Reinforced corrugated thin metal foil strip useful in a catalytic converter core, a catalytic converter core containing said strip and an electrically heatable catalytic converter containing said core

• US 5,240,682 A
• Filed: 05/06/1991
• Issued: 08/31/1993
• Est. Priority Date: 05/06/1991
• Status: Expired due to Term

• Current Assignee: Engelhard Corporation (BASF SE)
• Original Assignee: W R Grace & Company - CONN (Standard Industries Holdings, Inc.)
• Inventors: Whittenberger, William A., Cornelison, Richard C.
• Primary Examiner(s): Kryza, Lynn M.
• Application Number:
  US07/696,132
• Time in Patent Office: 848 Days
• Field of Search: 422/174, 422/177, 422/179, 422/180, 422/199, 502/439, 502/527, 55/DIG. 30, 55/520, 55/521, 60/300, 60/322
• US Class Current: 422/174
• CPC Class Codes: B01D 53/9454 characterised by a specific device
• CPC Class Codes: B01J 35/56 Foraminous structures having flow-through passages or channels, e.g. grids or three-dimensional monoliths
• CPC Class Codes: F01N 2330/02 Metallic plates or honeycombs, e.g. superposed or rolled-up corrugated or otherwise deformed sheet metal
• CPC Class Codes: F01N 3/2026 directly electrifying the catalyst substrate, i.e. heating the electrically conductive catalyst substrate by joule effect
• CPC Class Codes: F01N 3/2814 all sheets, plates or foils being corrugated
• CPC Class Codes: H05B 3/12 characterised by the composition or nature of the conductive material
• CPC Class Codes: Y02T 10/12 Improving ICE efficiencies
• CPC Class Codes: Y10S 55/30 Exhaust treatment

Abstract

There is provided an improved reinforced corrugated thin stainless steel strip in which either or both of the longitudinal edges are overfolded to increase the thickness and stiffness of the foil to better resist the tendency to failure in a severe hot-shake screening test. There is also provided a core and an electrically heatable catalytic converter containing the core for use in the exhaust line of an internal combustion engine.

Claims

1. A corrugated thin metal foil strip having a longitudinally extending center line with an initial strip width and having at least one longitudinal edge folded toward the center line of the strip prior to corrugating said strip to form a folded section and a remaining portion of the strip which is unfolded, the width of the folded section being from about 5% to about 25% of the width of the remaining portion of the strip which is unfolded.

2. A corrugated thin metal foil strip in accordance with claim 1 wherein the foil is corrugated in a herringbone, chevron, truncated herringbone, or sinusoidal pattern.

3. A corrugated thin metal foil strip in accordance with claim 1 wherein the foil is overfolded along one edge toward the center line of the strip.

4. A corrugated thin metal foil strip as defined in claim 1 wherein the foil strip is overfolded along both longitudinal edges.

5. A corrugated thin metal foil strip as defined in claim 1 wherein the corrugations have a pitch of from about 0.02" to about 0.2" and an amplitude of from about 0.02" to about 0.25".

6. A corrugated thin metal foil strip as defined in claim 1 wherein the foil has a thickness of from 0.001" to about 0.005".

7. A corrugated thin metal foil strip as defined in claim 1, wherein the metal is stainless steel.

8. A corrugated thin stainless steel strip as defined in claim 7 wherein the stainless steel is a ferritic stainless steel.

9. A corrugated thin metal foil strip in accordance with claim 1 further comprising a refractory metal oxide coating on at least one surface thereof, and a noble metal catalyst deposited on said refractory metal oxide coating.

10. A corrugated thin metal foil strip as defined in claim 9 wherein the refractory metal oxide coating comprises a major proportion of alumina.

11. A corrugated thin metal foil strip as defined in claim 10 wherein the alumina is gamma alumina.

12. A core for an electrically heatable catalytic converter including a core member having a predetermined geometric configuration and comprising a corrugated thin metal foil strip having a predetermined length, and a predetermined width, said foil strip being overfolded prior to corrugating said strip along at least one edge to form a folded section and a remaining portion of the strip which is unfolded, the width of the folded section being from about 5% to about 25% of the width of the remaining portion of the strip which is unfolded, said corrugated foil strip being spirally wound about an electrically conducting central metal post with at least one overfolded edge on the outer end of the core, and including a retaining shell tightly surrounding the core and being electrically bonded thereto.

13. A core as defined in claim 12 wherein the geometric configuration is circular.

14. A core as defined in claim 12, wherein the metal is stainless steel.

15. A core as defined in claim 12 further comprising a housing surrounding and supporting said core and insulation means for electrically isolating said core from said housing.

16. A core as defined in claim 15 including means for connecting the central post to one pole of a direct current voltage source, means for connecting the retaining shell to the housing, and means for connecting the housing to the opposite pole of said direct current voltage source.

17. A core as defined in claim 16 wherein the voltage source has a voltage rating of from 12 to 108 volts.

18. An electrically heatable catalytic converter for treating exhaust gas emanating from an internal combustion engine to remove pollutant materials therefrom, said converter comprising (1) an outer metallic housing having inner and outer walls, (2) an end cap adaptor at each end of said housing for adapting the configuration of the outer housing for insertion into a conventional exhaust system for said internal combustion engine, (3) an insulating liner for the inner wall of the housing, (4) a core for said converter within said insulating liner including a core member comprising a corrugated thin metal foil strip having a predetermined length and a predetermined width, the length being greater than the width, said foil strip being overfolded prior to corrugating said strip along at least one longitudinal edge to form a folded section and a remaining portion of the strip which is unfolded, the width of the folded section being from about 5% to about 25% of the width of the remaining portion of the foil strip which is unfolded, said foil strip being spirally wound about an electrically conducting central metal post with at least one overfolded edge on the outer end of the core, and including a retaining shell tightly surrounding said core and being electrically bonded thereto, (5) means for connecting said central post to one pole of a direct current voltage source, (6) means for connecting said housing to the other pole of a direct current voltage source, and (7) a direct current voltage source rated at from 12 to 108 volts.

19. An electrically heatable catalytic converter as defined in claim 18, wherein the metal is stainless steel.