Process for reclaiming thermally strained polyester scrap material

• US 5,225,130 A
• Filed: 10/30/1991
• Issued: 07/06/1993
• Est. Priority Date: 10/30/1990
• Status: Expired due to Fees

• Current Assignee: Hoechst Aktiengesellschaft (Sanofi )
• Original Assignee: Hoechst Aktiengesellschaft (Sanofi )
• Inventors: Deiringer, Guenther
• Primary Examiner(s): Thurlow, Jeffery
• Application Number:
  US07/783,699
• Time in Patent Office: 615 Days
• Field of Search: 264/169, 264/37, 264/DIG. 69, 264/140, 264/101, 264/102, 264/85, 264/211.23, 264/211.24, 425/202, 425/203, 425/205, 425/183, 425/185, 425/197
• US Class Current: 264/102
• CPC Class Codes: B29B 17/0026 by agglomeration or compacting
• CPC Class Codes: B29B 17/02 Separating plastics from other materials
• CPC Class Codes: B29B 17/04 Disintegrating plastics, e.g. by millingB29B9/02, B29B11/02, B29B13/10, B29B17/02 take precedence
• CPC Class Codes: B29B 2009/165 Crystallizing granules
• CPC Class Codes: B29B 2017/0224 Screens, sieves
• CPC Class Codes: B29B 7/38 rotary B29B7/52 takes precedence
• CPC Class Codes: B29B 7/58 Component parts, details or accessories; Auxiliary operations
• CPC Class Codes: B29B 7/66 Recycling the material B29B7/566 takes precedence
• CPC Class Codes: B29B 7/845 Venting, degassing or removing evaporated components in devices with rotary stirrers
• CPC Class Codes: B29B 7/885 with means for treating, e.g. milling, the charges B29B7/905 takes precedence
• CPC Class Codes: B29B 9/06 in the form of filamentary material, e.g. combined with extrusion
• CPC Class Codes: B29K 2067/003 PET, i.e. poylethylene terephthalate
• CPC Class Codes: C08J 11/06 without chemical reactions
• CPC Class Codes: C08J 2367/02 Polyesters derived from dicarboxylic acids and dihydroxy compounds; C08J2367/06 takes precedence
• CPC Class Codes: Y02W 30/62 Plastics recycling; Rubber recycling
• CPC Class Codes: Y10S 264/913 From fiber or filament, or fiber or filament containing article or product, e.g. textile, cloth fabric, carpet, fiberboard
• CPC Class Codes: Y10S 264/916 From porous material containing articles, e.g. sponge, foam
• CPC Class Codes: Y10S 264/918 From hollow- or container-type articles, e.g. tubes, bottles, cups
• CPC Class Codes: Y10S 264/92 by extruding material recycled from consumer used article or product

Abstract

Reclaiming of polyester waste material for re-use in the production of high-quality PET plastic material comprises shredding, cleaning, sorting and postcondensing said waste materials. The shredded scrap material comprises polyester waste materials of various molecular weights and degrees of purifying. The shredded material is molten and filtered The filtered melt is either post-condensed in the molten state and then granulated or is first granulated and then subjected to a solid phase post-condensation. The granules obtained in each case are preferably fed into an extruder and extruded together with virgin raw material so as to produce a useful film or article.

Claims

1. A process for reclaiming thermally strained polyester waste materials comprising the steps of:

a) shredding a mixture of polyester waste materials, said mixture comprising polyesters of different molecular weights and different degrees of conversion, so as to form a shredded polyester mixture,

b) melting said shredded mixture so as to form a molten material,

c) filtering said molten material down to a particle size of about 5 to 10 microns, by removing those impurities having a particle size of equal to about 5 to 10 microns and removing those impurities having a size of greater than 5 to 10 microns, so as to produce a filtered melt,

d) increasing by about 12 to about 150% as compared to the initial molecular weight of said filtered melt, the average molecular weight of said polyesters, by post-condensation, so as to produce a condensed mixture, and

e) recovering said condensed mixture.

2. A process of claim 1, wherein said post-condensation comprises liquid-phase post-condensation.

3. A process of claim 2, additionally comprising the step of:

f) feeding said recovered mixture to an extreuder and extruding it together with virgin polyester so as to produce an extruded article.

