Ventable rupture diaphragm-protected container for heating contained materials by microwave radiation

• US 5,230,865 A
• Filed: 09/21/1992
• Issued: 07/27/1993
• Est. Priority Date: 09/08/1989
• Status: Expired due to Term

• Current Assignee: CEM Global LLC
• Original Assignee: CEM Global LLC
• Inventors: Hargett, Wyatt P., Littau, Sara E.
• Primary Examiner(s): Housel, James C.
• Assistant Examiner(s): Snay, Jeffrey R.
• Application Number:
  US07/948,134
• Time in Patent Office: 309 Days
• Field of Search: 422/78, 422/99, 422/102, 422/103, 422/112, 422/113, 219/10.55 E, 219/10.55 M, 220/89.2, 220/89.1, 220/206, 220/207, 220/209, 220/366, 220/376
• US Class Current: 422/547
• CPC Class Codes: B01J 19/126 Microwaves
• CPC Class Codes: B01J 2219/1209 Features relating to the reactor or vessel
• CPC Class Codes: B01J 2219/1215 Single reactor
• CPC Class Codes: B01J 2219/1218 Multiple reactors
• CPC Class Codes: G01N 1/44 Sample treatment involving radiation, e.g. heat
• CPC Class Codes: H05B 6/6408 Supports or covers specially adapted for use in microwave heating apparatus
• CPC Class Codes: Y10T 436/25125 Digestion or removing interfering materials

Abstract

A ventable container for materials to be heated (preferably digested) by microwave radiation includes a movable rupture diaphragm in a venting passageway in a closure or cover for such container. Such diaphragm is tightenable into place so that the container is sealed and in such sealed state is protected by the rupture diaphragm against pressures that could develop in the container that are higher than that for which it was designed. An important feature of the invention is that the rupture diaphragm is controllably movable, when desired, to open positions to vent the container during heating and afterward, and is resealable after such venting. Because of the chemical reactivity of the reagents utilized in digestions an inner chemically resistant liner is desirably employed in conjunction with a physically stronger outer body, with the outer body giving the liner enough strength to withstand pressures developed during the heating. Also within the invention are processes for heating and digesting materials in the described containers with microwave radiation, microwave heating apparatuses including the invented containers, and lined containers wherein the liners are of improved sealing structures so that the containers are more tightly sealed when heated.

Claims

1. A ventable container that is protected by rupture means against possible damaging effects of pressures higher than those for which the container was designed to be held at given temperatures, which comprises radiant energy transmissive container body means for holding material to be heated by radiant energy, which body means comprises an opening for addition and removal of said material, closure means for sealing said container opening, and venting means for venting gas from the container, which venting means comprises a passageway for gas being vented from the container, which passageway terminates in an outlet, rupture means, seating means for the rupture means, against which seating means the rupture means is held, to close the venting passageway, and means for controllably and releasably holding the rupture means against the seating means to seal off the venting passageway from the container body means when the rupture means is intact and is held against the seating means, and for venting the container through the venting passageway and outlet, when the intact rupture means is released from the seating means, in which occurrence and when the rupture means ruptures, vented gas exits from the container through the passageway outlet.

2. A container according to claim 1, wherein the container body means is microwave transmissive and has the opening therein at the top thereof, the radiant energy is microwave radiation, the releasable holding means contacts the rupture means and applies force to it to hold it against the seating means, and the closure means includes the venting means therein.

3. A container according to claim 2 wherein the container body means comprises a liner inside a strengthening container body, the liner, strengthening container body and closure means are held in sealing contacts by collar means which holds the closure means against the container body means, the closure means is resealable after ventings, and the venting means vents the container when the rupture means ruptures, and controllably vents it when the force holding such rupture means against the seating means is released or is overcome by pressure in the container so that the rupture means moves away from the seating means a controllable distance and opens the passageway for venting of gas from the container.

4. A container according to claim 3, in which the container, liner and strengthening container body are essentially cylindrical, with bottoms, and the strengthening container bottom has external threads thereon, on the exterior thereof, the closure means closes the opening at the top of the container body means and includes a boss that contains the means for releasably holding the rupture means against the seating means, and that contains at least a portion of the venting passageway, and the collar means is cylindrical and is internally threaded to screw onto external threads on the exterior of the strengthening container body.

5. A container according to claim 4 wherein the closure means comprises a fluid operated pressure means for pressing against the rupture means so as to press it against the seating means, which pressure means is connected to a source of controllable fluid pressure so that the maximum pressure in the container is limited by the pressure of the fluid pressure means.

6. A container according to claim 4 wherein the liner, closure means and rupture means are of chemically resistant polyfluoroethylene, the strengthening container is of a polyether imide synthetic organic polymer, and the container is suitable for heating contained material to elevated temperatures and to pressures in the range of 7 to 35 kg./sq. cm. gauge.

7. A container according to claim 4 wherein the liner material is of a greater coefficient of expansion than the material of the strengthening container body, the container body is vertical, the liner bottom contacts the interior of the bottom of the strengthening container body and the liner is tapered upwardly and outwardly between the top of the cylindrical wall thereof and the top periphery thereof, and the upper part of the strengthening container body and a bottom part of the closure means near the periphery thereof are shaped to match the liner at the top thereof, which shapes of the upper parts of the liner and strengthening container body, together with the closure means, make the seal between the liner, strengthening container body and closure means of increased tightness as the temperature of such parts rises, due to a greater expansion of the liner than the strengthening container body.

8. A container according to claim 5 wherein the closure means comprises threaded stem means for screwing into a threaded vertical bore in the closure means, into which the threaded stem means is removeably inserted, for pressing the rupture means against the seating means and for releasing the rupture means from contact with the seating means by backing off the threaded stem means.

9. A ventable container according to claim 1 wherein said container is positioned in a microwave apparatus chamber where it is subjectable to microwave radiation to heat polar contents of the container and digest such contents or materials in them.

10. A ventable container according to claim 1, wherein said container is positioned in a microwave apparatus chamber on a turntable therein, in the presence of at least one additional such ventable container, with venting outlets thereof connected to a collecting vessel from which venting gases are further vented.