Process for preparation of modified polyphenylene ether or related polymers and the use thereof in modified high temperature rigid polymer of vinyl substituted aromatics

• US 5,219,951 A
• Filed: 09/12/1991
• Issued: 06/15/1993
• Est. Priority Date: 07/07/1988
• Status: Expired due to Term

• Current Assignee: Shell Internationale Research Maatschappij BV (Shell Plc)
• Original Assignee: Shell Internationale Research Maatschappij BV (Shell Plc)
• Inventors: Nelissen, Laurentius N. I. H., Zijderveld, Johannes M.
• Primary Examiner(s): Ziegler, Jacob
• Application Number:
  US07/758,112
• Time in Patent Office: 642 Days
• Field of Search: 525/397, 525/391, 525/390
• US Class Current: 525/391
• CPC Class Codes: C08F 283/08 on to polyphenylene oxides
• CPC Class Codes: C08G 65/485 Polyphenylene oxides
• CPC Class Codes: C08L 2666/04 Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
• CPC Class Codes: C08L 51/08 grafted on to macromolecular compounds obtained otherwise than by reactions only involving unsaturated carbon-to-carbon bonds
• CPC Class Codes: Y10S 525/905 Polyphenylene oxide

Abstract

Process for the manufacture of modified polyphenylene ether or structurally related polymers comprising:

the reaction of polyphenylene ether or structurally related polymer with a non-cyclic acid anhydride, in the presence of a pyridine derivative substituted by an amine group as catalyst, and in a vinyl substituted aromatic monomer as solvent;

modified polyphenylene ethers so obtained and use of them for the manufacture of modified high temperature rigid poly(vinyl substituted aromatic) polymer compositions.

Claims

1. Process for obtaining a blend of a modified polyphenylene ether and a poly(vinyl substituted aromatic) polymer, comprising the free radical polymerization by an initiating species of a vinyl substituted aromatic monomer in the presence of the modified polyphenylene ether obtained by a previous reaction of a compound of the formula:

##STR7## wherein R₁, R₂, R₃ and R₄ are independently a hydrogen atom, a halogen atom or an alkyl group or an alkoxy group, both being optionally substituted by halogen, cyano, hydroxy or phenyl group, and having 12 or less carbon atoms, an aryloxy or arylalkoxy group, optionally substituted by halogen, hydroxy or cyano group and having 12 or less carbon atoms, a di(alkyl)amino group or a di(alkanoyl)amido group, wherein the alkyl groups have 12 or less carbon atoms, and wherein R₁, R₂, R₃ and R₄ may represent different or the same groups in one repeating unit, and n represents an integer having a value of at least 50, with a non-cyclic acid anhydride of the general formula;

##STR8## wherein R₅ and R⁶ each independently represent an alkyl, alkenyl, aryl or aralkyl group, containing from 1 to 12 carbon atoms and optionally being substituted by hydroxy, halogen, alkyl containing 1-4 carbon atoms, in the presence of a catalyst of the formula;

##STR9## wherein R₉ and R₁₀ both represent in general non-electron withdrawing groups and wherein the symbols R₇ and R₈ represent hydrogen, halogen or lower alkyl, while R₇, R₈, R₉ and R₁₀ may represent different or the same groups in one molecule, and in a vinyl substituted aromatic monomer as solvent, said blend being made by means of bulk polymerization of said vinyl substituted aromatic monomer.

2. The product obtained by the process of claim 1.

3. Process for obtaining a blend of a modified polyphenylene ether and a poly(vinyl substituted aromatic) polymer, comprising the free radical polymerization by an initiating species of a vinyl substituted aromatic monomer in the presence of the modified polyphenylene ether obtained by a previous reaction of a compound of the formula:

##STR10## wherein R₁, R₂, R₃ and R₄ are independently a hydrogen atom, a halogen atom or an alkyl group or an alkoxy group, both being optionally substituted by halogen, cyano, hydroxy or phenyl group, and having 12 or less carbon atoms, an aryloxy or arylalkoxy group, optionally substituted by halogen, hydroxy or phenyl group, optionally substituted by halogen, hydroxy or cyano group and having 12 or less carbon atoms, a di(alkyl)amino group or a di(alkanoyl)amido group, wherein the alkyl groups have 12 or less carbon atoms, and wherein R₁, R₂, R₃ and R₄ may represent different or the same groups in one repeating unit, and n represents an integer having a value of at least 50, with a non-cyclic acid anhydride of the general formula;

##STR11## wherein R₅ and R₆ each independently represent an alkyl, alkenyl, aryl or aralkyl group, containing from 1 to 12 carbon atoms and optionally being substituted by hydroxy, halogen, alkyl containing 1-4 carbon atoms, in the presence of a catalyst of the formula;

##STR12## wherein R₉ and R₁₀ both represent in general non-electron withdrawing groups and wherein the symbols R₇ and R₈ represent hydrogen, halogen or lower alkyl, while R₇, R₈, R₉ and R₁₀ may represent different or the same groups in one molecule, and in a vinyl substituted aromatic monomer as solvent, said blend being made by means of free radical polymerization of said vinyl substituted aromatic monomer in the presence of a free radical initiator.