Electrochromatic glazings

• US 5,231,531 A
• Filed: 09/13/1991
• Issued: 07/27/1993
• Est. Priority Date: 09/14/1990
• Status: Expired due to Term

• Current Assignee: Saint-Gorbain Recherche
• Original Assignee: Saint-Gobain Recherche
• Inventors: Lerbet, Francois, Defendini, Francis
• Primary Examiner(s): Hille, Rolf
• Assistant Examiner(s): SAADAT, MAHSHID D
• Application Number:
  US07/759,323
• Time in Patent Office: 683 Days
• Field of Search: 359/275, 359/265, 359/269, 359/270, 359/271
• US Class Current: 359/275
• CPC Class Codes: E06B 2009/2464 featuring transparency control by applying voltage, e.g. LCD, electrochromic panels
• CPC Class Codes: G02F 1/163 Operation of electrochromic cells, e.g. electrodeposition cells; Circuit arrangements therefor

Abstract

An electrochromatic glazing system is provided. The system comprises a first glass sheet covered with a first transparent electrically conductive film and a second glass sheet covered with a second transparent electrically conductive film. A film of electrochromatic material, an electrolyte, and a counterelectrode are interposed between the first and second transparent electrically conductive films. The first and second electrically conductive films are connected to a voltage generator by an electrical control circuit and the voltage generator receives a set-point value from a control unit equipped with a memory and generates a potential difference as a function of the temperature of the electrolyte.

Claims

1. An electrochromatic glazing system comprising:

a first glass sheet covered with a first transparent electrically conductive film;

a second glass sheet covered with a second transparent electrically conductive film;

a film of an electromagnetic material;

an electrolyte having a temperature; and

a counterelectrode;

wherein the film of electrochromatic material, the electrolyte, and the counterelectrode are interposed between the first and second transparent electrically conductive films;

wherein the first and second electrically conductive films are connected to a voltage generator by an electrical control circuit;

wherein the voltage generator receives a set-point value from a control unit equipped with a memory and generates a potential difference U₁ as a function of the temperature of the electrolyte;

wherein application of a potential difference beyond a maximum potential difference will result in degradation of the system;

wherein the voltage generator generates potential difference u_1s for a short time period before generating said potential difference U₁, the intermediate potential difference u_1s being less than or equal to, in absolute value, the maximum potential difference;

wherein the potential difference u_1s has a corresponding intermediate current density i_1s that is simultaneously measured; and

wherein the current density i_1s is used by the control unit for selecting the potential difference U₁ to be generated.

2. The electrochromatic glazing system of claim 1, wherein the potential difference u_1s is applied during a period less than 500 ms.

3. The electrochromatic glazing system of claim 1, wherein the potential difference u_1s is applied during a period less than 100 ms.

4. The electrochromatic glazing system of claim 1, wherein the first and second electrically conductive films have first and second points, respectively, thereon that face each other from diagonally opposite positions on said films;

wherein the potential difference U₁ (t) during a switching phase is generated as a function of time such that there is a constant potential difference between the first and second points; and

wherein the potential difference U₁ (t) is governed by the control unit as a function of the temperature of the electrolyte.

5. The electrochromatic glazing system of claim 4, wherein the first and second electrically conductive films provide a quantity of electrical charges that are transferred during the switching phase;

and wherein the electrical charges are measured by a coulometer mounted on the electrical control circuit.

6. The electrochromatic glazing system of claim 5, wherein the supply of electrical charges to the system is interrupted if the measured quantity of charges reaches 10 Mc/cm².

7. The electrochromatic glazing system of claim 4, wherein the duration of the switching phase is measured by a time countdown unit, and wherein the duration of the switching phase is supplied as a set-point value and sent to the control unit.

8. The electrochromatic glazing system of claim 1, wherein the duration of a switching phase is controlled by a current intensity which is maintained at less than a threshold intensity, and wherein the current intensity is measured with an ammeter and the threshold intensity, which is a function of the temperature, is stored in the memory.

9. The electromechanic glazing system of claim 1, wherein the electrical control circuit comprises a volt meter that measures a voltage U₂ between a first point on one of the electrically conductive films and a second point on the other of said electrically conductive films, said first point directly facing said second point.

10. The electrochromatic glazing system of claim 9, wherein the electrical control circuit comprises a user interface for selecting a degree of coloration or decoloration of the system;

and wherein the potential difference U₁ associated with each degree of coloration is stored in the memory.

