Sensors based on nanosstructured composite films

• US 5,238,729 A
• Filed: 04/05/1991
• Issued: 08/24/1993
• Est. Priority Date: 04/05/1991
• Status: Expired due to Term

• Current Assignee: 3M Company
• Original Assignee: 3M Company
• Inventors: Debe, Mark K.
• Primary Examiner(s): Ryan, Patrick J.
• Assistant Examiner(s): Weisberger, Richard C.
• Application Number:
  US07/681,332
• Time in Patent Office: 872 Days
• Field of Search: 428/245, 428/142, 428/143, 428/221, 428/323, 428/336, 428/338, 430/56
• US Class Current: 428/142
• CPC Class Codes: G01N 27/127 comprising nanoparticles
• CPC Class Codes: Y10T 428/24364 with transparent or protective coating
• CPC Class Codes: Y10T 428/24372 Particulate matter
• CPC Class Codes: Y10T 428/249921 Web or sheet containing structurally defined element or component
• CPC Class Codes: Y10T 428/249923 Including interlaminar mechanical fastener
• CPC Class Codes: Y10T 428/25 Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
• CPC Class Codes: Y10T 428/265 1 mil or less
• CPC Class Codes: Y10T 428/268 Monolayer with structurally defined element
• CPC Class Codes: Y10T 428/31855 Of addition polymer from unsaturated monomers

Abstract

An electrically reactive composite article comprising a random or regular array of microstructures partially encapsulated within an encapsulating layer, microstructures each comprising a whisker-like structure, optionally having a conformal coating enveloping the whisker-like structure is described. The composite article is useful as an electrically conducting component of a circuit, antenna, microelectrode, reactive heater, and multimode sensor to detect the presence of vapors, gases, or liquid analystes.

Claims

1. A composite article with an electrically conductive surface, comprising an encapsulating layer having a regular or random array of discrete microstructures, each microstructure comprising an organic compound wherein the molecule thereof is planar and comprises claims or rings over which π

-electron density is extensively delocalized and an optional conformal coating enveloping said whisker-like structure, wherein said array of discrete microstructures is encapsulated in said encapsulating layer, such that one end of each microstructure is embedded within said encapsulating layer and the other end of each microstructure is exposed and coincident with the surface of said encapsulating layer.

2. The composite article according to claim 1, wherein said organic material is selected from the group consisting of polynuclear aromatic hydrocarbons and heterocyclic aromatic compounds.

3. The composite article according to claim 2, wherein said organic material is selected from the group consisting of perylenes, phthalocyanines, and porphyrins.

4. The composite article according to claim 3, wherein said organic material is N,N'"'"'-di(3,5-xylyl)perylene-3,4:

9,10 bis(dicarboximide).

5. The composite article according to claim 1, wherein said conformal coating is a conducting material selected from a group consisting of metals, inorganic compounds, and conducting polymers.

6. The composite article according to claim 5, wherein said metal is selected from the group consisting of aluminum, cobalt, cobalt chromium, nickel, nickel chromium, platinum, silver, gold, iron, copper and other transition metals.

7. The composite article according to claim 1, wherein said encapsulating material is organic or an inorganic material.

8. The composite article according to claim 7, wherein said organic material is selected from the group consisting of organic pigments, thermoplastic polymers and co-polymers derived from olefins and other vinyl monomers, condensation and addition polymers, and natural polymers and their derivatives.

9. The composite article according to claim 7, wherein said inorganic material is selected from the group consisting of gels, sols, or semiconductor, or metal oxides.

10. The composite article according to claim 1, wherein capacitive impedance is measured perpendicular to the surface plane of said article and resistive impedence is measured parallel to the surface plane of said article.

11. A sensor comprising the composite article in accordance with claim 1, wherein said conformal coating, said encapsulating material and said whisker-like structures are independently selected for their responsiveness to gas, vapor, or liquid analytes.

12. A flexible thin film according to claim 11.

13. The composite article according to claim 4, wherein said organic pigments are selected from the group consisting of perylene red, phthalocyanine, and porphyrins.

14. The composite article according to claim 8, wherein said thermoplastic polymers and co-polymers are selected from the group consisting of polyesters, polyimides, polyamides, polyethers, polyurethanes, and polyureas.