Polymeric anti-reflection coatings and coated articles

• US 5,225,244 A
• Filed: 08/14/1992
• Issued: 07/06/1993
• Est. Priority Date: 12/17/1990
• Status: Expired due to Term

• Current Assignee: Alliedsignal Inc. (Honeywell International Inc.)
• Original Assignee: Alliedsignal Inc. (Honeywell International Inc.)
• Inventors: Nahata, Ajay, McFarland, Michael J., Yardley, James T., Aharoni, Shaul M.
• Primary Examiner(s): Schofer, Joseph L.
• Assistant Examiner(s): SAROFIM, NABIL F
• Application Number:
  US07/930,886
• Time in Patent Office: 326 Days
• Field of Search: 427/240, 427/385.5, 427/407.1, 427/430.1
• US Class Current: 427/240
• CPC Class Codes: C08F 220/22 Esters containing halogen

Abstract

Solid bodies having a reflective surface are provided with an anti-reflection coating of a terpolymer composition derived from (a) perfluoroalkylalkyl acrylate or methacrylate, (b) acrylic, methacrylic or itaconic acid, and (c) hydroxyl- containing acrylate or methacrylate.

Claims

1. The method of providing an anti-reflection coating on a solid body having a reflective surface, which comprises depositing on said surface a layer of a polymeric composition comprising fluorinated copolymer having a polymer chain composed of ##STR6## units, wherein s, t and u represent weight proportions of the respective X, Y and Z units, and have values within the ranges of

s=from about 0.5 to about 0.99;

t=from about 0.005 to about 0.495; and

u=from about 0.005 to about 0.495;

with the sum of s+t+u being 1;

X represents units of the composition ##STR7## wherein R¹ is H, --CH₃, or mixtures thereof;

p is 1 or 2;

n is an integer of from about 1 to about 40;

Y represents units of the composition ##STR8## wherein R² is H, --CH₃ or --CH₂ COOH;

Z represents units of the composition ##STR9## wherein R³ is H, --CH₃, or CH₂ COOC_m H_2m+1, wherein m is an integer of from about 1 to about 4, and `R⁴ is an alkylene bridging group, straight chain, branched or cyclic, having from 1 to about 8 carbon atoms;

wherein the X, Y and Z units may be arranged in any sequence.

2. The method of claim 1 further comprising heating said layer of a polymeric composition at a temperature between about 120°

C. and about 180°

C. for time sufficient to effect cross-linking of said fluorinated copolymer.

3. The method of making an anti-reflection coated body according to claim 1, which comprises applying a solution of said fluorinated copolymer to said reflective surface, and evaporating the solvent.

4. The method of claim 3, further comprising heating the resultant coating at a temperature between about 120°

C. and about 180°

C. for time sufficient to effect cross-linking of said fluorinated copolymer.

5. The method of claim 3, wherein the solution of said copolymer is applied by spin-coating.

6. The method of claim 3, wherein the solution of said copolymer is applied by means of dipping said solid body into said solution.

7. The method of claim 4, wherein said solid body is transparent.

8. The method of claim 1, comprising the steps of depositing two layers of anti-reflection coatings, wherein the first layer which is in direct contact with said body comprises a polymer having a refractive index higher than the refractive index of said body, and the second layer has a lower refractive index than said body.

9. The method of claim 8 involving the step of applying a solution of said fluorinated copolymer to the first layer, and evaporating the solvent.

10. The method of claim 9 further comprising heating the second layer at temperature between about 120°

C. and about 180°

C. for time sufficient to effect cross-linking of the fluorinated copolymer.