Coating compositions which may be ambient cured

• US 5,214,086 A
• Filed: 09/04/1991
• Issued: 05/25/1993
• Est. Priority Date: 09/04/1991
• Status: Expired due to Term

• Current Assignee: BASF Corporation (BASF SE)
• Original Assignee: BASF Corporation (BASF SE)
• Inventors: Guyomard, Daniel, Mormile, Patrick J., Richards, Bradley M., Shepler, Stewart, Dantiki, Sudhakar
• Primary Examiner(s): Michl, Paul R.
• Assistant Examiner(s): Asinovsky, Olga
• Application Number:
  US07/754,900
• Time in Patent Office: 629 Days
• Field of Search: 524/237, 524/188
• US Class Current: 524/237
• CPC Class Codes: C08G 18/2865 Compounds having only one primary or secondary amino group; Ammonia
• CPC Class Codes: C08G 18/3256 Reaction products of polyamines with aldehydes or ketones
• CPC Class Codes: C08G 18/6229 Polymers of hydroxy groups containing esters of acrylic or methacrylic acid with aliphatic polyalcohols
• CPC Class Codes: C08G 18/6233 the monomers or polymers being esterified with carboxylic acids or lactones
• CPC Class Codes: C08G 18/6254 Polymers of alpha-beta ethylenically unsaturated carboxylic acids and of esters of these acids containing hydroxy groups
• CPC Class Codes: C08G 18/6529 Compounds of group C08G18/3225 or polyamines of C08G18/38
• CPC Class Codes: C08G 18/792 formed by oligomerisation of aliphatic and/or cycloaliphatic isocyanates or isothiocyanates
• CPC Class Codes: C08G 18/798 containing urethdione groups

Abstract

Coating Compositions are disclosed which may be ambient cured and are especially useful in refinish paint compositions. The Coating Compositions comprise at least one hydroxy functional resin, at least one isocyanate functional resin and a aldimine or ketimine.

Claims

1. A coating composition comprising the following:

a) at least one hydroxy functional resin,

b) at least one isocyanate functional resin and

c) a compound having the structure ##STR8## wherein n is 0 to 4,

R₁ is --H, or alkyl, aryl, cycloaliphatic or substituted alkyl, aryl, or cycloaliphatic group,

R₂ is --H, or alkyl, aryl, cycloaliphatic or substituted alkyl, aryl, or cycloaliphatic group, and

R₃ is aliphatic, aromatic, arylaliphatic or cycloaliphatic group, which may also contain O, N, S or Si.

R₁ and R₂ may be the same or different.

2. A coating composition of claim 1 which is cured at ambient temperature.

3. A coating composition of claim 1 which is baked to cure.

4. A coating composition of claim 1 that additionally contains at least one pigment.

5. A coating composition of claim 1 wherein the hydroxy functional resin is an acrylic resin with a hydroxyl number in the range of 20-200.

6. A coating composition of claim 1 wherein the hydroxy functional resin is an acrylic resin grafted with natural or synthetic fatty acid ester and the resulting resin having a hydroxyl number in the range of 20-200.

7. A coating composition of claim 1 wherein the hydroxyl functional resin is a saturated or unsaturated polyester resin with a hydroxyl number of 20-200.

8. A coating composition of claim 1 wherein the isocyanate functional resin is chosen from aliphatic, aromatic or cycloaliphatic mono-, or di- isocyanates, triisocyanurates, uretdiones, biurets or isocyanate functional prepolymers.

9. A coating composition of claim 8 wherein the isocyanate functional resin is a dimer or trimer of hexamethylene diisocyanate or a blend of both.

10. A coating composition comprising the following:

a) at least one hydroxy functional resin,

b) at least one isocyanate functional resin,

c) a compound having the structure ##STR9## wherein n is 0 to 4,

R₁ is --H, or alkyl, aryl, cycloaliphatic or substituted alkyl, aryl, or cycloaliphatic group,

R₂ is --H, or alkyl, aryl, cycloaliphatic or substituted alkyl, aryl, or cycloaliphatic group, and

R₃ is aliphatic, aromatic, arylaliphatic or cycloaliphatic group, which may also contain O, N, S or Si.

R₁ and R₂ may be the same or different and

d) a secondary amine functional reactive diluent.

11. A coating composition of claim 10 which is cured at ambient temperature.

12. A coating composition of claim 10 which is baked to cure.

13. A coating composition of claim 10 wherein the secondary amine functional reactive diluent contains, on average, 2 or more secondary amine groups per molecule.

14. A coating composition of claim 10 that additionally contains at least one pigment.

15. A coating composition of claim 10 wherein the hydroxy functional resin is an acrylic resin with a hydroxyl number in the range of 20-200.

