Process for preparation of styrene resin composition and styrene resin composition

• US 5,239,003 A
• Filed: 11/27/1991
• Issued: 08/24/1993
• Est. Priority Date: 11/30/1990
• Status: Expired due to Fees

• Current Assignee: Nippon Zeon Co., Ltd.
• Original Assignee: Nippon Zeon Co., Ltd.
• Inventors: Onishi, Hidenori, Watanabe, Hiroyuki
• Primary Examiner(s): Seidleck, James J.
• Assistant Examiner(s): Delaney, Patrick R.
• Application Number:
  US07/798,748
• Time in Patent Office: 636 Days
• Field of Search: 525/153, 525/157, 525/198, 525/333.6, 525/164, 525/181, 525/184, 525/193, 525/426
• US Class Current: 525/181
• CPC Class Codes: C08F 12/08 Styrene
• CPC Class Codes: C08F 212/08 Styrene
• CPC Class Codes: C08F 257/02 on to polymers of styrene or alkyl-substituted styrenes
• CPC Class Codes: C08F 8/30 Introducing nitrogen atoms or nitrogen-containing groups

Abstract

A process for preparing a styrene resin composition which comprises subjecting to bulk or bulk-suspension polymerization a solution obtained by dissolving (A) a modified styrene polymer obtained by introducing directly or through another atomic group at least one functional group represented by the general formula

>C═N.sup.+ <

into the polymer chain of a styrene polymer obtained by polymerizing 90 to 100% by weight of a styrene monomer with 0 to 10% by weight if a monomer copolymerizable with the styrene monomer, if desired together with (B) a rubber-like polymer in (C) a styrene monomer.

Claims

1. A process for preparing a styrene resin composition which comprises subjecting to bulk or bulk-suspension polymerization a solution obtained by dissolving a modified styrene polymer (A) in a styrene monomer (C), said modified styrene polymer being obtained by introducing directly or through another atomic group at least one functional group represented by the general formula into the styrene polymer chain obtained by polymerizing 90 to 100% by weight of a styrene monomer with 0 to 10% by weight of a monomer copolymerizable with the styrene monomer.

2. The process for preparing a styrene resin composition according to claim 1 wherein the amount of the modified styrene polymer (A) dissolved in said styrene monomer (C) is 0.1 to 50 parts by weight per 100 parts by weight of the styrene monomer (C).

3. The process for preparing a styrene resin composition according to claim 1 wherein the modified styrene polymer (A) is a styrene polymer obtained by reacting a living anionic styrene polymer with at least one compound selected from an N-substituted lactam or corresponding thiolactam, an N-substituted ethyleneurea or corresponding thiourea, an N-substituted aminoketone or corresponding thioketone, and an N-substituted aminoaldehyde or corresponding thioaldehyde, and then hydrolyzing the resulting product.

4. A styrene resin composition obtained by the method of claim 1.

5. The process for preparing a styrene resin composition according to claim 1 wherein a rubber-like polymer (B) is dissolved together with said modified styrene polymer (A).

6. The process for preparing a styrene resin composition according to claim 5, wherein said rubber-like polymer (B) is selected from the group consisting of polybutadiene, styrene-butadiene copolymers and acrylonitrile-butadiene copolymers.

7. The process for preparing a styrene resin composition according to claim 5, wherein the amount of the rubber-like polymer (B) dissolved together with said modified styrene polymer (A) comprises from 2 to 25 parts by weight per 100 parts by weight of the styrene monomer (C) and the modified styrene monomer (A).

8. The process for preparing a styrene resin composition according to claim 1, wherein said styrene monomer is selected from the group consisting of styrene, vinyltoluene, 1,3-dimethylstyrene, α

-methylstyrene, chlorostyrene, and vinylnaphthalene.

9. The process for preparing a styrene resin composition according to claim 1, wherein said monomer copolymerizable with the styrene monomer is a conjugated diene monomer.

10. The process for preparing a styrene resin composition according to claim 1, wherein the amount of the modified styrene polymer (A) dissolved in the styrene monomer (C) is from 0.1 to 50 parts by weight per 100 parts by weight of the styrene monomer (C).

11. The process for preparing a styrene resin composition according to claim 10, wherein the amount of the modified styrene polymer (A) dissolved in the styrene monomer (C) is from 1 to 10 parts by weight per 100 parts by weight of the styrene monomer (C).

12. The process for preparing a styrene resin composition according to claim 1 which comprises bulk polymerizing said solution at a temperature of between 50°

to 250°

C. in the absence of a catalyst.

13. The process for preparing a styrene resin composition according to claim 1, which comprises bulk polymerizing said solution at a temperature of between 20°

to 200°

C. in the presence of a catalyst.

14. The process for preparing a styrene resin composition according to claim 1, which comprises bulk polymerizing said solution with stirring until the conversion of the styrene monomer to a polymer reaches 30%.

15. The process for preparing a styrene resin composition according to claim 1 which comprises bulk suspension polymerizing said solution with stirring until the conversion of the styrene monomer to a polymer reaches 10-50% thereby forming a polymerized mixture, dispersing said polymerized mixture in an aqueous medium in the presence of a suspension stabilizer, and suspension polymerizing said aqueous dispersion.

16. The process for preparing a styrene resin composition according to claim 1 further comprising compounding the styrene resin composition with one or more additives selected from the group consisting of pigments, flame retardants, and inorganic fillers.