Encapsulated electrochromic device and method for making same

• US 5,216,536 A
• Filed: 11/26/1991
• Issued: 06/01/1993
• Est. Priority Date: 11/26/1991
• Status: Expired due to Fees

• Current Assignee: Donnelly Corporation (Magna International Incorporated)
• Original Assignee: Donnelly Corporation (Magna International Incorporated)
• Inventors: Agrawal, Anoop, Cronin, John P., Zhang, Raymond L.
• Primary Examiner(s): Arnold, Bruce Y.
• Assistant Examiner(s): Lester, Evelyn A.
• Application Number:
  US07/798,622
• Time in Patent Office: 553 Days
• Field of Search: 359/265, 359/272, 359/274
• US Class Current: 359/274
• CPC Class Codes: G02F 1/1533 structural features not otherwise provided for
• CPC Class Codes: G02F 2001/1536 additional, e.g. protective, layer inside the cell

Abstract

The performance and operating characteristics of electrochromic devices may be improved by the incorporation of a moisture control layer comprised of either water reservoir material or water scavenger material in conjunction with a moisture permeable intermediate barrier layer within the device. The water reservoir material provides a source of water for those electrochromic stacks which require water for proper operation. For stacks which require protection from moisture, water scavenger material may be utilized. A moisture permeable intermediate barrier layer separates the moisture control layer from the electrochromic stack. The invention is also directed towards methods of incorporating such layers into electrochromic devices during their manufacture.

Claims

1. An electrochromic device which can be alternatively darkened or lightened comprising:

a substrate layer;

an electrochromic stack deposited upon said substrate layer;

a water resistant, moisture permeable intermediate barrier layer overlying said electrochromic stack;

a moisture control layer comprising one of a water reservoir material and a water scavenger material, said water reservoir material being hydrophilic in nature such that if sufficiently hydrated said water reservoir material may provide a source of water for said electrochromic device, said water scavenger material providing means to collect and bind water within said electrochromic device, said moisture control layer overlying said intermediate layer; and

means for hermetically sealing said electrochromic device.

2. An electrochromic device in accordance with claim 1, in which said sealing means comprises a primary seal, overlying said moisture control layer and a secondary seal applied over and in contact with said primary seal, said secondary seal providing means for additional protection from environmental and mechanical damage.

3. An electrochromic device in accordance with claim 1 wherein said sealing means comprises a backing plate overlying said moisture control layer.

4. An electrochromic device in accordance with claim 1 wherein said moisture permeable intermediate barrier layer has a water permeability in the range of 0.005 to 10 mg/cm-mm² -day.

5. An electrochromic device in accordance with claim 1 wherein said moisture permeable intermediate barrier layer is comprised of a shock absorbing material for providing protection to said electrochromic stack.

6. An electrochromic device in accordance with claim 1 wherein said moisture permeable intermediate barrier layer is comprised of a material curable upon exposure to at least one of ultraviolet light, heat, infrared radiation, and microwaves.

7. An electrochromic device in accordance with claim 1 wherein said moisture permeable intermediate barrier layer is applied to a thickness of about 0.001 to 5 mm.

8. An electrochromic device in accordance with claim 1 wherein said moisture permeable intermediate barrier layer is comprised of one or more materials selected from the group consisting of;

organo-ceramics, epoxies, urethanes, ureas, acrylics, polyesters, silicones, vinyls, amides, imides and sulfones.

9. An electrochromic device in accordance with claim 1 utilizing said water reservoir material, wherein said water reservoir material has an initial water content in the range of about 0.005 mg to 5 mg of water per cm² of area of said electrochromic stack and said reservoir material having a thickness of about 0.002 mm to about 5 mm.

10. An electrochromic device in accordance with claim 1 utilizing said water reservoir material, wherein said water reservoir material is applied to a thickness of about 0.002 mm to about 5 mm.

11. An electrochromic device in accordance with claim 1 utilizing said water reservoir material, wherein said water reservoir material is comprised of a hydrophilic filler dispersed within at least one of a thermosetting and a thermoplastic resin.

