Protective and decorative sheet material having a transparent topcoat

• US 5,215,811 A
• Filed: 12/20/1990
• Issued: 06/01/1993
• Est. Priority Date: 04/28/1988
• Status: Expired due to Term

• Current Assignee: Avery Dennison Corporation
• Original Assignee: Eastman Kodak Company
• Inventors: Hartman, Marvis E., Reafler, Gerald G.
• Primary Examiner(s): Thibodeau, Paul J.
• Assistant Examiner(s): Le, Hoa T.
• Application Number:
  US07/601,804
• Time in Patent Office: 894 Days
• Field of Search: 428/480, 428/483, 428/31, 428/328, 428/336, 428/343, 428/354, 428/423.3, 428/423.7, 428/424.2, 428/908.8, 428/212, 428/213, 428/216
• US Class Current: 428/212
• CPC Class Codes: B29C 51/14 using multilayered preforms or sheets
• CPC Class Codes: B29L 2007/002 Panels; Plates; Sheets
• CPC Class Codes: B29L 2031/722 Decorative or ornamental articles
• CPC Class Codes: B32B 27/00 Layered products comprising a layer of synthetic resin fibrous or filamentary layer made of a synthetic resin B32B5/02; particulate layer made of a synthetic resin B32B5/16; foamed layer made of a synthetic resin B32B5/18
• CPC Class Codes: Y10T 428/24942 including components having same physical characteristic in differing degree
• CPC Class Codes: Y10T 428/2495 Thickness [relative or absolute]
• CPC Class Codes: Y10T 428/24975 No layer or component greater than 5 mils thick
• CPC Class Codes: Y10T 428/256 Heavy metal or aluminum or compound thereof
• CPC Class Codes: Y10T 428/265 1 mil or less
• CPC Class Codes: Y10T 428/2848 Three or more layers
• CPC Class Codes: Y10T 428/31554 Next to second layer of polyamidoester
• CPC Class Codes: Y10T 428/31565 Next to polyester [polyethylene terephthalate, etc.]
• CPC Class Codes: Y10T 428/31573 Next to addition polymer of ethylenically unsaturated monomer

Abstract

A protective and decorative polymeric sheet material for bonding to substrates by thermoforming comprises a flexible carrier film, a paint layer on one surface of the carrier film containing a colorant or light reflective flakes or both; and a transparent topcoat overlying the paint layer. At least a portion of the transparent topcoat is a rubbery cushioning layer formed of a non-crosslinked, or lightly crosslinked polymeric composition of low Tg.

The sheet material has an unextended state and is heat softenable to a plastic state in which it is extendable to an extended state at least 50% greater in area than the unextended state. The paint and topcoat layers have substantially uniform quality and appearance in both the unextended and extended states. In a preferred embodiment, the thickness of the transparent topcoat is at least 0.1 millimeter. The thick topcoat provides improved retention of gloss and distinctness of image when the sheet material is stretched. As compared with sheet material of which the topcoat layer consists entirely of crosslinked polymer of relatively high Tg, the sheet material of the invention shows a reduced tendency to peel back from the substrate when cut and subjected to high temperature.

Claims

1. A protective and decorative sheet material for use in a thermoforming process in which it is stretched and bonded to a three-dimensional substrate, said material comprising:

a flexible and stretchable, thermoformable polymeric carrier film;

a stretchable, thermoformable paint layer adhered to one surface of said carrier film;

said paint layer comprising a polymeric binder and a colorant or substantially flat light reflective flakes or both;

a transparent polymeric topcoat overlying said paint layer, said topcoat comprising (a) a rubbery cushioning layer of a stretchable and thermoformable polymeric composition which is non-crosslinked or of low crosslink density and has a glass transition temperature below 20°

C. and (b) a crosslinked surface layer of higher glass transition temperature; and

said sheet material having an unextended state prior to being thermoformed;

said sheet material being heat softenable to a state in which it is thermoformable over irregular surfaces to an extended state having an area at least 50% greater than that of the unextended state.

2. The sheet material of claim 1 wherein said carrier film is of substantially uniform thickness.

3. The sheet material of claim 2 wherein the paint layer contains light reflective flakes and the thickness of the topcoat is at least about 0.1 millimeter.

4. The sheet material of claim 3 wherein the flakes are metallic flakes.

5. The sheet material of claim 1 wherein the crosslinked layer is thinner than the cushioning layer and has a glass transition temperature of at least about 40°

C.

6. The sheet material of claim 5 wherein the surface layer is a clear layer of a crosslinked polyurethane.

7. The sheet material of claim 6 including a pressure-sensitive adhesive layer on the opposite side of said carrier film from said paint layer.

8. The sheet material of claim 7 including a thin adhesion promoting layer between said carrier film and said paint layer.

9. The sheet material of claim 1 wherein said carrier film comprises a blend of copolyesters based on poly(1,4-cyclohexylenedimethylene terephthalate) and styrene maleic anhydride copolymers.

10. The sheet material according to claim 1 wherein the paint layer contains no flakes and the thickness of the topcoat is less than 0.1 millimeter.

11. The sheet material of claim 1 wherein the topcoat has a thickness of at least 0.1 millimeter, said topcoat comprising (a) a cushioning layer formed of a non-pigmented polymer of substantially the same composition as the polymeric binder of the paint layer and (b) overlying the cushioning layer a clear crosslinked polymeric layer which is thinner than and of higher glass transition temperature than the cushioning layer.