16. A coating composition of claim 10 wherein the hydroxy functional resin is an acrylic resin grafted with natural or synthetic fatty acid ester and the resulting resin having a hydroxyl number in the range of 20-200.

17. A coating composition of claim 10 wherein the hydroxyl functional resin is a saturated or unsaturated polyester resin with a hydroxyl number of 20-200.

18. A coating composition of claim 10 wherein the isocyanate functional resin is chosen from aliphatic, aromatic or cycloaliphatic mono-, or di- isocyanates, triisocyanurates, uretdiones, biurets or isocyanate functional prepolymers.

19. A coating composition of claim 18 wherein the isocyanate functional resin is a dimer or trimer of hexamethylene diisocyanate or a blend of both.

20. A coating composition comprising the following:

a) at least one hydroxy functional resin,

b) at least one isocyanate functional resin,

c) a compound having the structure ##STR10## wherein n is 0 to 4,

R₁ is --H, or alkyl, aryl, cycloaliphatic or substituted alkyl, aryl, or cycloaliphatic group,

R₂ is --H, or alkyl, aryl, cycloaliphatic or substituted alkyl, aryl, or cycloaliphatic group, and

R₃ is aliphatic, aromatic, arylaliphatic or cycloaliphatic group, which may also contain 0, N, S or Si.

R₁ and R₂ may be the same or different and

d) an hydroxyl functional reactive diluent.

21. A coating composition of claim 20 which is cured at ambient temperature.

22. A coating composition of claim 20 which is baked to cure.

23. A coating composition of claim 20 wherein the hydroxyl functional reactive diluent contains, on average, 2 or more hydroxyl groups per molecule.

24. A coating composition of claim 20 that additionally contains at least one pigment.

25. A coating composition of claim 20 wherein the hydroxy functional resin is an acrylic resin with a hydroxyl number in the range of 20-200.

26. A coating composition of claim 20 wherein the hydroxy functional resin is an acrylic resin grafted with natural or synthetic fatty acid ester and the resulting resin having a hydroxyl number in the range of 20-200.

27. A coating composition of claim 20 wherein the hydroxyl functional resin is a saturated or unsaturated polyester resin with a hydroxyl number of 20-200.

28. A coating composition of claim 20 wherein the isocyanate functional resin is chosen from aliphatic, aromatic or cycloaliphatic mono-, or di- isocyanates, triisocyanurates, uretdiones, biurets or isocyanate functional prepolymers.

29. A coating composition of claim 28 wherein the isocyanate functional resin is a dimer or trimer of hexamethylene diisocyanate or a blend of both.

30. A coating composition comprising the following:

a) at least one hydroxy functional resin,

b) at least one isocyanate functional resin,

c) a compound having the structure ##STR11## wherein n is 0 to 4,

R₁ is --H, or alkyl, aryl, cycloaliphatic or substituted alkyl, aryl, or cycloaliphatic group,

R₂ is --H, or alkyl, aryl, cycloaliphatic or substituted alkyl, aryl, or cycloaliphatic group, and

R₃ is aliphatic, aromatic, arylaliphatic or cycloaliphatic group, which may also contain O, N, S or Si.

R₁ and R₂ may be the same or different and

d) an oxazolidine functional reactive diluent.

31. A coating composition of claim 30 which is cured at ambient temperature.

32. A coating composition of claim 30 which is baked to cure.

33. A coating composition of claim 30 that additionally contains at least one pigment.

34. A coating composition of claim 30 wherein the hydroxy functional resin is an acrylic resin with a hydroxyl number in the range of 20-200.

35. A coating composition of claim 30 wherein the hydroxy functional resin is an acrylic resin grafted with natural or synthetic fatty acid ester and the resulting resin having a hydroxyl number in the range of 20-200.

36. A coating composition of claim 30 wherein the hydroxyl functional resin is a saturated or unsaturated polyester resin with a hydroxyl number of 20-200.

37. A coating composition of claim 30 wherein the isocyanate functional resin is chosen from aliphatic, aromatic or cycloaliphatic mono-, or di- isocyanates, triisocyanurates, uretdiones, biurets or isocyanate functional prepolymers.

38. A coating composition of claim 37 wherein the isocyanate functional resin is a dimer or trimer of hexamethylene diisocyanate or a blend of both.

39. A coating composition comprising the following:

a) at least one hydroxy functional resin,

b) at least one isocyanate functional resin,

c) the reaction product of one mole of Isophorone Diamine with 2 moles of Isobutyraldehyde and

d) a secondary amine functional reactive diluent.

40. A coating composition of claim 39 wherein the isocyanate functional resin is a dimer or trimer of hexamethylene diisocyanate or a blend of both.