4. A process of claim 1, wherein said mixture of polyester waste materials comprises polyesters selected from the group consisting of polyethylene terephthalate, polytetramethylene terephthalate, poly-1,4-cyclohexylenedimethyl terephthalate, polyethylene-2,6-naphthalate, and mixtures thereof.

5. A process of claim 4, wherein said mixture of polyester waste materials consists essentially of a clean mixture of said polyesters, comprising essentially no labels, lids, coatings, dirt, adhesives, or polymers other than said polyesters.

6. A process of claim 4, wherein said mixture of polyester waste materials consists essentially of a mixture of polyethylene terephthalate polyesters

7. A process of claim 1, wherein the specific viscosity of the polyesters employed in step a) is from about 600 to about 1100.

8. A process of claim 1, wherein said step d) is performed continuously with agitation and degassing at a reduced pressure and a temperature above the melting point of said polyesters.

9. A process of claim 8, wherein said temperature is about 270 to about 310°

C., wherein said pressure is about 0.5 to about 5 mbar and said step c) occurs continuously over a period of about 0.5 to about 4 hours.

10. A process of claim 9, wherein said mixture of polyester waste materials consists essentially of polyethylene terephthalate, wherein said temperature is about 280 to about 295°

C., said pressure is about 1.5 to about 2 mbar, and said step d) is performed continuously over a period of about 0.5 to about 1.5 hours, wherein the specific viscosity of said polyethylene terephthalate is increased from about 800 to about 1050 during said step d).

11. A process of claim 9, wherein said mixture of polyester waste materials consists essentially of polyethylene terephthalate, wherein said temperature is about 280°

to about 295°

C., said pressure is about 3 to about 5 mbar, and said step d) is performed continuously over a period of about 1 to about 2 hours, wherein the specific viscosity of said polyethylene terephthalate is increased from about 800 to about 950 during said step d).

12. A process of claim 1 additionally comprising between steps c) and d) the steps of:

i) solidifying said filtered melt, so as to produce a solidified mixture,

ii) granulating said solidified mixture so as to produce a granulated mixture, and

iii) increasing by about 30 to 150%, as compared to the initial molecular weight of said granulated mixture, the average molecular weight of said granulated mixture.

13. A process of claim 12, additionally comprising the step of:

f) feeding said granulated mixture to an extruder and extruding it together with virgin polyester so as to produce an extruded article.

14. A process of claim 12, wherein said mixture of polyester waste materials comprises polyesters selected from the group consisting of polyethylene terephthalate, polytetramethylene terephthalate, poly-1,4-cyclohexylenedimethyl terephthalate, polyethylene-2,6-naphthalate, and mixtures thereof.

15. A process of claim 14, wherein said mixture of polyester waste materials consists essentially of a clean mixture of said polyesters, comprising essentially no labels, lids, coatings, dirt, adhesives, or polymers other than said polyesters.

16. A process of claim 15, wherein said mixture of polyester waste materials consists essentially of a mixture of polyethylene terephthalate polyesters.

17. A process of claim 14, wherein the specific viscosity of said mixture of polyester waste materials is from about 600 to about 1100.

18. A process of claim 12, wherein said granulated mixture comprises granules of relative uniform size and shape.

19. A process of claim 12, wherein said step d) is performed continuously in a fluidized bed apparatus, using inert gases as heat transfer agents and flushing gases.

20. A process of claim 19, wherein said inert gases comprise nitrogen.

21. A process of claim 19, wherein said polyester waste material consists essentially of polyethylene terephthalate, and during step d), the temperature is about 200°

to about 250°

C., and the treatment time is about 8 hours so as to increase the specific viscosity of said polyethylene terephthalate from about 800 to about 1050.

22. A process of claim 12, wherein said polyester waste material consists essentially of polyethylene terephthalate, wherein step d) is performed discontinuously, at a reduced pressure of about 0.1 mbar, over a period of about 12 hours, so as to increase the specific viscosity of said polyethylene terephthalate from about 800 to about 1050.

23. A process of claim 22, wherein step d) is performed in a tumbler drier at a temperature of about 200 to about 250°

C.

24. A process of claim 12, wherein said postcondensation comprises solid phase postcondensation so as to produce a condensed, granulated mixture.