Spectrophotometric monitoring of multiple water treatment performance indicators using chemometrics

• US 5,242,602 A
• Filed: 03/04/1992
• Issued: 09/07/1993
• Est. Priority Date: 03/04/1992
• Status: Expired due to Term

• Current Assignee: Biotronics Technology Incorporated, W.R. Grace & Co.-Conn. (WR Grace & Company)
• Original Assignee: Biotronics Technology Incorporated, W R Grace & Company - CONN (WR Grace & Company)
• Inventors: Richardson, John, Kahle, Scott J., Brickhouse, Mark D., Kelly, John A., Schlager, Kenneth J., Kye, Larry M., Engstrom, Gary G.
• Primary Examiner(s): Drodge, Joseph W.
• Application Number:
  US07/845,889
• Time in Patent Office: 552 Days
• Field of Search: 210/85, 210/94, 210/95, 210/96.1, 210/143, 210/739, 210/745, 210/656, 422/82.05, 422/82.09, 436/171, 436/39, 364/498, 364/500, 364/502, 356/306, 356/319, 356/320, 356/326, 356/300, 356/303
• US Class Current: 210/745
• CPC Class Codes: G01N 21/31 Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry G01N21/72 takes precedence
• CPC Class Codes: G01N 21/8507 Probe photometers, i.e. with optical measuring part dipped into fluid sample
• CPC Class Codes: G01N 2201/129 Using chemometrical methods
• CPC Class Codes: G01N 33/1813 specific cations in water, e.g. heavy metals electrochemical analysis G01N27/26; detection of ions by colorimetry G01N31/22
• CPC Class Codes: G01N 33/182 specific anions in water electrochemical analysis G01N27/26; detection of ions by colorimetry G01N31/22

Abstract

The present invention is directed to a novel method for analyzing aqueous systems to simultaneously quantify the concentrations of multiple active or inactive treating components which may be contained therein. The method comprises determining the absorbance or emission spectrum of the components in the aqueous system over the wavelength range of from 200 to 2500 nm, and then applying chemometrics algorithms to extract and analyze features in the spectrum that are specific to the qualitative and quantitative concentrations from the specific components to simultaneously determine the concentrations of the components.

Claims

1. A method for simultaneously measuring the concentration of multiple performance indicators comprising components used in treating an aqueous system comprising directly determining an absorbance or emission spectrum of the aqueous system in a wavelength range of 200 to 2500 nm, and applying chemometrics algorithms to the absorbance or emission spectrum to simultaneously determine the concentrations of the performance indicators.

2. The method according to claim 1 wherein the concentrations of the performance indicators determined by the chemometrics algorithms are compared to predefined ranges for the respective performance indicators, and if any of the concentrations of the performance indicators are outside the predefined ranges, changing the dosage of those performance indicators which are outside this range.

3. The method according to claim 1 wherein the aqueous system is a cooling water system, a boiler water system, a desalinization unit, a wastewater treatment facility, or pulp or paper processing equipment.

4. The method according to claim 1 wherein the spectrum is analyzed with a UV-vis-NIR diode array spectrophotometer in a wavelength range of from 200 nm to 2500 nm.

5. The method according to claim 1 wherein the chemometrics algorithm is based on a rotated principle component analysis of absorbance or emission spectrum.

6. The method according to claim 1 wherein the performance indicators are selected from the group consisting of scale inhibitors, corrosion inhibitors, lubricants, metal working fluids, pH regulators, dispersants, defoaming agents, sequestrants, biocides, detackifiers, precipitating agents.

7. A method for simultaneously measuring the concentration of multiple performance indicators comprising components used in treating an aqueous system comprising directly determining an absorbance or emission spectrum of the aqueous system which contains the performance indicators in a wavelength range of 200 to 2500 nm, and applying chemometrics algorithms to the absorbance or emission spectrum to simultaneously determine the concentrations of the respective performance indicators and wherein the chemometrics algorithm is based on principle component analysis of the absorbance or emission spectrum.

8. The method according to claim 7 wherein the principle component analysis is based on a first derivative of the absorbance or emission spectrum.

9. The method according to claim 7 wherein the principle component analysis is based on a second derivative of the absorbance or emission spectrum.

10. A method for simultaneously measuring the concentrations of multiple performance indicators comprising one or more treating components and at least one inert tracer in aqueous systems comprising directly determining an absorbance or emission spectrum of the aqueous system in a wavelength range of 200 to 2500 nm, and applying chemometrics algorithms to the absorbance or emission spectrum to determine the concentrations of the performance indicators and the at least one inert tracer.

11. The method according to claim 10 wherein the concentrations of the performance indicators determined by the chemometrics algorithms are compared to predefined ranges for the respective performance indicators, and if any of the concentrations of the performance indicators are outside the predefined ranges, changing the dosage of those performance indicators which are outside this range.

12. The method according to claim 10 wherein the aqueous system is a cooling water system, a boiler water system, a desalinization unit, a wastewater treatment facility, or pulp or paper processing equipment.

13. The method according to claim 10 wherein the spectrum is analyzed with a UV-vis-NIR diode array spectrophotometer in a wavelength range of from 200 nm to 800 nm.

14. The method according to claim 10 wherein the chemometrics algorithm is based on a rotated principle component analysis of absorbance or emission spectrum.

15. The method according to claim 10 wherein the performance indicators are selected from the group consisting of scale inhibitors, corrosion inhibitors, lubricants, metal working fluids, pH regulators, dispersants, defoaming agents, sequestrants, biocides, detackifiers, precipitating agents.

16. A method for simultaneously measuring the concentrations of multiple performance indicators comprising one or more treating components and at least one inert tracer in an aqueous system comprising directly determining an absorbance or emission spectrum of the aqueous system in a wavelength range of from 200 to 2500 nm, and applying chemometrics algorithms to the absorbance or emission spectrum to determine the concentrations of the performance indicators and the at least one inert tracer and wherein the chemometrics algorithms is based on principle component analysis of the absorbance or emission spectrum.

17. The method according to claim 16 wherein the principle component analysis is based on a first derivative of the absorbance or emission spectrum.

18. The method according to claim 16 wherein the principle component analysis is based on a second derivative of the absorbance or emission spectrum.