro)capsules
• CPC Class Codes: C11D 3/395 Bleaching agents

Abstract

An active-halogen bleach such as dichloroisocyanurate dihydrate encapsulated in a coating of a synthetic detergent such as sodium octyl sulfonate. The capsule may further comprise an initial coating of a soluble inorganic detergent builder or filler. The capsule is table in highly alkaline environments such as detergent composition.

Claims

1. An encapsulate halogen bleach composition that is chemically stable and compatible when combined with an alkaline cleaning composition and does not interfere with the action of the cleaning composition, the capsule comprising:

(a) a halogen bleach core; and

(b) an encapsulating coating effective to isolate the core, wherein the core comprises about 20 to 90 wt-% of the encapsulate composition and the coating comprises about 10 to 80 wt-% of the encapsulate composition, said coating comprising,

(i) a first coating layer of an inorganic agent coated over said bleach core, and

(ii) a second coating layer of an n-alkyl sulfonate compound coated over said inorganic agent.

2. The composition of claim 1 wherein the core comprises a source of active-chlorine.

3. The composition of claim 1 wherein the core comprises a dichloroisocyanurate compound.

4. The composition of claim 1 wherein the n-alkyl sulfonate compound comprises an alkali metal octyl sulfonate.

5. The composition of claim 1 wherein:

(a) the core comprises about 30 to 70 wt. % of a dichloroisocyanurate dihydrate compound based upon the composition; and

(b) the second coating layer comprises an octyl sulfonate compound.

6. The composition of claim 1 wherein:

(a) the core comprises about 40 to 55 wt. % of a dichloroisocyanurate dihydrate based upon the composition; and

(b) the coating comprises a sodium octyl sulfonate.

7. An encapsulate chlorine bleach composition that is chemically stable and compatible when combined with an alkaline cleaning composition, and does not interfere with the action of the cleaning composition, the capsule comprising a chlorine bleach core and two encapsulating coatings effective to isolate the core, wherein the core comprises about 20 to 89.5 wt-% of the encapsulate composition, the first coating, which is a soluble inorganic coating agent comprises about 0.5 to 50 wt-% of the encapsulate composition, and the second coating comprises an n-alkyl sulfonate compound at a concentration of about 10 to 70 wt-% of the encapsulate composition.

8. The composition of claim 7 wherein the core comprises a source of active-chlorine.

9. The composition of claim 7 wherein the core comprises a dichloroisocyanurate compound.

10. The composition of claim 7 wherein the first coating comprises a builder salt.

11. The composition of claim 7 wherein the first coating is a member selected from the group consisting of an alkali metal phosphate compound, sodium sulfate and mixtures thereof.

12. The composition of claim 7 wherein the n-alkyl sulfonate comprises an alkali metal octyl sulfonate.

13. The composition of claim 7 wherein:

(a) the core comprises about 35 to 60 wt. % of a dichloroisocyanurate dihydrate based upon the composition;

(b) the first coating comprises about 15 to 45 wt. % of a mixture of an alkyl metal tripolyphosphate and sodium sulfate based upon the composition; and

(c) the second coating comprises about 10 to 35 wt. % of an n-alkyl sulfonate based upon the composition.

14. A chlorine bleach composition compatible in a cleaning composition, that neither degrades the active components of the cleaning composition or interferes with their action, which consists of an encapsulated composition having a core and two encapsulating coatings effective to isolate the active halogen, wherein:

(a) the core comprises a particle of dichloroisocyanurate dihydrate having a particle size of_-- 10 to 60 U.S. mesh;

(b) the first coating consists of about 15 to 45 wt. % of a mixture of about 10 to 40 wt. % sodium tripolyphosphate and about 60 to 90 wt. % sodium sulfate based upon the composition; and

(c) the second coating consists of about 10 to 35 wt. % of a sodium octyl sulfonate based upon the composition.

15. A process for encapsulating a halogen bleach which comprises the steps of:

(a) forming a fluidized bed of an active halogen core material comprising a source of active halogen having a particle size of about 8 to 120 U.S. mesh;

(b) forming a first coating of a soluble inorganic coating agent on the particles in the bed; and

(c) forming a second coating of an n-alkyl sulfonate compound which is substantially inert with respect to the halogen bleach core, on the particles in the bed;

whereby the coating renders the halogen bleach core stable in an alkaline environment.

16. The process of claim 15 wherein the second coating is formed by spraying the n-alkyl sulfonate compound to form the coating.

17. The process of claim 15 wherein the core comprises a source of active chlorine.

18. The process of claim 15 wherein the coating comprises an alkali metal octyl sulfonate.

19. The process of claim 15 wherein the encapsulated halogen bleach is maintained at an elevated temperature after addition of the coating, in order to evaporate any free moisture left in the encapsulate.

20. The process of claim 15 wherein:

p1 (a) the core comprises a dichloroisocyanurate compound;

(b) the coating comprises an n-alkyl sulfonate compound; and

(c) the fluidized bed is maintained at about 35°

to 100°

C.

21. The process of claim 15 wherein:

(a) the core comprises about 65 to 90 wt. % of a dichloroisocyanurate dihydrate based upon the composition;

(b) the coating comprises about 10 to 35 wt. % of an n-alkyl sulfonate compound based upon the composition; and

(c) the fluidized bed is maintained at about 40°

to 80°

C.

22. A process for encapsulating a halogen bleach which comprises the steps of:

(a) forming a fluidized bed of a core material, wherein the core material comprises an active halogen component having a particle size of about 8 to 120 U.S. mesh;

(b) forming a first coating of a soluble inorganic coating agent, which is substantially inert with respect to the halogen bleach core, on the particles in the bed; and

(c) forming a second coating of an n-alkyl sulfonate compound, which is substantially inert with respect to the halogen bleach core and the first coating, on the particles in the bed,

whereby the coating renders the halogen bleach core stable in an alkaline environment.

23. The process of claim 22 wherein the coating are formed by spraying.

24. The process of claim 22 wherein the core comprises a source of active chlorine.

25. The process of claim 22 wherein the first coating is a member selected from the group consisting of alkali metal phosphate components, sodium sulfate and mixtures thereof.

26. The process of claim 22 wherein the encapsulated halogen bleach is maintained at an elevated temperature after addition of the second coating in order to evaporate any free moisture left in the encapsulate.

27. The process of claim 22 wherein:

(a) the core comprises about 30 to 60 wt. % of a dichloroisocyanurate dihydrate based upon the composition;

(b) the first coating comprises about 15 to 40 wt. % of a mixture of an alkali metal tripolyphosphate and sodium sulfate based upon the composition;

(c) the second coating comprises about 10 to 35 wt. % of an n-alkyl sulfonate based upon the composition,

(d) the fluidized bed is maintained at about 40°

to 80°

C. while the first coating is applied; and

(e) the fluidized bed is maintained at about 40°

to 70°

C. while the second coating is applied.

28. The process of claim 22 wherein:

(a) the core comprises about 30 to 60 wt. % of a 10 to 40 U.S. mesh size particle of dichloroisocyanurate based upon the composition;

(b) the first coating comprises about 15 to 45 wt. % of a mixture of about 10 to 40 wt. % sodium tripolyphosphate and about 60 to 90 wt. % sodium sulfate based upon the composition;

(c) the second coating comprises about 10 to 35 wt. % of a sodium octyl sulfonate based upon the composition; and

(d) the fluidized bed is maintained at about 40°

to 80°

C. while both coats are applied.