Process for predicting properties of multi-component fluid blends

• US 5,223,714 A
• Filed: 11/26/1991
• Issued: 06/29/1993
• Est. Priority Date: 11/26/1991
• Status: Expired due to Term

• Current Assignee: Marathon Petroleum Company LLC (Marathon Petroleum Corporation)
• Original Assignee: Ashland Oil, Inc. (Ashland Global Holdings, Inc.)
• Inventors: Maggard, Steven M.
• Primary Examiner(s): Hannaher, Constantine
• Assistant Examiner(s): Glick, Edward J.
• Application Number:
  US07/797,832
• Time in Patent Office: 581 Days
• Field of Search: 250/341, 250/339, 250/343, 436/55
• US Class Current: 250/343
• CPC Class Codes: F02B 3/06 with compression ignition compression ignition engines using air or gas for blowing fuel into compressed air in cylinder F02B13/02
• CPC Class Codes: G01N 21/3504 for analysing gases, e.g. multi-gas analysis
• CPC Class Codes: G01N 21/3577 for analysing liquids, e.g. polluted water
• CPC Class Codes: G01N 21/359 using near infrared light
• CPC Class Codes: G01N 33/2829 Mixtures of fuels
• CPC Class Codes: Y10T 436/12 Condition responsive control

Abstract

The octane of components used in the blending of gasoline is used to predict the octane of the finished gasoline blend by measuring absorbances, preferably in the near-infrared range, and metering the fraction of each blending component as independent variables and performing a multiple regression on the data modeling the dependent variable of the various octanes. Percent aromatics in diesel fuel and other finished chemical or physical properties of the finished blend can be controlled by feed-forward and/or feed-back techniques.

Claims

1. A process for controlling the blending of a plurality of fluid components comprising in combination the steps of:

a) measuring an absorbance at selected wavelengths in the infrared indicative of a property of each of said plurality of fluid components to be blended together;

b) outputting a signal indicative of each said absorbance for each of said components;

c) optionally converting said absorbance signal indicative of said property to a first or higher mathematical derivative signal;

d) weightedly adding substantially linearly the absorbance signals or the first powers of said derivative signals to provide a signal indicative of the blended value of said property after said components are blended together;

e) controlling the quantity of said plurality of fluid components in response to said signal indicative of said blended value.

2. A process according to claim 1 wherein said absorbance signal is converted to a first or higher derivative and the first powers thereof are weightedly added.

3. A process according to claim 1 wherein said absorbance comprises absorbance measured in the near-infrared range.

4. A process according to claim 1 wherein said components are fuels.

5. A process according to claim 1 wherein said property is boiling point.

6. A process according to claim 1 wherein said property is end boiling point.

7. A process according to claim 1 wherein said property is octane.

8. A process according to claim 1 wherein said property is cetane number.

9. A process according to claim 1 wherein said property is aromatic content.

10. A process according to claim 1 wherein said property is olefin content.

11. A process according to claim 1 wherein said absorbances of said plurality of fluid components are isonumeric for each component.

12. A process according to claim 1 wherein said property is vapor pressure.

13. A process according to claim 1 wherein said property is Reid Vapor Pressure.