Solid imaging system using photohardening inhibition

• US 5,236,326 A
• Filed: 08/06/1992
• Issued: 08/17/1993
• Est. Priority Date: 07/05/1990
• Status: Expired due to Fees

• Current Assignee: DSM B.V.
• Original Assignee: E. I. du Pont de Nemours and Company (Corteva, Inc.)
• Inventors: Grossa, Mario
• Primary Examiner(s): Chiesa, Richard L.
• Application Number:
  US07/925,622
• Time in Patent Office: 376 Days
• Field of Search: 425/174, 425/174.4, 425/162, 264/22, 427/54.1, 427/53.1, 427/55, 427/508, 427/510, 427/521, 522/2, 430/327, 430/13, 430/271, 430/333, 430/269, 430/394, 430/396, 430/15, 430/17, 430/527, 430/917, 118/620, 118/641
• US Class Current: 425/174.4
• CPC Class Codes: B29C 64/135 the energy source being concentrated, e.g. scanning lasers or focused light sources
• CPC Class Codes: B29K 2995/0073 smooth

Abstract

An imaging apparatus produces a film of photohardened composition by exposing a layer of photohardenable composition to actinic radiation through a surface of a barrier transparent to the radiation and in contact with the composition at an interface therewith. An inhibition layer is created within the photohardenable composition in contact with the interface that inhibits photohardening of the composition within the inhibition layer during exposure, thereby precluding adhesion of any photohardened composition to the barrier.

Claims

1. In an apparatus for fabricating a film of photohardened composition including a first source of actinic radiation for exposing a layer of photohardenable composition to induce photohardening of the composition layer, and a barrier transparent to the radiation having a surface to be positioned in contact with the composition to form an interface therewith, the improvement in the apparatus comprising a second source of actinic radiation for activating an inhibitor of photohardening contained in the composition to create an inhibition layer in contact with the interface that inhibits photohardening of the composition within the inhibition layer during exposure from said first radiation source, thereby precluding adhesion of any photohardened composition to the barrier.

3. An apparatus as defined in claim 1 or 2, further comprising means for moving the film away from the interface in a direction orthogonal thereto in order to form a new layer of photohardenable composition adjacent to the interface.

4. An apparatus as defined in claim 3, further comprising a vessel for containing the photohardenable composition, and wherein the moving means comprises a movable platform disposed within the composition upon which the photohardened material is supported.

5. An apparatus as defined in claim 1 or 2, wherein the inhibitor of photohardening is a nitroso-dimer.

6. An apparatus as defined in claim 5, wherein the nitroso dimer is 2,3-diaza-1,4,4-trimethylbicyclo[3.2.1]oct-2-ene-N,N-dioxide.

2. An apparatus for fabricating a film from a photohardenable composition comprising:

a first source of actinic radiation for exposing a layer of the photohardenable composition to induce photohardening of the composition layer in order to form the film;

a transparent barrier having two opposite surfaces, one of the surface to be positioned in contact with the composition and to form an interface therewith, the other surface being disposed in a way to remain unwetted by the composition; and

a second source of actinic radiation for activating an inhibitor of photohardening contained in the composition to create an inhibition layer in contact with the interface that inhibits photohardening of the composition within the inhibition layer during exposure from said first radiation source, thereby precluding adhesion of any film to the barrier.