Method for producing molybdenum trioxide (MOO.sub.3) from raw materials that contain MOS.sub.2

• US 5,223,234 A
• Filed: 02/27/1992
• Issued: 06/29/1993
• Est. Priority Date: 12/22/1988
• Status: Expired due to Fees

• Current Assignee: Corporacion Nacional Del Cobre De Chile, Klockner-Humboldt-Deutz AG
• Original Assignee: Corporacion Nacional Del Cobre De Chile, Klockner-Humboldt-Deutz AG
• Inventors: Melcher, Gerhard, Megerle, Friedrich, Herrera, Gerardo A., Diaz, Claudio Q.
• Primary Examiner(s): Lewis, Michael
• Assistant Examiner(s): Bos, Steven
• Application Number:
  US07/842,793
• Time in Patent Office: 488 Days
• Field of Search: 423/53, 423/59, 423/606, 75/746, 75/751, 75/754, 75/623, 266/148, 266/168, 266/172, 266/201, 266/217, 266/225, 266/227, 422/129, 502/321
• US Class Current: 423/59
• CPC Class Codes: C01G 39/02 Oxides; Hydroxides
• CPC Class Codes: C01P 2006/80 Compositional purity

Abstract

A method and apparatus for producing molybdenum trioxide from raw materials containing molybdenum disulfide including melting the raw materials in an oxidizing atmosphere volatilizing a major portion of the raw materials as molybdenum trioxide with the remainder bonded in a molten slag as MoO₄ and directing an oxidizing gas onto the molten slag to convert the MoO₄ to molybdenum trioxide with the volatilization gas and the gas from the slag being united, the gas cooled and the molybdenum trioxide condensed from the gas into solid form (undesirable admixtures are separated from molybdenum trioxide raw oxides hydrometallurgically).

Claims

1. A method of producing molybdenum trioxide from raw materials containing molybdenum disulfide comprising the steps of:

melting raw materials containing molybdenum disulfide in an oxidizing atmosphere and volatilizing 50% to 90% of said molybdenum disulfide to generate an exhaust gas containing MoO₃ with a remainder of the molybdenum bonded in a molten slag as MoO₄ ;

volatilizing the MoO₄ in said molten slag by converting the MoO₄ to volatile MoO₃ while directing an oxidizing gas onto the molten slag at a pressure in the range of pO₂ =0.05 through 0.5 atm. thereby preventing the formation of MoO₂ and substantially depleting said molten slag of molybdenum with admixtures including at least Fe and Cu remaining in the slag;

uniting said exhaust gas with said volatile MoO₃ to form a united gas;

and cooling said united gas and condensing molybdenum trioxide from said united gas into solid form.

2. A method of producing molybdenum trioxide from raw materials containing molybdenum disulfide in accordance with the steps of claim 1:

wherein the molybdenum content of the slag is lowered from about 25% through 50% to less than 8% by the direction of oxidizing gas onto the molten slag.

3. A method of producing molybdenum trioxide from raw materials containing molybdenum disulfide in accordance with the steps of claim 1:

wherein said raw materials are calcined and melted as sulfidic molybdenum concentrate in a melting cyclone in suspension with oxygen at temperatures in the range of 1350°

C. to 1600°

C.

4. A method of producing molybdenum trioxide from raw materials containing molybdenum disulfide in accordance with the steps of claim 1:

wherein the oxidizing gas is directed onto the slag bath in multiple streams with a partial oxygen pressure in the range of PO₂ =0.05 through 0.5 atm.

5. A method of producing molybdenum trioxide from raw materials containing molybdenum disulfide in accordance with the steps of claim 1:

wherein the condensing of molybdenum trioxide from the united gas is conducted at exhaust gas temperatures in the range of 200°

C. through 400°

C. in a dust separator.

6. A method of producing molybdenum trioxide from raw materials containing molybdenum disulfide comprising the steps:

melting raw materials containing molybdenum disulfide in an oxidizing atmosphere and volatilizing an amount of molybdenum disulfide to generate an exhaust gas containing molybdenum trioxide with a remainder of the molybdenum bonded in a molten slag as MoO₄ with the melted materials;

volatilizing the MoO₄ in said molten slag by converting the MoO₄ to volatile molybdenum trioxide while directing an oxidizing gas onto the surface of the molten slag at a pressure in the range of pO₂ 0.05 through 0.05 atm. thereby preventing the formation of molybdenum dioxide and substantially depleting said molten slag of molybdenum with admixtures including at least Fe and Cu remaining in the slag;

uniting said exhaust gas with said volatile molybdenum trioxide to form a united gas;

cooling the united gas and condensing the molybdenum trioxide from the united gas into solid form;

and withdrawing the slag containing said undesirable admixture including Fe and Cu.