Multi-layer metal coated diamond abrasives with an electrolessly deposited metal layer

• US 5,232,469 A
• Filed: 03/25/1992
• Issued: 08/03/1993
• Est. Priority Date: 03/25/1992
• Status: Expired due to Term

• Current Assignee: Diamond Innovations Incorporated (Sandvik AB)
• Original Assignee: General Electric Company
• Inventors: McEachron, Roger, Slutz, David E., Connors, Edward J.
• Primary Examiner(s): Bell, Mark L.
• Assistant Examiner(s): THOMPSON, WILLIE
• Application Number:
  US07/857,139
• Time in Patent Office: 496 Days
• Field of Search: 51/293, 51/295, 51/309
• US Class Current: 51/295
• CPC Class Codes: B22F 1/18 Non-metallic particles coated with metal
• CPC Class Codes: B24D 3/06 metallic or mixture of metals with ceramic materials, e.g. hard metals, "cermets", cements
• CPC Class Codes: C09K 3/1445 the coating consisting exclusively of metals
• CPC Class Codes: C22C 26/00 Alloys containing diamond or cubic or wurtzitic boron nitride, fullerenes or carbon nanotubes

Abstract

Multi-layer coated diamond abrasive particles having improved wear performance in abrasive tools are provided, wherein the coating comprises a single homogenous, carbide forming metal primary layer, preferably of chromium, and at least one non-carbide forming secondary layer applied by electroless deposition, preferably comprised of nickel/phosphorus or cobalt/phosphorus.

Claims

1. An abrasive particle suitable for use in sintered metal bonded abrasive tools comprising a diamond abrasive having a multi-layer coating consisting essentially of one homogeneous carbide forming metal primary layer chemically bonded to the surface of the diamond abrasive and at least one non-carbide forming metal secondary layer deposited electrolessly.

2. An abrasive particle as in claim 1, wherein said non-carbide forming metal secondary layer comprises cobalt/phosphorus, iron/phosphorus, or nickel/phosphorus.

3. An abrasive particle as in claim 2, wherein the amount of said non-carbide forming metal secondary layer ranges from 10 to 50 wt %, based on the weight of the uncoated diamond abrasive particle.

4. An abrasive particle as in claim 2, having two different non-carbide forming metal secondary layers deposited electrolessly.

5. An abrasive particle as in claim 1, wherein the diamond abrasive particles have an average particle size in the range of 1 to 1500 μ

m.

23. A sintered metal bonded abrasive tool comprising a sintered metal matrix and abrasive particles of claim 1.

6. An abrasive particle suitable for use in a sintered metal bonded abrasive tool comprising a diamond abrasive having a multi-layer coating consisting essentially of one homogeneous carbide forming metal primary layer deposited by chemical vapor deposition, or packed salt deposition and a non-carbide forming metal secondary layer deposited by electroless deposition.

7. An abrasive particle as in claim 6, wherein said non-carbide forming metal secondary layer comprises cobalt/phosphorus or nickel/phosphorus.

8. An abrasive particle as in claim 6, wherein the carbide forming metal primary layer has a thickness ranging from 0.1-10 μ

m.

9. An abrasive particle suitable for use in sintered metal bonded abrasive tools comprising a diamond abrasive having a multi-layer coating consisting essentially of one homogeneous chromium metal primary layer chemically bonded to the surface of the diamond abrasive and at least one non-carbide forming metal secondary layer deposited electrolessly.

10. An abrasive particle as in claim 9, wherein the amount of said non-carbide forming metal secondary layer ranges from 10 to 50 wt %, based on the weight of the uncoated diamond abrasive particle.

11. An abrasive particle as in claim 9, wherein the non-carbide forming metal secondary layer is comprised of one layer of nickel/phosphorus or cobalt/phosphorus.

12. An abrasive particle as in claim 9, having two different non-carbide forming metal secondary layers deposited electrolessly.

13. An abrasive particle as in claim 9, wherein the diamond abrasive particles have an average particle size in the range of 1 to 1500 μ

m.

14. An abrasive particle suitable for use in a sintered metal bonded abrasive tool comprising a diamond abrasive having a multi-layer coating consisting essentially of one homogeneous chromium metal primary layer deposited by chemical vapor deposition, or packed salt deposition and a non-carbide forming metal secondary layer deposited by electroless deposition.

15. An abrasive particle as in claim 14, wherein said non-carbide forming metal secondary layer comprises cobalt/phosphorus or nickel/phosphorus.

16. An abrasive particle as in claim 14, wherein the chromium metal primary layer has a thickness ranging from 0.1-10 μ

m.

17. A process for the preparation of coated diamond abrasive particles for use in sintered metal bonded abrasive tools, said process comprising applying one homogeneous carbide forming metal primary layer to the surface of said diamond abrasive particles by chemical vapor deposition or packed salt deposition and applying at least one secondary layer of a non-carbide forming metal by electroless deposition.

18. A process according to claim 17, wherein the homogenous carbide forming metal primary layer consists essentially of chromium and is chemically bonded to the diamond abrasive particle without a separate sintering step.

19. A process according to claim 17, wherein the carbide forming metal primary layer is applied at a thickness ranging from 0.1 to 10 μ

m, and the secondary layer is applied in an amount in the range of 10-50 wt %, based on the weight of the uncoated diamond abrasive particles.

20. A process according to claim 17, wherein two different secondary layers are applied by electroless deposition.

21. A method according to claim 17, wherein the secondary layer is deposited from at least one of nickel hypophosphite or cobalt hypophosphite solution.

22. A process according to claim 17, comprising the additional steps of mixing the coated diamond abrasive particles with a sinterable metal, pressing the mixture at ambient temperature to form a solid mass of a desired shape and heating the solid mass to a temperature sufficiently high to sinter said sinterable metal.

24. An abrasive tool which comprises a sintered metal matrix and multi-layer coated diamond abrasive particles wherein the multi-layer coating consists essentially of one homogenous carbide-forming primary metal layer chemically bonded to the surface of the diamond abrasive and at least one non-carbide forming metal secondary layer deposited electrolessly.

25. An abrasive tool according to claim 24, wherein the primary carbide forming metal primary layer is applied by packed salt deposition or chemical vapor deposition and the non-carbide forming metal secondary layer is applied by electroless deposition, and said carbide forming metal primary layer consists essentially of chromium, and said non-carbide forming metal secondary layer comprises cobalt/phosphorus or nickel/phosphorus.

26. An abrasive tool according to claim 24, which is an insert for a saw blade.