Two-stage mat forming preforming and molding process

• US 5,217,654 A
• Filed: 01/30/1992
• Issued: 06/08/1993
• Est. Priority Date: 01/30/1992
• Status: Expired due to Term

• Current Assignee: The C.A. Lawton Co.
• Original Assignee: C A Lawton Company
• Inventors: Buckley, Daniel T.
• Primary Examiner(s): AFTERGUT, KAREN K
• Application Number:
  US07/828,310
• Time in Patent Office: 495 Days
• Field of Search: 264/257, 264/258, 264/22, 264/25, 264/27, 264/103, 264/134, 264/138, 264/145, 264/160, 264/309, 264/135, 264/136, 264/259, 264/266, 264/279, 264/294, 264/324, 264/325 , 264/328.1, 522/4, 522/6, 522/100-103, 522/170, 156/166
• US Class Current: 264/478
• CPC Class Codes: B29C 43/04 using movable moulds
• CPC Class Codes: B29C 43/14 in several steps
• CPC Class Codes: B29C 70/345 using matched moulds
• CPC Class Codes: B29C 70/50 for producing articles of indefinite length, e.g. prepregs, sheet moulding compounds [SMC] or cross moulding compounds [XMC]
• CPC Class Codes: B29C 70/543 Fixing the position or configuration of fibrous reinforcements before or during moulding for non-woven fabrics D04H3/08
• CPC Class Codes: B29K 2105/24 crosslinked or vulcanised
• CPC Class Codes: B29K 2105/243 Partially cured
• CPC Class Codes: C08J 3/243 Two or more independent types of crosslinking for one or more polymers
• CPC Class Codes: Y10S 264/59 Processes in which a partial cure is involved
• CPC Class Codes: Y10S 264/66 Processes of reshaping and reforming

Abstract

Glass fiber mats are made for subsequent use in preforming for an RTM or SRIM molding process, for example, such that the binder applied to the mat has two distinct curing stages. In the first stage, a partial cure is provided by visible light upon a free radical generation in response to a photoinitiator mixed in the binder in an exact ratio to give a predictable increase in viscosity to that of a semi-solid so that the fibers are sufficiently bound for subsequent handling, but not sufficient to complete a cure, while leaving a second stage ready for a final cure which is achieved by the use of a cationic-type second photoinitiator which is sensitive to ultraviolet light. During the second curing stage, the mat is formed into a three-dimensional shape of a desired end product and cured with ultraviolet radiation while still in the mold, to obtain a rigid three-dimensional preform structure.

Claims

1. A method of making a preform comprising the steps of:

(a) mixing a two-stage binder including a first binder constituent which has a photoinitiator responsive to visible light to generate free radicals which cross link and provide a viscosity sufficient to hold glass fibers together and a second binder constituent which has a cationic-type second photoinitiator responsive to ultraviolet light to generate electrons for cross linking and rendering the binder rigid;

(b) applying the two-stage binder to a mat of glass fiber reinforcement material to coat glass fibers of the mat without filling interstices among the glass fibers;

(c) exposing the two-stage binder to visible light to partially polymerize the binder such that it has a viscosity sufficient to hold the glass fibers together for subsequent handling;

(d) placing the partially polymerized binder-coated mat into a preform mold which is transparent to ultraviolet radiation;

(e) pressing the mat into a desired shape; and

(f) exposing the pressed mat to ultraviolet radiation through the mold to activate the second photoinitiator and produce a rigid three-dimensional preform.

2. The method of claim 1, wherein the step (a) of mixing a two-stage binder and the step (f) of exposing the binder-coated mat to ultraviolet radiation are further defined as:

(a1) mixing the two-stage binder to include the second constituent which is responsive for curing in response to a predetermined wavelength; and

(f1) exposing the pressed mat to ultraviolet light of the predetermined wavelength.

3. The method of claim 1, wherein the step (b) is further defined as:

(b1) applying the two-stage binder in a range of 2% to 8% by weight of the glass fiber reinforcing material.

4. The method of claim 1, wherein the step (c) of exposing the two-stage binder to visible light is further defined as:

(c1) exposing the two-stage binder to visible light until the generated free radicals are all cross linked.

5. The method of claim 1, wherein the step (f) is further defined as:

(f1) exposing the pressed mat to ultraviolet light for a predetermined time so that it continues to provide electrons for cross linking for that predetermined time.

6. A method of making a three-dimensional preform, comprising the steps:

(a) applying a coating of a two-stage binder to a mat of glass fibers to coat the fibers without filling interstices among the fibers, with a binder comprising a first constituent including a first photoinitiator which is responsive to visible light to produce free cross-linking radicals to provide a partial cure for the binder in which the binder has a viscosity sufficient to hold the glass fibers together, and be plastic and deformable, and a second constituent including a cationic-type second photoinitiator which is responsive to ultraviolet radiation to cure by producing cross-linking electrons so that the binder becomes rigid;

(b) exposing the binder-coated mat to visible light to activate the first photoinitiator of the first constituent;

(c) placing the binder-coated mat in an ultraviolet-transparent mold having a desired size and shape of the three-dimensional preform to be made;

(d) pressing the mat in the mold into the desired size and shape of the preform to be formed;

(e) exposing the pressed mat to ultraviolet radiation through the mold to activate the second photoinitiator of the second constituent to form a rigid preform; and

(f) removing the rigid preform from the mold.

7. The method of claim 6, wherein the step (a) of applying a coating to the binder is further defined as:

(a1) applying a film of the binder to the glass fibers in a range 1% to 12% by weight of the glass fibers in the mat.

8. The method of claim 7, wherein the step (a1) of applying a coating is further defined as:

(a1a) applying a film of the binder to the glass fibers in the range of 2% to 8% by weight of the glass fibers in the mat.

9. The method of claim 6, and further comprising the steps of:

(g) placing the rigid preform in a second mold which replicates a part to be formed;

(h) inserting deformable plastic material into the second mold along with the preform;

(i) pressing the preform and the deformable plastic material in the second mold to flow the plastic material such that it fills the interstices of the glass fibers of the preform;

(j) curing the plastic material to rigidize the pressed preform having the deformable plastic material therein to form a desired part; and

(k) removing the formed desired part from the second mold.