12. A water reservoir material in accordance with claim 11, wherein said water reservoir material is comprised of a cross-linked polyacrylamide in a silicone resin.

13. An electrochromic device in accordance with claim 1 utilizing said water reservoir material, wherein said water reservoir material is comprised of a hydrophilic polymeric material dispersed within a standard resin;

said hydrophilic polymeric material comprising at least one of the following hydrophilic groups;

amines, amides, hydroxides, carboxylic acids, acids, sulfones and ethylene-oxide based polyethers.

14. A water reservoir material in accordance with claim 13, wherein said water reservoir material is comprised of a water soluble amine dispersed in a standard epoxy resin.

15. An electrochromic device in accordance with claim 1 utilizing said water scavenger material, wherein said water scavenger material absorbs up to 50% of said material'"'"'s weight of water.

16. An electrochromic device in accordance with claim 1 utilizing said water scavenger material, wherein said water scavenger material is applied to a thickness of about 0.002 mm to about 5 mm.

17. An electrochromic device in accordance with claim 1 utilizing said water scavenger material, wherein said water scavenger material is comprised of one or more materials selected from the group;

epoxies, urethanes, ureas, acrylics, polyesters, amides, silicones, vinyls and imides.

18. A method of assembling an electrochromic device which can be alternatively darkened or lightened comprising:

forming an electrochromic stack onto a substrate;

depositing a water resistant, moisture permeable intermediate barrier layer onto said electrochromic stack whereby said intermediate layer is left uncured in its liquid or semisolid state, thereby forming a first half of said electrochromic device;

depositing a moisture control layer comprising one of a water reservoir material and a water scavenger material, said water reservoir material being hydrophilic in nature such that if sufficiently hydrated said water reservoir material may provide a source of water for said electrochromic device, said water scavenger material providing means to collect and bind water within said electrochromic device, onto the surface of a backing plate;

curing said moisture control layer deposited upon said backing plate to form a second half of said electrochromic device;

mating said first half and second half of said electrochromic device by contacting the exposed surface of said uncured intermediate layer of said first half to the exposed surface of said cured moisture control layer of said second half;

curing said intermediate layer; and

hermetically sealing said electrochromic device by applying a seal material onto said backing plate to constitute a primary seal.

19. A method of assembling an electrochromic device in accordance with claim 18, such that subsequent to mating of said halves, said moisture permeable intermediate barrier layer is cured by exposure to at least one of ultraviolet light, heat, infrared radiation, and microwaves.

20. A method of assembling an electrochromic device in accordance with claim 18 utilizing said water reservoir material, wherein said water reservoir material is hydrated by exposure to a high humidity environment.

21. A method of assembling an electrochromic device in accordance with claim 18 further comprising applying a secondary seal onto said primary seal.

22. A method of assembling an electrochromic device which can be alternatively darkened or lightened comprising:

forming an electrochromic stack onto a substrate;

depositing a water resistant, moisture permeable intermediate barrier layer onto said electrochromic stack;

applying a moisture control layer comprising one of a water reservoir material and a water scavenger material, said water reservoir material being hydrophilic in nature such that if sufficiently hydrated said water reservoir material may provide a source of water for said electrochromic device, said water scavenger material providing means to collect and bind water within said electrochromic device, onto said intermediate layer; and

hermetically sealing said electrochromic device.

23. A method of assembling an electrochromic device in accordance with claim 22, wherein said hermetically sealing step comprises incorporating a backing plate over said moisture control layer.

24. A method of assembling an electrochromic device in accordance with claim 23 utilizing said water reservoir material wherein said water reservoir material is hydrated by exposure to a high humidity environment.

25. A method of assembling an electrochromic device in accordance with claim 22 wherein said hermetically sealing step comprises applying a primary seal to said moisture control layer and applying a secondary seal over and in contact with said primary seal, said secondary seal providing additional protection from environmental and mechanical damage.

26. A method of assembling an electrochromic device in accordance with claim 25 utilizing said water reservoir material, wherein said water reservoir material is hydrated by exposure to a high humidity environment.