Liquefier process

• US 5,231,835 A
• Filed: 06/05/1992
• Issued: 08/03/1993
• Est. Priority Date: 06/05/1992
• Status: Expired due to Fees

• Current Assignee: Praxair Technology Incorporated (Linde Plc)
• Original Assignee: Praxair Technology Incorporated (Linde Plc)
• Inventors: Weber, Joseph A., Beddome, Robert A.
• Primary Examiner(s): Capossela, Ronald C.
• Application Number:
  US07/894,587
• Time in Patent Office: 424 Days
• Field of Search: 62/8, 62/9, 62/36, 62/38
• US Class Current: 62/615
• CPC Class Codes: F25J 1/0015 Nitrogen
• CPC Class Codes: F25J 1/0017 Oxygen
• CPC Class Codes: F25J 1/0022 Hydrocarbons, e.g. natural gas
• CPC Class Codes: F25J 1/0037 of a return stream
• CPC Class Codes: F25J 1/0042 by liquid expansion with extraction of work
• CPC Class Codes: F25J 1/0045 by vaporising a liquid return stream
• CPC Class Codes: F25J 1/0202 in a quasi-closed internal refrigeration loop F25J1/0208, F25J1/0219, F25J1/0224 take precedence
• CPC Class Codes: F25J 1/0234 Integration with a cryogenic air separation unit cryogenic separation of air F25J3/04
• CPC Class Codes: F25J 1/0288 using work extraction by mechanical coupling of compression and expansion of the refrigerant, so-called companders
• CPC Class Codes: F25J 2270/06 with multiple gas expansion loops
• CPC Class Codes: F25J 2290/34 Details about subcooling of liquids

Abstract

Dual turbine-booster compressor units are arranged for advantageous liquefaction operations using high pressure heat exchangers.

Claims

1. An improved cyogenic liquefier process comprising:

(a) passing compressed nitrogen gas, upon cooling in brazed aluminum, multi-pass heat exchanger means to the inlet of a cold turbo-expander unit;

(b) recycling nitrogen gas exhausted from said cold turbo-expander unit through said heat exchanger means for the warming thereof to ambient temperature prior to passage to recycle compression means;

(c) compressing said recycled nitrogen gas in a two zone recycle compressor, a portion of the thus compressed nitrogen comprising said compressed nitrogen gas passed to the cold turbo-expander unit;

(d) passing the remaining portion of the thus compressed nitrogen to the booster compression unit of the cold turbo-expander;

(e) further compressing the nitrogen from the cold turbo-expander booster compressor unit, upon cooling, to an elevated pressure of from about 800 to about 2,500 psia in the booster compression unit of a warm turbo-expander unit;

(f) dividing said nitrogen stream, at elevated pressure, into two streams;

(g) passing one stream of nitrogen at elevated pressure to the inlet of said warm turbo-expander unit for expansion therein;

(h) warming the nitrogen exhausted from said warm turbo-expander unit in said heat exchanger means;

(i) recycling the thus-warmed nitrogen from said heat exchanger means to the second zone of said two zone recycle compressor for compression therein, together with the recycle nitrogen from said cold turbo-expander; and

(j) cooling said second stream of nitrogen at elevated pressure in said heat exchanger means;

(k) withdrawing a nitrogen liquid stream from said heat exchanger means in a recovery line; and

(l) controlling the flow of said nitrogen liquid stream in the product recovery line, whereby the use of dual turbine booster compressor units, together with said brazed aluminum heat exchangers capable of operating at elevated pressures, enable the desired liquid nitrogen to be produced at desirable energy efficiency levels.

2. The process of claim 1 in which said elevated pressure is on the order of about 1,400 psia.

3. The process of claim 1 and including passing said cooled second stream of nitrogen to a liquid turbine unit for expansion therein.

4. The process of claim 3 and including passing said cooled second stream of nitrogen to a subcooler portion of said heat exchanger means prior to passage to said liquid turbine unit.

5. The process of claim 4 and including dividing said nitrogen liquid stream, and passing a large portion thereof from the process as desired liquid nitrogen product, and passing a small portion thereof through said subcooler portion of the heat exchanger means to form low pressure nitrogen vapor, warming said nitrogen vapor in the remaining portions of said heat exchanger means, and passing said nitrogen vapor to feed compressor means.

