Process for purification of aqueous solutions containing hydrogen sulfide, hydrogen cyanide, and ammonia

• US 5,236,557 A
• Filed: 12/18/1991
• Issued: 08/17/1993
• Est. Priority Date: 12/22/1990
• Status: Expired due to Fees

• Current Assignee: Hoechst Aktiengesellschaft (Sanofi )
• Original Assignee: Hoechst Aktiengesellschaft (Sanofi )
• Inventors: Brunke, Wolfgang, Fischer, Rolf-Dieter, Schneller, Peter, Muller, Thomas, Poloszyk, Klaus, Leder, Norbert, Gerhardus, Ulrich
• Primary Examiner(s): WYSE, THOMAS G
• Application Number:
  US07/810,720
• Time in Patent Office: 608 Days
• Field of Search: 203/10, 203/33-37, 203/71, 210/750, 210/752, 210/766, 210/903, 210/904
• US Class Current: 203/10
• CPC Class Codes: C02F 1/586 by removing ammoniacal nitrogen for biological methods C02F3/00
• CPC Class Codes: C02F 2101/18 Cyanides
• CPC Class Codes: Y10S 210/903 Nitrogenous
• CPC Class Codes: Y10S 210/904 -CN containing

Abstract

Aqueous solutions which are contaminated by hydrogen sulfide, hydrogen cyanide, and ammonia are brought to a pH of about 3 or less after their formation and treated with an inert gas in a stripping column to remove the sulfide and cyanide. The pH of the solution is then increased to about 10 or more and the solution is again treated with an inert gas in a second stripping column to remove the ammonia.

Claims

1. A process for the purification of an aqueous solution containing hydrogen sulfide, hydrogen cyanide, and ammonia comprising adding an acidic compound to said aqueous solution in an amount sufficient to bring said aqueous solution to a first pH of not more than about 3.0 after formation of said aqueous solution, passing said solution through a first stripping column, contacting said solution with a first inert gaseous medium, thereby removing at least most of said sulfide and cyanide to form a partially stripped solution,

adding an alkaline compound to said stripped solution sufficient to bring said stripped solution to a second pH of at least about 10.0, passing said stripped solution through a second stripping column, contacting said stripped solution with a second inert gaseous medium, thereby removing at least most of said ammonia to form a waste water solution.

2. The process of claim 1 wherein said aqueous solution has contacted by said first inert gaseous medium at a first elevated temperature.

3. The process of claim 1 wherein said stripped solution is contacted by said second inert gaseous medium at a second elevated temperature.

4. The process of claim 1 wherein said acidic compound is a strong inorganic acid.

5. The process of claim 4 wherein said acid is sulfuric or nitric.

6. The process of claim 1 wherein said aqueous solution is contacted by said first medium and said stripped solution is contacted by said second medium at a stripping temperature of 60°

C. to 150°

C.

7. The process of claim 6 wherein said stripping temperature is 80°

C. to 120°

C.

8. The process of claim 1 wherein said aqueous solution is contacted by said first medium and said stripped solution is contacted by said second medium at a stripping pressure of 0.02 to 0.5 MPa.

9. The process of claim 8 wherein said stripping pressure is 0.05 to 0.12 MPa.

10. The process of claim 1 wherein said first stripping column has 1 to 30 theoretical plates.

11. The process of claim 10 wherein said first stripping column has 6 to 12 theoretical plates.

12. The process of claim 1 wherein said second column has 5 to 50 theoretical plates.

13. The process of claim 12 wherein said second column has 6 to 20 theoretical plates.

14. The process of claim 1 wherein said first medium and said second medium are individually steam or air.

15. The process of claim 14 wherein said first medium and said second medium are steam.

16. The process of claim 1 wherein said alkaline compound is selected from the group consisting of alkali metal hydroxides, calcium oxide, and calcium hydroxide.

17. The process of claim 16 wherein said alkaline compound is sodium hydroxide, calcium oxide, or calcium hydroxide.

18. The process of claim 15 wherein said steam is generated by heating said aqueous solution and/or said stripped solution.

19. The process of claim 1 wherein a first overhead product emerges from the head of said first column, said first product being condensed and recycled to said head of said first column.

20. The process of claim 1 wherein a second overhead product emerges from the head of said second column, said second product being condensed and recycled to said head of said second column.

21. The process of claim 1 wherein said aqueous solution is brought to said first pH without intermediate storage of said solution.