Liquid crystal optical element with liquid crystal in polymer matrix with particular modulus of elasticity

• US 5,235,445 A
• Filed: 04/17/1992
• Issued: 08/10/1993
• Est. Priority Date: 04/17/1991
• Status: Expired due to Fees

• Current Assignee: Asahi Glass Company, Limited (AGC, Inc.)
• Original Assignee: AG Technology Co., Ltd.
• Inventors: Niiyama, Satoshi, Kumai, Hiroshi, Gunjima, Tomoki, Hirai, Yoshinori
• Primary Examiner(s): Sikes, William L.
• Assistant Examiner(s): Gross, Anita Pellman
• Application Number:
  US07/869,961
• Time in Patent Office: 480 Days
• Field of Search: 359/51, 359/52
• US Class Current: 349/89
• CPC Class Codes: C09K 19/544 as dispersing or encapsulating medium around the liquid crystal
• CPC Class Codes: G02F 1/1334 based on polymer dispersed liquid crystals, e.g. microencapsulated liquid crystals
• CPC Class Codes: G02F 1/1362 Active matrix addressed cells G02F1/134336, G02F1/134363 take precedence
• CPC Class Codes: G02F 2202/023 curable
• CPC Class Codes: G02F 2203/30 Gray scale

Abstract

A liquid crystal optical element comprises a pair of substrates with electrodes and a liquid crystal and polymer composite material, which is interposed between the pair of substrates, in which liquid crystal is dispersed and held in a polymer matrix so that the refractive index of the polymer matrix substantially coincides with the refractive index of the liquid crystal used in either state of applying a voltage or without applying voltage, and the refractive indices don'"'"'t coincide with each other in the other state, wherein the elastic modulus of the polymer material which forms the polymer matrix is 3×10⁷ N/m² or less at 20° C. and 1×10³ N/m² or more at 40° C.

Claims

1. A liquid crystal optical element comprising a pair of substrates with electrodes and a liquid crystal and polymer composite material, which is interposed between the pair of substrates, in which liquid crystal is dispersed and held in a polymer matrix so that the refractive index of the polymer matrix substantially coincides with the refractive index of the liquid crystal used in either state of applying of a voltage or without applying a voltage, and the above refractive indices don'"'"'t coincide with each other in the other state, characterized in that the elastic modulus of the polymer material which forms the polymer matrix is 3×

10⁷ N/m² or less at 20°

C. and 1×

10³ N/m² or more at 40°

C.

2. The liquid crystal optical element according to claim 1, wherein the temperature at which the loss modulus of the polymer material which forms the polymer matrix becomes the maximum, is 0°

C. or less.

3. The liquid crystal optical element according to claim 1, wherein the polymer material which forms the polymer matrix is obtained by photo-curing a photo-curable vinyl type compound.

4. The liquid crystal optical element according to claim 1, wherein the dielectric anisotropy Δ

ε

of the liquid crystal used satisfy the relation of 5<

Δ

ε

<

13.

5. The liquid crystal optical element according to claim 4, wherein the dielectric anisotropy Δ

ε

of the liquid crystal used satisfy the relation of Δ

ε

<

1.45·

ε

_m where Δ

_m is the dielectric constant of the liquid crystal and polymer composite material at a low voltage sufficiently lower than the threshold voltage.

6. The liquid crystal optical element according to claim 1, wherein the liquid crystal used is a nematic liquid crystal having a positive dielectric anisotropy, and the ordinary refractive index (n₀) of the liquid crystal substantially coincides with the refractive index n_p of the polymer matrix.

7. The liquid crystal optical element comprises a liquid crystal as defined in claim 1, which effects a display including a half-tone display.

8. A liquid crystal display element for effecting a display including a half-tone display which comprises an active matrix substrate having an active element for each picture element electrode, a counter electrode substrate provided with a counter electrode and a liquid crystal and polymer composite material in which a nematic liquid crystal having a positive dielectric anisotropy is dispersed and held in a polymer matrix so that the refractive index of the polymer matrix substantially coincides with the ordinary refractive index (n₀) of the liquid crystal used, said liquid crystal and polymer composite material being interposed between the active matrix substrate and the counter electrode substrate, characterized in that the elastic modulus of the polymer material which forms the polymer matrix is 3×

10⁷ N/m² or less at 20°

C. and 1×

10³ N/m² or more at 40°

C.

9. The liquid crystal display element according to claim 8, wherein the temperature at which the loss modulus of the polymer material which forms the polymer matrix becomes the maximum, is 0°

C. or less.

10. The liquid crystal display element according to claim 8, wherein the polymer material which forms the polymer matrix is obtained by photo-curing a photo-curable vinyl type compound.

13. The liquid crystal display element according to claim 8, wherein said active element is a thin film transistor.

14. The liquid crystal display element according to claim 13, wherein said active element is a polycrystal silicon thin film transistor.

15. A projection type liquid crystal display apparatus which comprises in combination a liquid crystal display element as defined in claim 8, a projection light source and a projection optical system.

16. The projection type liquid crystal display apparatus according to claim 15, which further comprises a liquid crystal display element wherein the dielectric anisotropy Δ

ε

of the liquid crystal satisfy the relation of 5<

Δ

ε

<

13.

17. The projection type liquid crystal display apparatus according to claim 16, wherein the dielectric anisotropy Δ

ε

of the liquid crystal satisfy the relation of Δ

ε

<

1.45·

Δ

_m where Δ

_m is the dielectric constant of the liquid crystal and polymer composite material at a low voltage sufficiently lower than the threshold voltage.

18. The projection type liquid crystal display apparatus according to claim 15, in which a liquid crystal optical element having a thin film transistor is used.

19. The projection type liquid crystal display apparatus according to claim 18, in which a liquid crystal optical element having a polycrystal silicon thin film transistor is used.

20. The projection type liquid crystal display apparatus according to claim 15, wherein the projection optical system comprises a device for reducing diffusion light to reduce light scattered at the liquid crystal optical element so that the device reduces light which doesn'"'"'t forward straightly to incident light among light which has passed through the liquid crystal optical element.

11. The liquid crystal display element according to claim wherein the dielectric anisotropy Δ

ε

of the liquid [crystal used satisfy the relation of 5<

Δ

ε

<

13.

12. The liquid crystal display element according to claim 11, wherein the dielectric anisotropy Δ

ε

of the liquid crystal used satisfy the relation of Δ

ε

<

1.45·

ε

_m where ε

_m is the dielectric constant of the liquid crystal and polymer composite material at a low voltage sufficiently lower than the threshold voltage.