Multilayer composites coextruded with the use of impact-reinforced impervious resin compositions and their use for the manufacture of fuel storage vessels

• US 5,230,935 A
• Filed: 11/27/1992
• Issued: 07/27/1993
• Est. Priority Date: 06/22/1990
• Status: Expired due to Fees

• Current Assignee: Solvay & CIE
• Original Assignee: Solvay & CIE
• Inventors: De Longree, Pierre, Delimoy, Didier
• Primary Examiner(s): SLUBY, PATRICIA
• Application Number:
  US07/982,420
• Time in Patent Office: 242 Days
• Field of Search: 428/36.7, 428/516, 428/520
• US Class Current: 428/36.7
• CPC Class Codes: B32B 27/18 characterised by the use of special additives
• CPC Class Codes: C08L 2666/24 Graft or block copolymers according to groups C08L51/00, C08L53/00 or C08L55/02; Derivatives thereof
• CPC Class Codes: C08L 29/04 Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
• CPC Class Codes: Y10T 428/1383 Vapor or gas barrier, polymer derived from vinyl chloride or vinylidene chloride, or polymer containing a vinyl alcohol unit is sandwiched between layers [continuous layer]
• CPC Class Codes: Y10T 428/31913 Monoolefin polymer
• CPC Class Codes: Y10T 428/31928 Ester, halide or nitrile of addition polymer

Abstract

Multilayer composites coextruded with the use of polyolefins and of impact-reinforced impervious resin compositions based on hydrolysed copolymers of vinyl acetate and ethylene comprising, as an additive improving the impact strength, elastomeric copolymers of ethylene and propylene which are modified by grafting an α,β-ethylenically unsaturated carboxylic acid and, preferably, by maleic anhydride.

The coextruded multilayer composites are very particularly suitable for the manufacture of fuel storage vessels combining impact strength and high imperviousness to petrol and to petrol/alcohol mixtures.

Claims

1. A coextruded multilayer composite, comprising:

a layer of a polyolefin;

a layer of an impact-reinforced impervious resin composition consisting essentially of a hydrolyzed copolymer of vinyl acetate and ethylene, and an elastomeric copolymer of ethylene and propylene which is modified by grafting an α

,β

-ethylenically unsaturated carboxylic acid as an additive in an amount effective for improving impact strength; and

an intermediate layer of a polymeric adhesive bonding together the layer of a polyolefin and the layer of an impact-reinforced impervious resin composition.

2. The coextruded multilayer composite according to claim 1 wherein the modified elastomeric copolymers of ethylene and propylene comprise form 40 to 95 mol % of ethylene-derived monomer units, form 60 to 5 mol % of propylene-derived monomer units and from 0.1 to 1.5% by weight of monomer units derived from an α

,β

-ethylenically unsaturated carboxylic acid.

3. The coextruded multilayer composite according to claim 1, wherein the modified elastomeric copolymers of ethylene and propylene comprise from 45 to 85 mol % of ethylene-derived monomer units, from 55 to 15 mol % of propylene-derived monomer units and from 0.6 to 1.2% by weight of monomer units derived from and α

,β

-ethylenically unsaturated carboxylic acid.

4. The coextruded multilayer composite according to claim 1, wherein the elastomeric copolymers of ethylene and propylene are modified by grafting with maleic anhydride.

5. The coextruded multilayer composite according to claim 1, wherein the impervious resin compositions comprise form 5 to 35% by weight of modified elastomeric copolymers of ethylene and propylene.

6. The coextruded multilayer composite according to claim 5, wherein the impervious resin compositions comprise from 15 to 25% by weight of modified elastomeric copolymers of ethylene and propylene.

7. The coextruded multilayer composite according to claim 1 wherein they comprise three layers consisting of an outer layer of high density polyethylene, an intermediate layer of polymeric adhesive and an outer layer consisting of an impact-reinforced impervious resin composition.

8. The coextruded multilayer composite according to claim 1, wherein they comprise three layers consisting of an outer layer of polypropylene, an intermediate layer of polymeric adhesive and an outer layer consisting of an impact-reinforced impervious resin composition.

9. The coextruded multilayer composite according to claim 1, wherein they comprise essentially two outer layers of high density polyethylene, an internal layer consisting of an impact-reinforced impervious resin composition and two intermediate layers of polymeric adhesive.

10. In a process of manufacturing a fuel storage vessel the improvement comprising manufacturing said vessel from a coextruded multilayer composite according to claim 9.