6. The process of claim 3 and including driving compressor means by said liquid turbine unit and compressing a portion of the recycled nitrogen gas in said compressor means.

7. The process of claim 6 in which the portion of recycled nitrogen gas compressed in said compressor means is a portion of the recycled nitrogen gas being passed to the first zone of said two zone recycle compressor.

8. The process of claim 1 and including passing said cooled second stream of nitrogen to a subcooler portion of said heat exchanger means, and including dividing said nitrogen liquid stream and passing a large portion thereof from the process as desired liquid nitrogen product, and passing a small portion thereof through said subcooler portion of the heat exchanger means to form low pressure nitrogen vapor, warming said nitrogen vapor in the remaining portions of said heat exchanger means, and passing said nitrogen vapor to feed compressor means.

9. The process of claim 1 in which said compressed nitrogen gas comprises dry, carbon-dioxide free air from the prepurifier portion of an air separation plant.

10. The process of claim 1 and including compressing make-up, external source nitrogen in said two zone recycle compressor.

11. An improved gas liquefier process comprising:

(a) passing compressed liquefier gas, upon cooling in brazed aluminum, multi-pass heat exchanger means to the inlet of a cold turbo-expander unit;

(b) recycling liquefier gas exhausted from said cold turbo-expander unit through said heat exchanger means for the warming thereof to ambient temperature prior to passage to recycle compression means;

(c) compressing said recycled liquefier gas in a two zone recycle compressor means, a portion of the thus compressed liquefier gas comprising said compressed liquefier gas passed to the cold turbo-expander unit;

(d) passing the remaining portion of the thus compressed liquefier gas to the booster compression unit of the cold turbo-expander;

(e) further compressing the liquefier gas from the cold turbo-expander booster compressor unit, upon cooling, to an elevated pressure in the booster compression unit of a warm turbo-expander unit;

(f) dividing said liquefier gas stream, at elevated pressure, into two streams;

(g) passing one stream of liquefier gas at elevated pressure to the inlet of said warm turbo-expander unit for expansion therein;

(h) warming the liquefier gas exhausted from said warm turbo-expander unit in said heat exchanger means;

(i) recycling the thus-warmed liquefier gas from said heat exchanger means to the second zone of said two zone recycle compressor means for compression therein, together with the recycle liquefier gas from said cold turbo-expander; and

(j) cooling said second stream of liquefier gas at elevated pressure in said heat exchanger means;

(k) withdrawing a product liquid stream from said heat exchanger means in a recovery line; and

(l) controlling the flow of said product liquid stream in the product recovery line, whereby the use of dual turbine booster compressor units, together with said brazed aluminum heat exchangers capable of operating at elevated pressures, enable the desired product liquid to be produced at desirable energy efficiency levels.

12. The process of claim 11 and including passing said product liquid to a liquid turbine unit for expansion therein.

13. The process of claim 12 and including passing said product liquid to a subcooler portion of said heat exchanger means prior to passage to said liquid turbine unit.

14. The process of claim 12 and including driving said compressor means by said liquid turbine unit and compressing a portion of the recycled liquefier gas in said compressor means.

15. The process of claim 14 in which the portion of recycled liquefier gas compressed in said compressor means is a portion of the recycled liquifier gas being passed to the first zone of said two zone recycle compressor means.

16. The process of claim 11 and including passing said cooled liquefier gas to a subcooler portion of said heat exchanger means, and including dividing said liquefier product stream and passing a large portion thereof from the process as desired liquefier product, and passing a small portion thereof through said subcooler portion of the heat exchanger means to form low pressure liquefier vapor, warming said liquefier vapor in the remaining portions of said heat exchanger means, and passing said liquefier vapor to feed compressor means.

17. The process of claim 11 in which said liquefier gas comprises air.

18. The process of claim 11 in which said liquefier gas comprises oxygen.

19. The process of claim 11 in which said liquefier gas comprises methane.

20. The process of claim 11 and including compressing make-up, external source liquefier gas in said two zone recycle compressor means.