Diamond having multiple coatings and methods for their manufacture

• US 5,224,969 A
• Filed: 04/13/1992
• Issued: 07/06/1993
• Est. Priority Date: 07/20/1990
• Status: Expired due to Fees

• Current Assignee: Norton Company (Compagnie De Saint-Gobain)
• Original Assignee: Norton Company (Compagnie De Saint-Gobain)
• Inventors: Hansen, Jeffrey S., Chen, Sy-Hwa
• Primary Examiner(s): Bell, mark L.
• Assistant Examiner(s): THOMPSON, WILLIE
• Application Number:
  US07/868,071
• Time in Patent Office: 449 Days
• Field of Search: 51/295, 51/307, 51/309, 428/408, 428/429
• US Class Current: 51/295
• CPC Class Codes: B24D 3/06 metallic or mixture of metals with ceramic materials, e.g. hard metals, "cermets", cements
• CPC Class Codes: C09K 3/1445 the coating consisting exclusively of metals
• CPC Class Codes: Y10T 428/30 Self-sustaining carbon mass or layer with impregnant or other layer
• CPC Class Codes: Y10T 428/31612 As silicone, silane or siloxane
• CPC Class Codes: Y10T 428/31678 Of metal

Abstract

A diamond element having good bonding properties and a method for fabricating the diamond element in which a diamond substrate is coated by and bonded to a first layer of chromium carbide, a second layer containing titanium, vanadium, zirconium, niobium, tantalum, iron, cobalt, nickel or copper, is bonded to said first layer, and a third layer of tungsten, or molybdenum deposited by a CVD technique utilizing metal halides, is bonded to said second layer. The second layer functions to protect the chromium carbide layer against attack by halide containing gas during the CVD deposition of the tungsten, or molybdenum.

Claims

1. A diamond element having good bonding properties, comprising:

a. a diamond substrate;

b. a first layer bonded to said diamond substrate;

c. a second layer bonded to said first layer; and

d. a third layer bonded to said second layer, said first layer including chromium carbide, said third layer including a transition element and said second layer including an element selected from the group consisting of titanium, vanadium, zirconium, niobium, tantalum, iron/ cobalt, nickel and copper.

2. The diamond element as recited in claim 1 wherein said second layer comprises a metal nitride.

3. An article of manufacture containing a firmly secured diamond element, said tool comprising:

a. a diamond substrate;

b. a first layer chemically bonded to said diamond substrate;

c. a second layer chemically bonded to said first layer;

d. a third layer chemically bonded to said second layer; and

e. a body bonded to said third layer, said first layer including chromium carbide, said third layer including a transition element and said second layer including an element selected from the group consisting of titanium, vanadium, zirconium, niobium, tantalum, iron, cobalt, nickel and copper.

4. The article of manufacture as recited in claim 3 wherein said second layer comprises a metal nitride.

5. A method for producing a diamond element capable of being securely bonded to a substrate, the method comprising the steps of:

a. depositing a first layer on said diamond element;

b. depositing a second layer on said diamond element; and

c. depositing a third layer on said diamond element, said first layer including chromium carbide, said third layer including a transition element and said second layer including an element selected from the group consisting of titanium, vanadium, zirconium, niobium, tantalum, iron, cobalt, nickel and copper.

6. The method as recited in claim 5 wherein said step of depositing a third layer comprises the step of depositing said tungsten or molybdenum in a chemical vapor deposition process in the presence of halide gas and wherein said second layer comprises a compound resistant to attack by said halide gas.

7. The method as recited in claim 6 wherein said step of depositing a second layer includes the step of depositing a layer of material resistant to attack by halides.

8. The method as recited in claim 5 wherein said step of depositing a second layer includes the step of passivating said second layer against attack by halides.

9. The method as recited in claim 8 wherein said passivating step includes nitridation.