11. The electrochromatic glazing system of claim 9, wherein the electrical control circuit comprises a user interface for selecting the degree of coloration or decoloration of the system;

wherein the same potential difference U₁ is used for all the degrees of coloration or decoloration; and

wherein the degree of coloration or decoloration is controlled by measuring, with a coulometer, a quantity of electrical charges transferred.

12. The electrochromatic glazing system of claim 1 further comprising means for measuring information corresponding to the degree of illumination to which the glazing is exposed and for transmitting this information to the control unit.

13. An electrochromatic glazing system comprising:

a first glass sheet covered with a first transparent electrically conductive film;

a second glass sheet covered with a second transparent electrically conductive film;

a film of an electrochromatic material;

an electrolyte having a temperature; and

a counterelectrode;

wherein the film of electrochromatic material, the electrolyte, and the counterelectrode are interposed between the first and second transparent electrically conductive films; and

means for electrically connecting the first and second electroconductive films to a voltage generator, said electrical connecting means including means for storing information corresponding to a desired degree of coloration of the glazing; and

means for controlling the voltage generator to generate a voltage between the first and second electroconductive film as a function of the temperature of the electrolyte, thus obtaining the desired degree of coloration of the glazing.

14. The electrochromatic glazing system of claim 13 further comprising means for measuring the temperature of the electrolyte, said measurement means connected to the voltage generator controlling means, so that the voltage may be varied to obtain constant transmission of light through the glazing.

15. The electrochromatic glazing system of claim 13 further comprising means for measuring information corresponding to the degree of illumination to which the glazing is exposed, said information measuring means electrically connected to the voltage generator controlling means, so that the voltage may be varied to obtain constant transmission of light through the glazing.

16. The electrochromic glazing system of claim 13 which further comprises means for measuring the current density passing to the first and second electroconductive films, said measurement means connected to the voltage generator controlling means so that the generated voltage may be maintained below a predetermined maximum value.

17. The electrochromic glazing system of claim 16 wherein the voltage is maintained below the maximum value by intermittent generation thereof, and which further comprises timer means for delaying the generation of voltage.

18. An electrochromic glazing system comprising:

a first glass sheet covered with a first transparent electrically conductive film;

a second glass sheet covered with a second transparent electrically conductive film;

a film of electrochromic material interposed between said first and second electrically conductive films;

an electrolyte having a temperature and being interposed between said first and second electrically conductive films;

an counterelectrode interposed between said first and second electrically conductive films;

means for measuring the temperature of said electrolyte;

means for supplying a set point value corresponding to a value of potential difference as a function of the temperature of said electrolyte; and

means for initiating a switching phase by generating a potential difference U₁ in accordance with said set point value, said initiating means receiving said set point value from said supplying means and interconnecting said first and second transparent electrically conductive films;

wherein said electrochromic film is adapted to be switched from a state of coloration to a state of decoloration in a first switching phase, and from a state of decoloration to coloration in a second switching phase.

19. The system according to claim 18, wherein said means for supplying a set point value comprises a control unit having a memory.

20. The system according to claim 18, wherein said means for measuring the temperature of said electrolyte comprises an ammeter, and wherein said initiating means is adapted to generate a predetermined intermediate potential difference u_1s for a short time before generating said potential difference U₁, said intermediate potential difference u_1s having a corresponding intermediate current intensity i_1s measurable by said ammeter and depending on the temperature of said electrolyte.

21. The system of claim 20, wherein said system is operable at a highest operating temperature, wherein application of a potential difference beyond a maximum potential difference results in degradation of the system at said highest operating temperature, and wherein said intermediate potential difference u_1s is less than or equal to, in absolute value, said maximum potential difference.

22. The system of claim 18, wherein said first and second electrically conductive films have first and second points, respectively, thereon that face each other from diagonally opposite positions on said films;

wherein the potential difference U₁ during a switching phase is generated as a function of time such that there is a constant potential difference between the first and second points; and

wherein the potential difference U₁ is governed by the control unit as a function of the temperature of the electrolyte.

23. The system of claim 22, wherein for a given electrolyte temperature, said means for initiating a switching phase generates a different potential difference U₁ for each shade of coloration such that each shade of coloration requires a switching phase of equal duration.

24. The system of claim 22, wherein for a given electrolyte temperature, said means for initiating a switching phase generates a single potential difference U₁ for each shade of coloration such that voltage is applied long enough to obtain a desired shade of coloration.