Preprinted retroreflective highway sign and method for making the sign

• US 5,213,872 A
• Filed: 04/19/1991
• Issued: 05/25/1993
• Est. Priority Date: 04/19/1991
• Status: Expired due to Term

• Current Assignee: Avery Dennison Corporation
• Original Assignee: Stimsonite Corp. (Avery Dennison Corporation)
• Inventors: Pricone, Robert M., Zanotti, Richard, Szopinski, Alex A.
• Primary Examiner(s): Ryan, Patrick J.
• Assistant Examiner(s): KRYNSKI, WILLIAM A
• Application Number:
  US07/687,989
• Time in Patent Office: 767 Days
• Field of Search: 359/514, 359/523, 359/530, 359/533, 359/534, 359/535, 359/536, 359/537, 359/538, 359/539, 359/540, 428/195, 428/343, 428/76
• US Class Current: 428/195.1
• CPC Class Codes: B32B 2264/102 Oxide or hydroxide
• CPC Class Codes: B32B 2307/416 Reflective
• CPC Class Codes: B32B 2590/00 Signboards, advertising panels, road signs
• CPC Class Codes: B32B 27/12 next to a fibrous or filamentary layer
• CPC Class Codes: B32B 27/18 characterised by the use of special additives
• CPC Class Codes: B32B 27/308 comprising acrylic (co)polymers
• CPC Class Codes: B32B 3/30 characterised by a layer formed with recesses or projections, e.g. hollows, grooves, protuberances, ribs apertured layer B32B3/266; layer with cavities or internal voids B32B3/26
• CPC Class Codes: B32B 7/06 permitting easy separation
• CPC Class Codes: B32B 7/12 using interposed adhesives or interposed materials with bonding properties
• CPC Class Codes: G09F 13/16 Signs formed of or incorporating reflecting elements or surfaces, e.g. warning signs having triangular or other geometrical shape
• CPC Class Codes: Y10S 428/913 Material designed to be responsive to temperature, light, moisture
• CPC Class Codes: Y10T 156/1023 Surface deformation only [e.g., embossing]
• CPC Class Codes: Y10T 428/24802 Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
• CPC Class Codes: Y10T 428/31507 Of polycarbonate

Abstract

A retroreflective unitary laminate material having an acrylic layer on which a sign legend is printed and which is covered by an ultraviolet absorbent overlay that has poor affinity for paint and low surface tension thus protecting the printed sign from deterioration due to weathering and enabling the sign to be readily cleansed without damaging the printed signs, and minimizing water beading on the sign front face.

Claims

1. A unitary retroreflective composite preprinted sheeting material for use in sign-making, comprising:

(a) a first resinous material having first and second oppositely facing surfaces;

(b) a second resinous material overlaying and laminated to said first surface of said first resinous material;

(c) a printed legend disposed between said laminated first and second resinous materials; and

(d) retroreflective optical elements provided in juxtaposition to said second surface of said first resinous material to form a preprinted retroreflective sheet material of unitary laminate for use in making signs.

2. The sheeting material set forth in claim 1, wherein said legend is preprinted on said first surface of said first resinous material.

3. The sheeting material set forth in claim 1, wherein said legend is preprinted on said second resinous material providing said overlay.

4. The sheeting material set forth in claim 1, wherein said retroreflective optical elements comprise a plurality of cube corner retroreflecting elements formed on said second surface of said first resinous material.

5. The sheeting material set forth in claim 1, wherein said second resinous material overlaying said first resinous material comprises a fluorinated resin which resists paint adherence, thereby enabling said sheeting material to be cleansed without damaging the preprinted legend.

6. The sheeting material set forth in claim 1, wherein said second resinous material comprises an ultraviolet absorbent material.

7. The sheeting material set forth in claim 1, wherein said second resinous material includes a material ahving low surface energy to enable reduction in water beading on the outer surface of said sign-making material thereby reducing "dew-out" conditions.

8. The sheeting amterial set forth in claim 1, wherein said retroreflective optical elements comprise a plurality of cube corner retroreflecting elements formed on said second surface of said first resinous material;

and said second resinous material comprises an ultraviolet absorbent, fluorinated resin which resists paint adherence, thereby enabling said sheeting material to be cleansed without damaging the preprinted legend.

9. The sign making material as in claim 1, wherein the retroreflective material further includes:

a layer of hydrophobic granular silica material placed on at least a portion of the embossed optical pattern for enhancing reflectivity;

a back coating applied to and protecting the silica material and any exposed portion of the embossed material;

an adhesive on the exposed side of the coating to allow the reflective material to be attached to a desired base; and

a removable release sheet on the adhesive.

10. The material as in claim 9 wherein the ultraviolet absorbing overlay is a fluorinated resin about 2 mil in thickness and which resists paint adherence, thereby to enable the sign to be cleansed without damaging the printed sign and that protects the sign from weathering.

11. The material as in claim 10, wherein the resinous sheeting material is a thermoplastic acrylic material and is about 6 mil in thickness.

12. The material as in claim 11 wherein the retroreflective material is formed in a continuous sheet having a plurality of successively printed legends thereon.

13. A reflective sign comprising:

a substrate forming the base layer of the sign; and

a unitary laminate of retroreflective material adhesively attached to the substrate, the unitary laminate comprising;

a resinous sheeting material;

a legend printed on the forward facing surface of the resinous material;

an ultraviolet absorbing overlay laminated to the forward surface of the resinous material having the printed legend thereon;

a cube corner type optical pattern embossed upon the rear surface of the resinous sheeting material;

a layer of hydrophobic granular silica material over at least a portion of the embossed pattern;

a back coating applied to the silica material and to any exposed areas of the embossed rear surface to provide a flat, smooth surface; and

an adhesive means for attaching the unitary laminate of retroreflective material to the substrate.

15. A reflective sign as in claims 13 or 14 wherein the ultraviolet absorbing overlay is about 2 mil in thickness and resists paint adherence and is of low surface tension to enable the sign to be cleansed without damaging the printed sign and to minimize water beading on the sign front face.

16. A reflective sign as in claim 15 wherein the resinous sheeting material is a thermoplastic material of about a 6 mil in thickness.

17. A reflective sign as in claim 16 wherein the thermoplastic material is acrylic.

14. A backing means comprising:

a substrate forming the base layer of the sign; and

a unitary laminate of retroreflective material adhesively attached to the substrate, the unitary laminate comprising;

a resinous sheeting material;

a legend printed on the forward facing surface of the resinous material;

an ultraviolet absorbing overlay laminated to the forward surface of the resinous material having the printed legend thereon;

a cube corner type optical pattern embossed upon the rear surface of the resinous sheeting material;

a layer of backing material over at least a portion of the embossed pattern;

an adhesive means for attaching the unitary laminate of retroreflective material to the substrate.